Process for capturing a heavy metal contained in a moist gas, integrating a heat pump to heat the gas introduced into a capture mass

Patent metadata

Field	Value
Publication number	US-9889404-B2
Application number	US-201414908003-A
Country	US
Kind code	B2
Filing date	Jun 17, 2014
Priority date	Jul 31, 2013
Publication date	Feb 13, 2018
Grant date	Feb 13, 2018

Abstract

Capturing at least one heavy metal, from mercury and arsenic, contained in a moist gas comprising water vapor, by the following steps:
a) heating the moist gas by heat exchange with a compressed heat transfer fluid obtained in step e) in order to obtain a condensed heat transfer fluid and a gas reheated to a temperature Tc; b) bringing the reheated gas into contact with a heavy metal capture mass in order to obtain a gas depleted in heavy metal; c) decompressing the cooled heat transfer fluid; d) cooling the gas depleted in heavy metal by heat exchange with the heat transfer fluid produced in step c) in order to obtain a cooled gas at a temperature Tf, the heat transfer fluid being vaporized; e) compressing the vaporized heat transfer fluid in a manner such as to obtain a compressed heat transfer fluid, the compressed heat transfer fluid being recycled.

First claim

The invention claimed is:

1. A process for capturing at least one heavy metal, selected from mercury and arsenic, contained in a moist gas comprising water vapour, in which the following steps are carried out:
extracting a natural gas from an underground deposit; then
introducing the natural gas into a sludge elimination device; then
introducing the natural gas into a gas-liquid separation device; then sending the natural gas to the following step a);
a) heating ( 1001 ) the moist gas by heat exchange with a compressed heat transfer fluid obtained in step e) in order to obtain a condensed heat transfer fluid and a gas reheated to a temperature Tc with a reduced water vapour content;
b) bringing the reheated gas with a reduced water vapour content obtained in step a) into contact with a heavy metal capture mass ( 2000 ) in order to obtain a gas which is depleted in heavy metal, whereby the water vapour content of the moist gas was sufficiently reduced in step a) so that capillary condensation on the heavy metal capture mass is reduced or avoided;
c) decompressing ( 4000 ) the cooled heat transfer fluid obtained in step a);
d) cooling ( 1003 ) the gas depleted in heavy metal by heat exchange with the heat transfer fluid produced in step c) in order to obtain a cooled gas at a temperature Tf, the heat transfer fluid being vaporized during step d); and
e) compressing ( 3000 ) the vaporized heat transfer fluid obtained in step d) in a manner such as to obtain a compressed heat transfer fluid, the compressed heat transfer fluid being recycled to step a) to complete a heat pump circuit;

then, after step e), the following steps are carried out:
eliminating at least a portion of the H 2 S and CO 2 contained in the gas depleted in heavy metal; and then
eliminating at least a portion of the water vapour contained in the gas depleted in heavy metal.

2. The process according to claim 1 in which, before carrying out step a), a heat exchange is carried out between the moist gas and the gas depleted in heavy metal obtained from step b).

3. The process according to claim 1 , in which the temperature Tc is determined in a manner such that the reheated gas with a reduced water vapour content obtained in step a) has a relative humidity of less than 90%.

4. The process according to claim 1 , in which the difference between Tc and Tf is less than 50° C.

5. The process according to claim 1 , in which the capture mass comprises an active phase selected from at least one metallic sulphide based on a metal selected from the group constituted by copper (Cu), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co) and nickel (Ni).

6. The process according to claim 1 , in which the capture mass comprises an active phase composed of elemental sulphur.

7. The process according to claim 1 in which, when the moist gas contains H 2 S, the capture mass comprises an active phase composed of at least one metallic oxide of a metal selected from copper (Cu), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co) and nickel (Ni).

8. The process according to claim 1 , in which the capture mass comprises an active phase composed of at least one metallic oxide of a metal selected from copper (Cu) and lead (Pb).

9. The process according to claim 5 , in which the active phase is distributed over a porous support, the porous support being selected from the group constituted by aluminas, phosphorus-containing aluminas, silica-aluminas, silicas, clays, activated carbons, zeolites, titanium oxides, zirconium oxides and mixtures thereof.

10. The process according claim 1 , in which the heat transfer fluid is selected from hydrocarbons containing 1 to 7 carbon atoms and optionally one or more heteroatomic ligands.

11. The process according to claim 1 , in which at least one of the following operations is carried out:
before carrying out step e), carrying out a supplemental step for heating the vaporised heat transfer fluid obtained in step d);
before carrying out step b), carrying out a supplemental step for further heating the reheated gas obtained in step a);
before carrying out step c), carrying out a supplemental step for further cooling the cooled heat transfer fluid obtained in step a).

12. The process according to claim 11 , in which an exchange of heat of the vaporized heat transfer fluid obtained in step d) with the cooled heat transfer fluid obtained in step a) is carried out.

13. The process according to claim 1 , in which the moist gas is selected from one of the following gases: a natural gas, a shale gas, a coal gas, a synthesis gas, combustion fumes, a gaseous hydrocarbon effluent, chlor-alkali plant exhaust gases, and rare earth production plant exhaust gases.

14. The process according to claim 1 , in which the moist gas is introduced into step a) at a pressure in the range of 2 to 10 MPa, at a temperature in the range of 20° C. to 80° C., and at a relative humidity in the range of 30% to 100%.

15. The process according to claim 1 , in which the moist gas introduced into step a) contains mercury in a proportion of between 10 nanograms and 1 gram of mercury per Nm 3 of the moist gas.

16. The process according to claim 1 , in which, in step a) the heat exchange heats the moist gas by 1° C. to 20° C.

17. The process according to claim 1 , in which the reheated gas with a reduced water vapour content obtained in step a) has a relative humidity of less than 80%.

18. The process according to claim 1 , in which the reheated gas with a reduced water vapour content obtained in step a) has a relative humidity of less than 75%.

Assignees

• Ifp Energies Now

Inventors

• Guillou Florent
• Porcheron Fabien
• Barthelet Karin
• Baudot Arnaud
• Lepine Yann
• Jubin Clotilde

Classifications

• B01J20/06

  comprising oxides or hydroxides of metals not provided for in group B01J20/04 · CPC title

• C10L2290/46

  Compressors or pumps · CPC title

• B01J20/3028

  Granulating, agglomerating or aggregating · CPC title

• B01D2253/1124

  Metal oxides · CPC title

• B01D2251/60

  Inorganic bases or salts · CPC title