Protective film

Patent metadata

Field	Value
Publication number	US-9890257-B2
Application number	US-201414651586-A
Country	US
Kind code	B2
Filing date	Nov 21, 2014
Priority date	Nov 21, 2013
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

The present invention relates to a protective film, a conductive laminate including the protective film, and a polarizing plate including the protective film, and provides the protective film which has peel strength controlled to be low, thus allowing for an easy removal of the protective film, which has an excellent polymerization stability and pot life, and may prevent a problem of an additive transfer to an adherend due to the additive.

First claim

What is claimed is:

1. A protective film, comprising a pressure-sensitive adhesive layer which contains:
a pressure-sensitive adhesive base resin having polyorganosiloxane as a polymerization unit, wherein the polymerization unit of polyorganosiloxane is derived from a compound of Formula 1:

wherein:
n is an integer in the range of 0 to 1,500;
R represents identical or different components, and represents hydrogen, an alkyl group, an alkoxy group, or an alkynyl group, respectively, and P is a polymerizable functional group; and
the polyorganosiloxane has a functional group equivalent of 3,000 to 20,000 g/mol;

a multifunctional crosslinking agent which crosslinks the pressure-sensitive adhesive base resin, wherein the multifunctional crosslinking agent is a mixture of an aliphatic linear polyvalent NCO and an aliphatic ring-shaped polyvalent NCO, the aliphatic linear polyvalent NCO and aliphatic ring-shaped polyvalent NCO present in a ratio in the range of 6:4 to 9:1 to form the mixture; and
a curing retarder.

2. The protective film of claim 1 , wherein the polyorganosiloxane has a weight-average molecular weight of 300 to 100,000.

3. The protective film of claim 1 , wherein the polymerizable functional group comprises an alkenyl group, an epoxy group, a cyano group, a carboxyl group, an acryloyl group, a methacryloyl group, an acryloyloxy group, or a methacryloyloxy group.

4. The protective film of claim 1 , wherein the pressure-sensitive adhesive base resin further comprises a (meth)acrylic acid ester monomer as a polymerization unit.

5. The protective film of claim 4 , wherein the pressure-sensitive adhesive base resin comprises polymerization units derived from 80 to 99.8 parts by weight of the (meth)acrylic acid ester monomer and 0.1 to 10 parts by weight of polyorganosiloxane.

6. The protective film of claim 4 , wherein the pressure-sensitive adhesive base resin further comprises a polymerization unit derived from a copolymerizable monomer having a crosslinkable functional group.

7. The protective film of claim 6 , wherein the copolymerizable monomer having a crosslinkable functional group is one or more selected from the group consisting of a hydroxy group-containing comonomer, a carboxyl group-containing comonomer, and a nitrogen containing-comonomer.

8. The protective film of claim 6 , wherein the copolymerizable monomer having a crosslinkable functional group is included at 0.01 to 14 parts by weight with respect to 100 parts by weight of the pressure-sensitive adhesive base resin.

9. The protective film of claim 1 , wherein the multifunctional crosslinking agent is included at 0.01 to 20 parts by weight with respect to 100 parts by weight of the pressure-sensitive adhesive base resin in the pressure-sensitive adhesive layer.

10. The protective film of claim 1 , wherein the curing retarder is one or more selected from the group consisting of methyl acetoacetate, ethyl acetoacetate, octyl acetoacetate, oleyl acetoacetate, lauryl acetoacetate, stearyl acetoacetate, acetyl acetone, 2,4-hexanedione, or benzoyl acetone.

11. The protective film of claim 1 , further comprising a base layer, wherein the pressure-sensitive adhesive layer is formed on one side of the base layer.

12. The protective film of claim 11 , wherein the base layer comprises a one-component polymer such as a polycarbonate, a polyether sulfone, a polyacrylate, a polyester-based polymer, a polyolefin-based polymer or a norbornene-based polymer, a copolymerized polymer, or an epoxy-based polymer.

13. The protective film of claim 1 , wherein the pressure-sensitive adhesive base resin is a resin which requires 5 hours or more until a viscosity of the resin is increased to twice or more than the initial viscosity of the resin which has just been prepared, immediately after the resin is mixed with a crosslinking agent.

14. The protective film of claim 1 , wherein the polymerizable functional group comprises an alkenyl group, an epoxy group, a cyano group, or a carboxyl group.

15. The protective film of claim 1 , wherein the curing retarder comprises a β-keto ester selected from the group consisting of methyl acetoacetate, ethyl acetoacetate, octyl acetoacetate, oleyl acetoacetate, lauryl acetoacetate, and stearyl acetoacetate.

16. A conductive laminate comprising:
a conductive film having at least one conductive layer; and
the protective film of claim 1 adhered to one side of the conductive film.

17. A polarizing plate comprising:
at least one polarizer; and
the protective film of claim 1 adhered to one side of the polarizer.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Hui Je
• Kim Hyun Cheol
• Park Yong Su

Classifications

• C08G18/6229 Primary

  Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols · CPC title

• B32B2250/03

  3 layers · CPC title

• B32B38/10

  Removing layers, or parts of layers, mechanically or chemically · CPC title

• C09J183/04

  Polysiloxanes · CPC title

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title