Anode for lithium metal battery, and electrochemical device comprising same
US-12176528-B2 · Dec 24, 2024 · US
US9887400B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9887400-B2 |
| Application number | US-41872509-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 6, 2009 |
| Priority date | Jun 16, 2008 |
| Publication date | Feb 6, 2018 |
| Grant date | Feb 6, 2018 |
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A secondary battery is disclosed. In one embodiment, the secondary battery includes i) an electrode assembly comprising upper and lower surfaces opposing each other, ii) a container configured to receive the electrode assembly via an opening defined at one end thereof, iii) a cap assembly configured to close the opening of the container, wherein an electrolyte injection hole is defined in the cap assembly, and wherein the electrolyte injection hole is configured to receive electrolyte and iv) an insulation case configured to be received by the container and being interposed between the cap assembly and the electrode assembly, wherein a first electrolyte permeation passage is formed between an outer surface of the insulation case and an inner surface of the container, and wherein the first electrolyte permeation passage is configured to expedite the permeation of the received electrolyte into the lower surface of the electrode assembly.
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What is claimed is: 1. A secondary battery, comprising: an etectrode assembly; a can configured to receive the electrode assembly via an opening defined at one end thereof; a cap assembly configured to seal the opening of the can; and an insulation case configured to be received in the can and being interposed between the cap assembly and the electrode assembly, wherein a separating space is formed between an outer surface of the insulation case and an inner surface of the can, wherein the insulation case comprises: a seating plate seated on an upper surface of the electrode assembly, wherein the seating plate has a pair of long sides opposing each other and a pair of short sides opposing each other; a side wall extending from the seating plate toward the cap assembly, wherein the side wall comprises a first side wall surrounding one of the short sides of the seating plate and extending to the long sides, and a second side wall surrounding the other short side of the seating plate and extending to the long sides, wherein the first and second side walls are spaced apart from each other such that the side wall is discontinuously formed, wherein the side wall further comprises a third side wall formed between and spaced apart from the first and second side walls, wherein the third side wall is formed in one of the long sides, and wherein at least a portion of the third side wall faces no side wall in a direction perpendicularly extending from one of the long sides to the other long side; and a projection extending from the side wall toward an inner surface of the can, wherein the projection comprises at least one first sub-projection extending from the first side wall and at least one second sub-projection extending from the second side wall. 2. The secondary battery of claim 1 , wherein the separating space is defined by i) the sub-projections, ii) the outer surface of the insulation case and iii) the inner surface of the can. 3. The secondary battery of claim 1 , wherein the height of at least one of the first and second sub-projections is substantially the same as that of at least one of the first and second side walls. 4. The secondary battery of claim 1 , wherein the lengths of the sub-projections are substantially the same as each other. 5. The secondary battery of claim 1 , wherein the sub-projections are formed on at least four corners of the outer surface of the insulation case so as to allow the insulation case to be fitted in the can. 6. The secondary battery of claim 1 , wherein the length of the sub-projections is about 10% to about 70% of an average thickness of the insulation case. 7. The secondary battery of claim 1 , wherein the sub-projections are positioned within a region corresponding to about 5% to about 60% of a circumference length of the insulation case. 8. The secondary battery of claim 1 , wherein an electrolyte passing region is formed outside the insulation case. 9. The secondary battery of claim 1 , further comprising: an electrolyte injection hole formed in the cap assembly and configured to receive electrolyte; a first electrolyte opening formed in the seating plate of the insulation case and configured to pass the electrolyte therethrough such that the electrolyte flows toward a first portion of the electrode assembly; and a second electrolyte opening formed in the seating plate of the insulation case and configured to pass the electrolyte therethrough such that the electrolyte flows toward a second portion of the electrode assembly, wherein the first portion is different in location from the second portion, and wherein the first and second electrolyte openings are separate from each other. 10. The secondary battery of claim 1 , further comprising an additional projection formed on the third side wall. 11. A secondary battery, comprising: an electrode assembly comprising upper and lower surfaces opposing each other; a container configured to receive the electrode assembly via an opening defined at one end thereof; a cap assembly configured to close the opening of the container, wherein an electrolyte injection hole is defined in the cap assembly, and wherein the electrolyte injection hole is configured to receive electrolyte; and an insulation case configured to be received by the container and being interposed between the cap assembly and the electrode assembly, wherein a first electrolyte permeation passage is formed between an outer surface of the insulation case and an inner surface of the container, and wherein the first electrolyte permeation passage is configured to expedite the permeation of the received electrolyte into the lower surface of the electrode assembly, wherein the insulation case comprises: a seating plate seated on an upper surface of the electrode assembly, wherein the seating plate has a pair of long sides opposing each other and a pair of short sides opposing each other; a side wall extending from the seating plate toward the cap assembly, wherein the side wall comprises a first side wall surrounding one of the short sides of the seating plate and extending to the long sides, and a second side wall surrounding the other short side of the seating plate and extending to the long sides, wherein the first and second side walls are spaced apart from each other such that the side wall is discontinuously formed, wherein the side wall further comprises a third side wall formed between and spaced apart from the first and second side walls, wherein the third side wall is formed in one of the long sides, and wherein at least a portion of the third side wall faces no side wall in a direction perpendicularly extending from one of the long sides to the other long side; and at least one projection which extends from the side wall toward an inner surface of the container, wherein the projection comprises at least one first sub-projection extending from the first side wall and at least one second sub-projection extending from the second side wall. 12. The secondary battery of claim 11 , wherein the first electrolyte permeation passage is defined by i) the sub-projections, ii) the inner surface of the container and iii) the outer surface of the insulation case. 13. The secondary battery of claim 11 , wherein a cross-section of the at least one of the sub-projections is one of the following: rectangular, triangular, semicircular and trapezoidal. 14. The secondary battery of claim 11 , wherein a second electrolyte permeation passage is formed in the insulation case, and wherein the second electrolyte permeation passage is configured to expedite the permeation of the received electrolyte into the upper surface of the electrode assembly. 15. The secondary battery of claim 11 , further comprising: an electrolyte injection hole formed in the cap assembly and configured to receive electrolyte; a first electrolyte passing opening formed in the seating plate of the insulation case and configured to pass the electrolyte therethrough such that the electrolyte flows toward a first portion of the electrode assembly; and a second electrolyte passing opening formed in the seating plate of the insulation case and configured to pass the electrolyte therethrough such that the electrolyte flows toward a second portion of the electrode assembly, wherein the first portion is different in location from the second portion, and wherein the first and second electrolyte openings are separate from each other. 16. The secondary battery of claim 11 , wherein the height of at least one of the first and second sub-projections is substantially the same as that of at leas
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