Electrolytic enrichment method for heavy water

Patent metadata

Field	Value
Publication number	US-9890062-B2
Application number	US-201414902363-A
Country	US
Kind code	B2
Filing date	Jul 24, 2014
Priority date	Jul 31, 2013
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

An electrolytic enrichment method for heavy water includes enriching heavy water by electrolysis using an alkaline water electrolysis cell including an anode chamber that holds an anode, a cathode chamber that holds a cathode, and a diaphragm. In the method, an electrolyte prepared by adding high-concentration alkaline water to raw material water containing heavy water is circularly supplied to the anode chamber and the cathode chamber from a circulation tank; an anode-side gas-liquid separator and an anode-side water-seal device are connected to the anode chamber, and a cathode-side gas-liquid separator and a cathode-side water-seal device are connected to the cathode chamber; and electrolysis is continued while the alkali concentration in the electrolyte supplied to both electrolysis chambers is maintained at a constant concentration by circularly supplying, to the circulation tank, the electrolyte from which the gas generated from the anode-side gas-liquid separator and the cathode-side gas-liquid separator is separated.

First claim

The invention claimed is:

1. An electrolytic enrichment method for heavy water, the method comprising:
enriching heavy water by electrolysis using an alkaline water electrolysis cell consisting of an anode chamber that holds an anode, a cathode chamber that holds a cathode, and a diaphragm that divides between the anode chamber and the cathode chamber,
wherein an electrolyte prepared by adding high-concentration alkaline water to raw material water consisting of heavy water containing tritium is circularly supplied to both electrolysis chambers including the anode chamber and the cathode chamber from a circulation tank containing the electrolyte;
an anode-side gas-liquid separator and an anode-side water-seal device are connected to the anode chamber, and a cathode-side gas-liquid separator and a cathode-side water-seal device are connected to the cathode chamber; and
continuing electrolysis while the alkali concentration in the electrolyte supplied to the both electrolysis chambers is maintained at a constant concentration by circularly supplying, to the circulation tank, the electrolyte from which the gas generated from each of the anode-side gas-liquid separator and the cathode-side gas-liquid separator is separated, so that heavy water in the electrolyte is enriched and, at the same time, the hydrogen gas is recovered or discharged from the cathode-side gas-liquid separator and the oxygen gas is recovered or discharged from the anode-side gas-liquid separator.

2. The electrolytic enrichment method for heavy water according to claim 1 , wherein electrolysis is continued while the alkali concentration of the electrolyte is maintained at the initial concentration by supplying raw material water in the amount corresponding to the water disappearing by the electrolysis to the circulation tank.

3. The electrolytic enrichment method for heavy water according to claim 1 , wherein the alkali concentration of the electrolyte is 1.5% to 40% by mass.

4. The electrolytic enrichment method for heavy water according to claim 1 , wherein the alkali concentration of the electrolyte is 20% to 30% by mass.

5. The electrolytic enrichment method for heavy water according to claim 1 , wherein electrolysis is continued while the alkali concentration of the electrolyte is maintained at a constant concentration by supplying the raw material water to the circulation tank so that the alkali concentration of the electrolyte does not exceed 40% by mass.

6. The electrolytic enrichment method for heavy water according to claim 5 ,
wherein electrolysis is continued while the alkali concentration of the electrolyte is maintained at a constant concentration by supplying the raw material water to the circulation tank so that the alkali concentration of the electrolyte does not exceed 30% by mass.

7. The electrolytic enrichment method for heavy water according to claim 1 ,
wherein the pressure in the cathode chamber and the pressure in the anode chamber are adjusted by adjusting the height of a water surface in the cathode-side water-seal device and the height of a water surface in the anode-side water-seal device, respectively, in order to control the ratio of the oxygen gas generated in the anode chamber mixed into the hydrogen gas generated in the cathode chamber and/or the ratio of the hydrogen gas generated in the cathode chamber mixed into the oxygen gas generated in the anode chamber.

8. The electrolytic enrichment method for heavy water according to claim 1 , wherein the diaphragm is a neutral diaphragm.

9. The electrolytic enrichment method for heavy water according to claim 1 , wherein the diaphragm is a cation-exchange membrane.

Assignees

• Industrie De Nora Spa

Inventors

• Manabe Akiyoshi
• Nishiki Yoshinori
• Kunimatsu Akira

Classifications

• C01B13/0207

  Water · CPC title

• C01B5/02

  Heavy water; Preparation by chemical reaction of hydrogen isotopes or their compounds, e.g. 4ND3 + 7O2 ---> 4NO2 + 6D2O, 2D2 + O2 ---> 2D2O · CPC title

• C25B1/04

  by electrolysis of water · CPC title

• C02F2201/46185

  Recycling the cathodic or anodic feed · CPC title

• C02F2001/4619

  only cathodic or alkaline water, e.g. for reducing · CPC title