Ferrous phosphate powders, lithium iron phosphate powders for li-ion battery, and methods for manufacturing the same

Patent metadata

Field	Value
Publication number	US-9884765-B2
Application number	US-201514705618-A
Country	US
Kind code	B2
Filing date	May 6, 2015
Priority date	Jun 17, 2011
Publication date	Feb 6, 2018
Grant date	Feb 6, 2018

Abstract

Ferrous (II) phosphate (Fe 3 (PO 4 ) 2 ) powders, lithium iron phosphate (LiFePO 4 ) powders for a Li-ion battery and methods for manufacturing the same are provided. The lithium iron phosphate powders are represented by the following formula (II):

LiFe (1-a) M a PO 4   (II)

wherein, M, and a are defined in the specification, the lithium iron phosphate powders are composed of plural flake powders, the length of each of the flake powders is 0.1-10 μm, and a ratio of the length and the thickness of each of the flake powder is in a range from 11 to 400.

First claim

What is claimed is:

1. A method for manufacturing ferrous phosphate (II) powders, sequentially comprising the following steps:
(A) providing a P-containing precursor solution, wherein the P-containing precursor solution comprises: a P-containing precursor;
(B) adding a weakly alkaline compound into the P-containing precursor solution to obtain a mixture; and
(C) adding a ferrous (II) compound into the mixture to obtain ferrous (II) phosphate powders;
wherein the ferrous (II) phosphate powders are represented by the following formula (I):
Fe (3-x) M x (PO 4 ) 2 .yH 2 O  (I)

wherein M comprises at least one metal selected from the group consisting of Mn, Cr, Co, Cu, Ni, V, Mo, Ti, Zn, Zr, Tc, Ru, Rh, Pd, Ag, Cd, Pt, Au, Al, Ga, In, Be, Mg, Ca, Sr, B, and Nm, 0≦x<1.5, y is an integral of 0 to 8, the ferrous (II) phosphate powders are composed of plural flake powders, the length of each of the flake powder is 0.2-10 μm, the ratio of the length and thickness of each of the flake powder is in a range of 14 to 500.

2. The method as claimed in claim 1 , wherein at least one metal-containing compound is further added into the mixture to obtain a doped ferrous (II) phosphate powders in step (C).

3. The method as claimed in claim 2 , wherein the molar ratio of the metal-containing compound to the ferrous compound is 1:1 to 1:99999.

4. The method as claimed in claim 3 , wherein the molar ratio of the metal-containing compound to the ferrous compound is 1:2 to 1:9999.

5. The method as claimed in claim 1 , wherein the P-containing precursor is at least one selected from the group consisting of H 3 PO 4 , NaH 2 PO 4 , Na 2 HPO 4 , Mg 3 (PO 4 ) 2 , and NH 4 H 2 PO 4 .

6. The method as claimed in claim 1 , wherein the weakly alkaline compound is at least one selected from the group consisting of Na 2 CO 3 , and NaHCO 3 .

7. The method as claimed in claim 1 , wherein the ferrous compound is at least one selected from the group consisting of FeCl 2 , FeBr 2 , FeI 2 , FeSO 4 , (NH 4 ) 2 Fe(SO 4 ) 2 , Fe(NO 3 ) 2 , O 3 ) 2 , FeC 2 O 4 , (CH 3 COO) 2 Fe, and FeCO 3 .

8. The method as claimed in claim 2 , wherein the metal-containing compound is sulfates, carbonates, nitrates, oxalates, acetates, chlorites, bromides, or iodides of Mn, Cr, Co, Cu, Ni, V, Mo, Ti, Zn, Zr, Tc, Ru, Rh, Pd, Ag, Cd, Pt, Au, Al, Ga, In, Be, Mg, Ca, Sr, B, or Nb.

9. The method as claimed in claim 8 , wherein the metal-containing compound is sulfates of Mn, Cr, Co, Cu, Ni, Zn, Al, or Mg.

10. The method as claimed in claim 1 , further comprising a step (C1) after the step (C): washing the ferrous (II) phosphate powders.

11. The method as claimed in claim 10 , wherein the ferrous (II) phosphate powders is washed with ethanol, water, or a combination thereof.

12. The method as claimed in claim 10 , further comprising a step (C2) after the step (C1): drying the obtained ferrous (II) phosphate powders.

13. The method as claimed in claim 12 , wherein the ferrous (II) phosphate powders are dried at 40-120° C. for 5-100 hours.

14. The method as claimed in claim 1 , wherein the thickness of each of the flake powder is 1-50 nm.

15. The method as claimed in claim 1 , wherein the flake powders are powders composed of independent flakes, flake powders that one end of each of the flake powders connects to each other, flake powders connecting to each other at the center of the flakes, or flake powders that one end of each of the flake powders connects to each other to form a connecting center.

16. The method as claimed in claim 1 , wherein the ferrous (II) phosphate powders are crystallized ferrous (II) phosphate powders.

17. The method as claimed in claim 16 , wherein the ferrous (II) phosphate powders show an X-ray diffraction pattern 2θ angles (°) having characteristic peaks at about 18.32, 19.84, 23.24, 28.24, 30.32, 33.34, 35.88, 37.20, 39.36, 40.94, and 41.82.

18. The method as claimed in claim 17 , wherein the ferrous (II) phosphate powders show an X-ray diffraction pattern 2θ angles (°) having further characteristic peaks at about 20.72, 22.12, 24.86, 27.08, 34.3, and 44.14.

19. The method as claimed in claim 1 , wherein the ferrous (II) phosphate powders have a crystallization degree of more than 10%.

Assignees

• Univ Nat Tsing Hua

Inventors

• Chou Lih Hsin
• Chen Bing Kai
• Chu Hsin Hsu
• Yang Yueh Ting

Classifications

• C01B25/375

  of iron · CPC title

• H01B1/06

  mainly consisting of other non-metallic substances · CPC title

• Y10T428/2982

  Particulate matter [e.g., sphere, flake, etc.] · CPC title

• C01B25/45 Primary

  containing plural metal, or metal and ammonium · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title