Phased rubber composition and tire with tread

Patent metadata

Field	Value
Publication number	US-9890270-B2
Application number	US-201615257056-A
Country	US
Kind code	B2
Filing date	Sep 6, 2016
Priority date	Oct 8, 2015
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

The invention relates to a phased rubber composition and tire tread thereof intended for heavy duty service such as for example a truck tire. The phased rubber composition is comprised of the product of blending a first rubber phase comprised of cis 1,4-polybutadiene rubber and reinforcing filler comprised of rubber reinforcing carbon black and a second rubber phase comprised of natural cis 1,4-polyisoprene rubber and reinforcing filler comprised of precipitated silica.

First claim

What is claimed is:

1. A method for preparation of a sulfur curable rubber composition comprised of diene-based elastomers with reinforcing filler comprised of a combination of rubber reinforcing carbon black and precipitated silica comprised of:
(A) preparation of a first masterbatch comprised of cis 1,4-polybutadiene rubber and from about 35 to about 70 phr of reinforcing filler comprised of rubber reinforcing carbon black,
(B) preparation of a second masterbatch comprised of cis 1,4-polyisoprene natural rubber and from about 15 to about 50 phr of reinforcing filler comprised of precipitated silica, and
(C) blending said masterbatches:
(1) together followed by addition of sulfur curatives comprised of sulfur and sulfur vulcanization accelerator(s), or
(2) together with sulfur curatives comprised of sulfur and sulfur vulcanization accelerator(s);
wherein a silica coupling agent (silica coupler) is blended with:
(a) with the second masterbatch, or
(b) with the blend of masterbatches to couple the precipitated silica to the diene-based elastomer(s), where the silica coupling agent contains a moiety reactive with hydroxyl groups on said precipitated silica and another different moiety interactive with said diene-based elastomer(s),

wherein the rubber composition comprised of the blended masterbatches contains about 55 to about 70 phr of said cis 1,4-polybutadiene rubber and about 45 to about 30 phr of said cis 1,4-polyisoprene natural rubber;
wherein the rubber composition comprised of the blended masterbatches contains reinforcing filler comprised of from about 25 to about 40 phr of said rubber reinforcing carbon black and from about 5 to about 25 phr of said precipitated silica for a total of from about 40 to about 65 phr of said reinforcing filler,
wherein said first masterbatch further contains zinc oxide and said second masterbatch is substantially exclusive of zinc oxide,
wherein said first masterbatch further contains added fatty acid and said second masterbatch is substantially exclusive of added fatty acid.

2. The method of claim 1 wherein said second masterbatch contains at least one of microcrystalline wax and paraffinic wax and wherein said first masterbatch is substantially exclusive of microcrystalline wax and paraffinic wax.

3. The method of claim 1 where said cis 1,4-polybutadiene is a specialized cis 1,4-polybutadiene having a microstructure comprised of about 96 to about 99 percent cis 1,4-isomeric units, a number average molecular weight (Mn) in a range of from about 150,000 to about 200,000 and a heterogeneity index (Mw/Mn) in a range of from about 1.5/1 to about 2/1.

4. The method of claim 1 wherein said specialized cis 1,4-polybutadiene is prepared by neodymium catalysis of 1,3-butadiene monomer.

5. The method of claim 1 wherein said masterbatches are blended together followed by subsequently blending with sulfur curatives therewith comprised of sulfur and sulfur vulcanization accelerator(s).

6. The method of claim 1 wherein said masterbatches are blended together with sulfur curatives comprised of sulfur and sulfur vulcanization accelerator(s).

7. The method of claim 1 wherein said coupling agent is blended with said second masterbatch.

8. The method of claim 1 wherein said coupling agent is blended with said blend of masterbatches.

9. The method of claim 1 wherein a minor amount of precipitated silica is added to at least one of said first masterbatch or to the blend of first and second masterbatches.

10. The method of claim 1 wherein a minor amount of rubber reinforcing carbon black is added to at least one of said second masterbatch or to the blend of first and second masterbatches.

11. The method of claim 1 wherein a minor amount of additional diene-based rubber is added to at least one of said first masterbatch or to the blend of first and second masterbatches wherein said additional diene-based rubber is comprised of at least one of cis 1,4-polyisoprene rubber and styrene/butadiene rubber.

12. The method of claim 1 wherein a minor amount of additional diene-based rubber is added to at least one of said second masterbatch or to the blend of first and second masterbatches wherein said additional diene-based rubber is comprised of at least one of cis 1,4-polyisoprene synthetic rubber, cis 1,4-polybutadiene rubber and styrene/butadiene rubber.

13. A rubber composition prepared by the method of claim 1 .

14. A rubber composition prepared by the method of claim 1 comprised of a blend of a cis 1,4-polybutadiene rubber phase containing said rubber reinforcing carbon black and a dispersed cis 1,4-polyisoprene natural rubber phase containing said precipitated silica, wherein said cis 1,4-polybutadiene rubber phase contains from about 35 to about 70 phr of rubber reinforcing carbon black to thereby provide a path of least electrical resistance through said rubber composition.

15. A rubber composition prepared by the method of claim 2 .

16. A rubber composition prepared by the method of claim 3 .

17. A tire containing a component comprised of a sulfur cured rubber composition of claim 13 .

18. A tire containing a component comprised of a sulfur cured rubber composition of claim 14 .

19. The tire of claim 17 wherein said component is a tire tread.

20. The tire of claim 19 wherein said tread is comprised of said phased rubber blend which contains a path of least electrical resistance through the tread to the tread running surface by said dominate polybutadiene rubber phase to thereby promote dissipation of internally generated electrical charge to the tire running surface.

Assignees

• Goodyear Tire & Rubber

Inventors

• Forciniti Leandro
• Meza Roberto Cerrato
• Zhao Junling
• Busch Warren James
• Sandstrom Paul Harry
• Zartman Gregory Daniel

Classifications

• C08L9/00 Primary

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08J3/22

  using masterbatch techniques · CPC title

• C08J2407/00

  Characterised by the use of natural rubber · CPC title

• C08J2309/00

  Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08L7/00

  Compositions of natural rubber · CPC title