Double Network, Trans-free, and Fat-analogous Emulsion Gels for 3D/4D Printing and Preparation Thereof
US-2024415140-A1 · Dec 19, 2024 · US
US9888704B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9888704-B2 |
| Application number | US-201314388935-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 27, 2013 |
| Priority date | Mar 30, 2012 |
| Publication date | Feb 13, 2018 |
| Grant date | Feb 13, 2018 |
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A chocolate having good solidification properties, a high mold releasability and a high crystal stabilization rate, said chocolate being obtained by using an oil or fat composition wherein StOSt and POP triglycerides are contained each in a definite amount or more and StLSt, PLP, StStO and PPO triglycerides are contained each in a definite amount or less. As a result, the productivity of the chocolate can be increased.
Opening claim text (preview).
The invention claimed is: 1. An oil-and-fat composition, comprising 30 to 80 wt % of an oil-and-fat (A) and 20 to 70 wt % of an oil-and-fat (B), wherein the oil-and-fat (A) comprises 70 wt % or more of StOSt and not more than 5 wt % of arachidic acid relative to a constituent fatty acid in the oil-and-fat (A), and the oil-and-fat (B) comprises 60 wt % or more of POP, wherein: the oil-and-fat composition comprises: 80 wt % or more of SOS triglyceride, 25 wt % or more of StOSt, 10 wt % or more of POP, a ratio of StLSt/StOSt of 0.08 or less, a ratio of StStO/StOSt of 0.03 or less, and a ratio of PLP/POP of 0.10 or less, and wherein: S is a saturated fatty acid having C16 to C22, St is stearic acid, P is palmitic acid, L is linoleic acid, O is oleic acid, SOS is a triglyceride in which fatty acids at 1,3-positions are S and fatty acid at 2-position is O, StOSt is a triglyceride in which fatty acids at 1,3-positions are St and fatty acid at 2-position is O, StLSt is a triglyceride in which fatty acids at 1,3-positions are St and fatty acid at 2-position is L, StStO is a triglyceride in which fatty acids at 1,2-positions or 2,3-positions are St and fatty acid at 3-position or 1-position is O, PLP is a triglyceride in which fatty acids at 1,3-positions are P and fatty acid at 2-position is L, and POP is a triglyceride in which fatty acids at 1,3-positions are P and fatty acid at 2-position is O. 2. The oil-and-fat composition according to claim 1 , wherein the oil-and-fat composition comprises: a ratio of PPO/POP of 0.10 or less, and wherein: PPO is a triglyceride in which fatty acids at 1,2-positions or 2,3-positions are P and fatty acid at 3-position or 1-position is O. 3. A tempered chocolate comprising the oil-and-fat composition according to claim 1 . 4. A tempering type cacao butter alternative, comprising the oil-and-fat composition according to claim 1 . 5. A process for reducing aging time in a chocolate, comprising combining the oil-and-fat composition according to claim 1 with at least one ingredient to produce the chocolate. 6. The oil-and-fat composition according to claim 1 , wherein the oil-and-fat composition comprises: 3 wt % or less of SSS, and wherein SSS is a triglyceride in which fatty acids at 1,2,3-positions are S. 7. The oil-and-fat composition according to claim 1 , wherein the oil-and-fat composition comprises 35 to 60 wt % of StOSt. 8. The oil-and-fat composition according to claim 7 , wherein the oil-and-fat composition comprises: a ratio of PPO/POP of 0.10 or less, and wherein: PPO is a triglyceride in which fatty acids at 1,2-positions or 2,3-positions are P and fatty acid at 3-position or 1-position is O. 9. The oil-and-fat composition according to claim 8 , wherein the oil-and-fat (A) comprises not more than 1.3 wt % of arachidic acid relative to a constituent fatty acid in the oil-and-fat (A). 10. A process for producing an oil-and-fat composition, comprising mixing 30 to 80 wt % of an oil-and-fat (A) and 20 to 70 wt % of an oil-and-fat (B), wherein the oil-and-fat (A) comprises 70 wt % or more of StOSt and not more than 5 wt % of arachidic acid relative to a constituent fatty acid in the oil-and-fat (A), and the oil-and-fat (B) comprises 60 wt % or more of POP, wherein: the oil-and-fat composition comprises: 80 wt % or more of SOS triglyceride, 25 wt % or more of StOSt, 10 wt % or more of POP, a ratio of StLSt/StOSt of 0.08 or less, a ratio of StStO/StOSt of 0.03 or less, and a ratio of PLP/POP of 0.10 or less, and wherein: S is a saturated fatty acid having C16 to C22, St is stearic acid, P is palmitic acid, L is linoleic acid, O is oleic acid, SOS is a triglyceride in which fatty acids at 1,3-positions are S and fatty acid at 2-position is O, StOSt is a triglyceride in which fatty acids at 1,3-positions are St and fatty acid at 2-position is O, StLSt is a triglyceride in which fatty acids at 1,3-positions are St and fatty acid at 2-position is L, StStO is a triglyceride in which fatty acids at 1,2-positions or 2,3-positions are St and fatty acid at 3-position or 1-position is O, PLP is a triglyceride in which fatty acids at 1,3-positions are P and fatty acid at 2-position is L, and POP is a triglyceride in which fatty acids at 1,3-positions are P and fatty acid at 2-position is O. 11. The process according to claim 10 , further comprising: preparing the oil-and-fat (A) by a method comprising: preparing an interesterified oil by subjecting high-oleic plant oil comprising 80 wt % or more of oleic acid relative to a constituent fatty acid in the high-oleic plant oil, and stearic acid or stearic acid alcohol ester to interesterification with 1,3-position-specific lipase, and fractionating the interesterified oil by solvent fractionation or dry fractionation and recovering a high melting point fraction or a mid fraction as the oil-and-fat (A). 12. The process according to claim 10 , further comprising: preparing the oil-and-fat (B) by a method comprising: fractionating a palm oil by solvent fractionation or dry fractionation and recovering a high melting point fraction or a mid fraction as the oil-and-fat (B). 13. The process according to claim 12 , further comprising: preparing the oil-and-fat (B) by a method comprising: fractionating a palm oil by solvent fractionation or dry fractionation and recovering the high melting point fraction or the mid fraction as the oil-and-fat (B). 14. The process according to claim 13 , wherein the oil-and-fat composition comprises 35 to 60 wt % of StOSt. 15. The process according to claim 14 , wherein the oil-and-fat composition comprises: a ratio of PPO/POP in the oil-and-fat composition of 0.10 or less, and wherein: PPO is a triglyceride in which fatty acids at 1,2-positions or 2,3-positions are P and fatty acid at 3-position or 1-position is O. 16. The process according to claim 15 , wherein the oil-and-fat (A) comprises not more than 1.3 wt % of arachidic acid relative to the constituent fatty acid in the oil-and-fat (A). 17. A process for reducing aging time in a chocolate, comprising combining the oil-and-fat composition obtained by the process according to claim 16 with at least one ingredient to produce the chocolate.
Cocoa butter substitutes · CPC title
by differences of melting or solidifying points · CPC title
Ester interchange · CPC title
with fatty acids · CPC title
Food compositions, function of food ingredients or processes for food or foodstuffs · CPC title
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