Ethylene/alpha-olefin interpolymer composition

Patent metadata

Field	Value
Publication number	US-9884929-B2
Application number	US-201414888018-A
Country	US
Kind code	B2
Filing date	Apr 29, 2014
Priority date	Apr 30, 2013
Publication date	Feb 6, 2018
Grant date	Feb 6, 2018

Abstract

An ethylene/alpha-olefin interpolymer composition suitable for pipe applications prepared via solution polymerization process, and pipes made therefrom. The ethylene/alpha-olefin interpolymer composition suitable for pipe applications according to the present invention comprises greater than 80 percent by weight of units derived from ethylene and 20 percent or less by weight of units derived from one or more alpha olefin co-monomers, wherein said ethylene/alpha-olefin interpolymer has a density in the range of from 0.925 to 0.935 g/cm 3 , a melt index I 2 in the range of from 0.3 to 1.0 g/10 minutes, a melt flow ratio I 10 /I 2 in the range of from 7.9 to 11, a melt strength in the range of from 3 to 10 cN, a DSC heat curve having a melting peak temperature in the range of from 120 to 130° C., a crystallinity in the range of from 50 to 70 percent, a 1% flexural modulus in the range from 350 to 600 MPa, and a zero shear viscosity ratio (ZSVR) in the range of from 2 to 10.

First claim

The invention claimed is:

1. An ethylene/alpha-olefin interpolymer composition suitable for pipe applications prepared via solution polymerization process comprising greater than 80 percent by weight of units derived from ethylene and 20 percent or less by weight of units derived from one or more alpha olefin co-monomers, wherein said ethylene/alpha-olefin interpolymer has a density in the range of from 0.925 to 0.935 g/cm 3 , a melt index I 2 in the range of from 0.3 to 1.0 g/10 minutes, a melt flow ratio I 10 /I 2 in the range of from 7.9 to 11, a melt strength in the range of from 3 to 10 cN, a DSC heat curve having a melting peak temperature in the range of from 120 to 130° C., a crystallinity in the range of from 50 to 70 percent, a 1% flexural modulus in the range from 350 to 600 MPa, and a zero shear viscosity ratio (ZSVR) in the range of from 2 to 10.

2. The ethylene/alpha-olefin interpolymer composition suitable for pipe applications according to claim 1 , wherein said ethylene/alpha-olefin interpolymer composition further comprises one or more additives.

3. A pipe comprising the ethylene/alpha-olefin interpolymer composition according to claim 1 .

4. The pipe of claim 3 , wherein the pipe is a monolayer pipe.

5. The pipe of claim 3 , wherein said ethylene/alpha-olefin interpolymer composition has a time to failure at 95° C. and 3.4 MPa of at least 1000 h determined according to ISO 1167.

Assignees

• Dow Global Technologies Llc

Inventors

• Wang Jian
• Demirors Mehmet
• Bastero Amaia

Classifications

• C08F2500/02

  Low molecular weight, e.g. <100,000 Da. · CPC title

• C08F4/65908

  in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+ · CPC title

• C08F4/642

  Component covered by group C08F4/64 with an organo-aluminium compound {(C08F4/64003 - C08F4/64196 take precedence)} · CPC title

• C08K5/24

  Derivatives of hydrazine · CPC title

• C08F2420/02

  Cp or analog bridged to a non-Cp X anionic donor · CPC title