Method for producing hematite for ironmaking

Patent metadata

Field	Value
Publication number	US-9890055-B2
Application number	US-201414915698-A
Country	US
Kind code	B2
Filing date	Sep 4, 2014
Priority date	Sep 18, 2013
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

A method of producing (high-purity) hematite for ironmaking includes adding an oxidant and sulfuric acid to nickel oxide ore and then leaching nickel. The method further includes forming a neutralized residue having a sulfur grade exceeding 1.0% by weight by adding a neutralizing agent to leach slurry and being subjected to solid-liquid separation. The neutralizing agent functions to form plaster by reaction with a free sulfuric acid of surplus acid contained in the leach slurry. The leach slurry is a mixture of a leachate and a leach residue obtained after leaching the nickel. The method then includes heating the neutralized residue at a heating temperature of 600° C. or more and 1400° C. or less to form hematite having a sulfur grade of 1.0% or less by weight.

First claim

The invention claimed is:

1. A method for producing hematite for ironmaking by a high pressure acid leach (HPAL) process of adding an oxidant and sulfuric acid to nickel oxide ore that contains iron and then leaching nickel, the method further comprising:
forming a neutralized residue having a sulfur content exceeding 1.0% by weight by adding a neutralizing agent to leach slurry to form a neutralized leach slurry and subjecting the neutralized leach slurry to solid-liquid separation, the neutralizing agent serving to form calcium sulfate by reaction with a free sulfuric acid of surplus acid contained in the leach slurry, the leach slurry being a mixture of a leachate and a leach residue obtained after leaching the nickel; and
heating the neutralized residue at a heating temperature of 600° C. to 1400° C. to form hematite having a sulfur content of 1.0% or less by weight.

2. The method for producing the hematite for ironmaking according to claim 1 , wherein the heating temperature during heating is 800° C. to 1400° C. and the sulfur content of the hematite obtained after the heat treatment is 0.8% or less by weight.

3. The method for producing the hematite for ironmaking according to claim 1 , wherein the heating temperature during heating is 1000° C. to 1400° C. and the sulfur content of the hematite obtained after the heat treatment is 0.4% or less by weight.

4. A method for producing hematite for ironmaking by an HPAL process of adding an oxidant and sulfuric acid to nickel oxide ore that contains iron and then leaching nickel, the method further comprising:
forming a neutralized residue having a sulfur content exceeding 1.0% by weight by adding a neutralizing agent to leach slurry to form a neutralized leach slurry and subjecting the neutralized leach slurry to solid-liquid separation, the neutralizing agent serving to form a sulfur component in the form of jarosite by reaction with a free sulfuric acid of surplus acid contained in the leach slurry, the leach slurry being a mixture of a leachate and a leach residue obtained after leaching the nickel; and
heating the neutralized residue at a heating temperature of 600° C. to 1400° C. to form hematite having a sulfur content of 0.6% or less by weight.

5. The method for producing the hematite for ironmaking according to claim 4 , wherein the heating temperature during heating is 800° C. to 1400° C. and the sulfur content of the hematite obtained after the heat treatment is 0.8% or less by weight.

6. The method for producing the hematite for ironmaking according to claim 4 , wherein the heating temperature during heating is 1000° C. to 1400° C. and the sulfur content of the hematite obtained after the heat treatment is 0.4% or less by weight.

7. A method for producing hematite for ironmaking by an HPAL process of adding an oxidant and sulfuric acid to nickel oxide ore that contains iron and then leaching nickel, the method further comprising:
forming a neutralized residue having a sulfur content exceeding 1.0% by weight by adding two types of neutralizing agents to leach slurry to form a neutralized leach slurry and subjecting the neutralized leach slurry to solid-liquid separation, one neutralizing agent serving to form calcium sulfate and another neutralizing agent serving to form a sulfur component in the form of jarosite by reaction with a free sulfuric acid of surplus acid contained in the leach slurry, the leach slurry being a mixture of a leachate and a leach residue obtained after leaching the nickel; and
heating the neutralized residue at a heating temperature of 600° C. to 1400° C. to form hematite having a sulfur grade of 0.8% or less by weight.

8. The method for producing the hematite for ironmaking according to claim 7 , wherein the heating temperature during heating is 800° C. to 1400° C. and the sulfur content of the hematite obtained after the heat treatment is 0.8% or less by weight.

9. The method for producing the hematite for ironmaking according to claim 7 , wherein the heating temperature during heating is 1000° C. to 1400° C. and the sulfur content of the hematite obtained after the heat treatment is 0.4% or less by weight.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Sasaki Hideki
• KAN Yasumasa
• Mitsui Hiroyuki

Classifications

• C01G49/06 Primary

  Ferric oxide [Fe2O3] · CPC title

• Y02P10/212

  Cross-Sectional Technologies · mapped topic

• C22B23/043

  Sulfurated acids or salts thereof · CPC title

• C01P2006/80

  Compositional purity · CPC title

• C22B23/0461

  by chemical methods · CPC title