Mo—Si—B-based alloy powder, metal-material raw material powder, and method of manufacturing a Mo—Si—B-based alloy powder

Patent metadata

Field	Value
Publication number	US-9884367-B2
Application number	US-201214368976-A
Country	US
Kind code	B2
Filing date	Dec 21, 2012
Priority date	Dec 28, 2011
Publication date	Feb 6, 2018
Grant date	Feb 6, 2018

Abstract

A Mo—Si—B-based alloy for a heat-resistant alloy that satisfies, more than conventional, physical properties such as proof stress and hardness adapted to an increase in the melting point of 5 a welding object. The Mo—Si—B-based alloy powder is such that the full width at half maximum of (600) of Mo5SiB2 in X-ray diffraction peak data is 0.08 degrees or more and 0.7 degrees or less.

First claim

The invention claimed is:

1. A Mo—Si—B-based alloy powder comprising:
Mo 5 SiB 2 ,
oxygen in a content of 200 mass ppm or more and 45000 mass ppm or less,
carbon in a content of 50 mass ppm or more and 1000 mass ppm or less,
an inevitable compound, and
an inevitable impurity,
wherein a full width at half maximum of a (600) peak of the Mo 5 SiB 2 in X-ray diffraction is 0.08 degrees or more and 0.7 degrees or less, and
wherein the Mo 5 SiB 2 is a main component.

2. The Mo—Si—B-based alloy powder according to claim 1 , wherein the Si content is 4.2 mass % or more and 5.9 mass % or less, the B content is 3.5 mass % or more and 4.5 mass % or less, and the balance is Mo and an inevitable impurity.

3. The Mo—Si—B-based alloy powder according to claim 1 , wherein a specific surface area measured by a BET method is 0.05 m 2 /g or more and 1.0 m 2 /g or less.

4. The Mo—Si—B-based alloy powder according to claim 1 , wherein a (204) peak intensity of the Mo 5 SiB 2 is higher than a (114) peak intensity of the Mo 5 SiB 2 in the X-ray diffraction.

5. The Mo—Si—B-based alloy powder according to claim 1 , wherein the oxygen content is 840 mass ppm or more and 21600 mass ppm or less and the carbon content is 80 mass ppm or more and 220 mass ppm or less.

6. A metal-material raw material powder being a mixed powder comprising the Mo—Si—B-based alloy powder according to claim 1 and a powder of at least one or more kinds selected from the group consisting of Group IVA, VA, and VIA elements.

7. The metal-material raw material powder according to claim 6 , wherein the powder selected from the group consisting of the Group IVA, VA, and VIA elements is a powder of at least one or more kinds of Mo, W, Ta, Nb, and Hf.

8. A Mo—Si—B-based alloy powder comprising:
Mo 5 SiB 2 ,
wherein a full width at half maximum of a (600) peak of the Mo 5 SiB 2 in X-ray diffraction is 0.08 degrees or more and 0.7 degrees or less, and
wherein the Mo 5 SiB 2 is a main component.

9. A method of manufacturing the Mo—Si—B-based alloy powder according to claim 1 , comprising:
a mixing step of using a Mo powder, a MoSi 2 powder, and a MoB powder as raw materials and mixing them in a predetermined mixing ratio;
a heat treatment step of heat-treating a mixed powder, obtained by the mixing step, at 1350° C. or more and 1750° C. or less in an atmosphere containing hydrogen or an inert gas;
a disintegration treatment step of disintegrating a powder obtained by the heat treatment step; and
a step of sieving a powder obtained by the disintegration treatment step.

10. The Mo—Si—B-based alloy powder manufacturing method according to claim 9 , comprising a pre-reduction step of, prior to the mixing step, heat-treating in advance the MoB powder at 900° C. or more and 1300° C. or less in a hydrogen atmosphere.

Assignees

• Almt Corp

Inventors

• Yamazaki Shigekazu
• Tsuji Ayuri
• Katoh Masahiro
• Nakabayashi Seiji
• Ikegaya Akihiko

Classifications

• C22C1/045

  Alloys based on refractory metals · CPC title

• B22F1/00

  Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties · CPC title

• B22F1/0085

  Operations & Transport · mapped topic

• C22C1/1084

  by mechanical alloying (blending, milling) · CPC title

• C22C27/04 Primary

  Alloys based on tungsten or molybdenum · CPC title