Quantum dots, method, and devices

Patent metadata

Field	Value
Publication number	US-9887316-B2
Application number	US-201314041618-A
Country	US
Kind code	B2
Filing date	Sep 30, 2013
Priority date	Apr 1, 2011
Publication date	Feb 6, 2018
Grant date	Feb 6, 2018

Abstract

A quantum dot including a fluorine-containing ligand attached to a surface thereof and having a coating comprising a fluoropolymer over at least a portion of the outer surface of the quantum dot. A method for preparing a quantum dot with a coating comprising a fluoropolymer over at least a portion of the outer surface of the quantum dot is also disclosed. The method comprises contacting a quantum dot having a fluorine-containing ligand attached to a surface thereof with a fluoropolymer to coat the fluoropolymer over at least a portion of the outer surface of the quantum dot. A device including the quantum dot taught herein is further disclosed. An emissive material including the quantum dot taught herein is further disclosed.

First claim

What is claimed is:

1. A quantum dot including a fluorine-containing ligand attached to a surface thereof and further including a coating comprising a fluoropolymer that surrounds the outer surface of the quantum dot and the fluorine-containing ligand attached to the surface thereof,
wherein the fluoropolymer comprises a first functional group on the inner surface of the coating, wherein the first functional group comprises an aliphatic moiety comprising a main chain including at least 2 carbon atoms and one or more fluorine atoms, and wherein the first functional group is associated with the fluorine-containing ligand attached to the surface of the quantum dot,
wherein the fluoropolymer further comprises a plurality of non-fluorine containing functional groups on an outer surface of the coating, and
wherein the coating comprising the fluoropolymer has a thickness less than or equal to 100 nm.

2. A quantum dot in accordance with claim 1 wherein the fluoropolymer further includes one or more additional functional groups.

3. A quantum dot in accordance with claim 2 wherein an additional functional group comprises a hydroxyl group.

4. A quantum dot in accordance with claim 1 wherein the coating comprising the fluoropolymer functions as an electronic insulating layer around the quantum dot.

5. A quantum dot in accordance with claim 1 wherein the coating comprising the fluoropolymer allows energy transfer as the mode of quantum dot excitation.

6. A quantum dot in accordance with claim 1 further comprising one or more additional functional groups on the outer surface of the coating comprising the fluoropolymer, wherein at least one of the additional functional groups is selected to provide the coated quantum dot with predetermined properties.

7. A quantum dot in accordance with claim 1 further comprising one or more additional functional groups on the outer surface of the coating comprising the fluoropolymer, wherein at least one of the additional functional groups is selected to provide the coated quantum dot with hydrophilic characteristics.

8. A quantum dot in accordance with claim 1 further comprising one or more additional functional groups on the outer surface of the coating comprising the fluoropolymer, wherein at least one of the additional functional groups is selected to provide the coated quantum dot with hydrophobic characteristics.

9. A device comprising a pair of electrodes and including a layer therebetween, the layer comprising a quantum dot including a fluorine-containing ligand attached to a surface thereof and further including a coating comprising a fluoropolymer that surrounds the outer surface of the quantum dot and the fluorine-containing ligand attached to the surface thereof,
wherein the fluoropolymer comprises a first functional group on the inner surface of the coating, wherein the first functional group comprises an aliphatic moiety comprising a main chain including at least 2 carbon atoms and one or more fluorine atoms, and wherein the first functional group is associated with the fluorine-containing ligand attached to the surface of the quantum dot,
wherein the fluoropolymer further comprises a plurality of non-fluorine containing functional groups on an outer surface of the coating, and
wherein the coating comprising the fluoropolymer has a thickness less than or equal to 100 nm.

10. A device in accordance with claim 9 further including a protective coating over a surface of the device opposite a substrate on which the device is supported.

11. A light-emitting device comprising a pair of electrodes and including a layer therebetween, the layer comprising an emissive material comprising a quantum dot including a fluorine-containing ligand attached to a surface thereof and further including a coating comprising a fluoropolymer that surrounds the outer surface of the quantum dot and the fluorine-containing ligand attached to the surface thereof,
wherein the fluoropolymer comprises a first functional group on the inner surface of the coating, wherein the first functional group comprises an aliphatic moiety comprising a main chain including at least 2 carbon atoms and one or more fluorine atoms, and wherein the first functional group is associated with the fluorine-containing ligand attached to the surface of the quantum dot,
wherein the fluoropolymer further comprises a plurality of non-fluorine containing functional groups on an outer surface of the coating, and
wherein the coating comprising the fluoropolymer has a thickness less than or equal to 100 nm.

12. A light-emitting device in accordance with claim 11 further including a protective coating over a surface of the device opposite a substrate on which the device is supported.

13. An emissive material comprising a quantum dot in accordance with claim 1 .

14. A quantum dot in accordance with claim 1 wherein the fluoropolymer further includes one or more additional functional groups.

15. A quantum dot in accordance with claim 1 wherein an outer portion of the fluoropolymer is functionalized with a group that has energy transferring properties.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Breen Craig
• Steckel Jonathan S

Classifications

• C09K2211/14

  Macromolecular compounds · CPC title

• C09K11/08

  containing inorganic luminescent materials · CPC title

• C09K11/025

  non-luminescent particle coatings or suspension media · CPC title

• C09K11/06 Primary

  containing organic luminescent materials · CPC title

• H01L33/04 Primary

  Electricity · mapped topic