Water treatment method and water treatment apparatus
US-2024383788-A1 · Nov 21, 2024 · US
US9889408B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9889408-B2 |
| Application number | US-201515317903-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 15, 2015 |
| Priority date | Jul 23, 2014 |
| Publication date | Feb 13, 2018 |
| Grant date | Feb 13, 2018 |
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A filter system comprises a hollow fiber membrane filter having pores; and an electrostatic adsorption filter partially or wholly having positive charges to be ion adsorbed with nanoparticles of negative charges by an electrostatic attraction, the nanoparticles which exist in the water, and the electrostatic adsorption filter configured to remove in advance the nanoparticles from the water to be supplied to the hollow fiber membrane filter, to prevent a water passing amount of the hollow fiber membrane filter from being rapidly reduced. According to the present invention, the viruses existing in raw water may be removed in accordance with a size exclusion mechanism of the hollow fiber membrane filter, and the nanoparticles, which cause the reduction of the water passing amount of the hollow fiber membrane filter, may be removed using the electrostatic adsorption filter.
Opening claim text (preview).
The invention claimed is: 1. A filter system comprising: a hollow fiber membrane filter having pores; and an electrostatic adsorption filter partially or wholly having positive charges to be ion adsorbed with nanoparticles of negative charges by an electrostatic attraction, the nanoparticles which exist in water, and the electrostatic adsorption filter configured to remove in advance the nanoparticles from the water to be supplied to the hollow fiber membrane filter, to prevent a water passing amount of the hollow fiber membrane filter from being rapidly reduced, wherein the electrostatic adsorption filter includes: a hollow portion forming a flow path of the water to supply the water having the nanoparticles removed therefrom, to the hollow fiber membrane filter; and an ion adsorption portion formed to surround the hollow portion to allow the water to pass through the ion adsorption portion and flow to the hollow portion, and forming a pleated outer surface around the hollow portion to increase a surface area which is in contact with the water. 2. The filter system of claim 1 , wherein each of the pores is formed at a size smaller than 25 nm to remove viruses of an average size of 25 nm or more from water. 3. The filter system of claim 1 , wherein the ion adsorption portion includes: a non-woven fabric support; glass fibers attached to a surface of the non-woven fabric support; and an ion adsorption material formed on a surface of the glass fibers by grafting, providing positive charges to be ion adsorbed with the nanoparticles of negative charges existing in the water passing through the non-woven fabric support. 4. The filter system of claim 1 , wherein the ion adsorption portion includes: a non-woven fabric support; fibrillate celluloses attached to a surface of the non-woven fabric support; and an ion adsorption material formed on a surface of the celluloses by grafting, providing positive charges to be ion adsorbed with the nanoparticles of negative charges existing in the water passing through the non-woven fabric support. 5. The filter system of claim 3 , wherein the ion adsorption material includes alumina, the alumina being dissociated into a positive ion of AlO + and a negative ion of OH − in the water and providing positive charges required for ion adsorption by using the positive ion of AlO + . 6. The filter system of claim 1 , further comprising a housing for accommodating therein the hollow fiber membrane filter and the electrostatic adsorption filter to form a single module, wherein an inner flow path of the housing includes: a raw water supply flow path for flowing raw water to the electrostatic adsorption filter; a connection flow path connected from the electrostatic adsorption filter to the outer surface of the hollow fiber membrane filter to flow the water having the nanoparticles primarily removed therefrom while passing through the electrostatic adsorption filter, to the hollow fiber membrane filter; and a discharge flow path flowing the water having viruses secondarily removed therefrom while passing through the hollow fiber membrane filter, to the outside of the housing. 7. The filter system of claim 1 , further comprising a first housing for accommodating therein the hollow fiber membrane filter and a second housing for accommodating therein the electrostatic adsorption filter, whereby the hollow fiber membrane filter and the electrostatic adsorption filter are respectively built in their housings. 8. The filter system of claim 1 , further comprising a carbon block filter comprised to remove residual chlorine remaining in the water by allowing the water to pass through a carbon block, wherein the carbon block filter is arranged to purify at least one of water having the nanoparticles removed therefrom while passing through the electrostatic adsorption filter, and water having viruses removed therefrom while passing through the hollow fiber membrane filter. 9. The filter system of claim 8 , wherein the carbon block filter surrounds an outer surface of the carbon block to remove in advance the nanoparticles from the water to be supplied to the carbon block. 10. The filter system of claim 8 , wherein the carbon block filter includes an adsorption material to additionally remove heavy metals or organic compounds, and wherein the adsorption material forms the carbon block filter by being mixed with a raw material of the carbon block together with a binder and by undergoing a compression molding process.
by ion-exchange (ion-exchange in general B01J) · CPC title
Application of an electric field, different from the potential difference across the membrane · CPC title
Heavy metals or heavy metal compounds · CPC title
comprising free carbon; comprising carbon obtained by carbonising processes · CPC title
Separators · CPC title
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