Method for producing a lithium microbattery

Patent metadata

Field	Value
Publication number	US-9882183-B2
Application number	US-201415022450-A
Country	US
Kind code	B2
Filing date	Sep 16, 2014
Priority date	Sep 16, 2013
Publication date	Jan 30, 2018
Grant date	Jan 30, 2018

Abstract

The fabrication method of a lithium microbattery provides for use of a substrate successively covered by: a cathode, a solid electrolyte, and a first electrically conducting layer made from a material configured to combine with the lithium atoms. The first layer is devoid of contact with the cathode. The method further includes formation of a second electrically conducting layer configured to form a diffusion barrier for the lithium atoms. The second layer is electrically connected to the first layer and leaves at least a part of the first layer uncovered, the part being facing the electrolyte. Electrochemical deposition of a lithium anode is then performed from germination from the first and second electrically conducting layers.

First claim

The invention claimed is:

1. A fabrication method of a lithium microbattery, comprising the following successive steps:
providing a substrate successively covered, and in order, by:
a cathode;
a solid electrolyte;
a first electrically conducting layer made from a first material, the first layer being devoid of contact with the cathode;

forming a second electrically conducting layer configured to form a diffusion barrier for the lithium atoms, the second electrically conducting layer being electrically connected to the first layer and leaving at least an uncovered part of the first layer, said uncovered part being facing the electrolyte;
electrochemically depositing a lithium anode from germination from the first electrically conducting layer and the second electrically conducting layer so as to form with the first electrically conducting layer a film comprising lithium and the first material.

2. The method according to claim 1 , wherein the first material is chosen such that the film comprising lithium and the first material forms the interface between the solid electrolyte and the lithium anode.

3. The method according to claim 1 , wherein the film comprising lithium and the first material is made from an alloy formed by lithium and atoms of the first material.

4. The method according to claim 1 , comprising a formation step of a first hermetic and electrically insulating encapsulation layer on a portion of the second electrically conducting layer so as to prevent electrochemical deposition.

5. The method according to claim 1 , wherein the solid electrolyte is provided with lateral flanks connected by a surface opposite to the substrate, and wherein the first electrically conducting layer is arranged on the substrate and on the solid electrolyte so as to cover in continuous manner said lateral flanks and said surface joining the lateral flanks.

6. The method according to claim 1 , wherein a second hermetic and electrically insulating encapsulation layer coats the anode and the solid electrolyte.

7. The method according to claim 1 , the second electrically conducting layer covers a portion of the first electrically conducting layer arranged on the substrate.

8. The method according to claim 1 , wherein the first electrically conducting layer is made from a material from the list comprising Sn, Al, Au and Pt, doped silicon, and doped germanium.

9. The method according to claim 1 , wherein the second electrically conducting layer is made from a material from the list comprising Ti, Ni, W, Cr and Mo.

10. The method according to claim 1 , wherein the lithium anode has a thickness greater than twice the thickness of the first layer.

11. The method according to claim 1 , wherein the thickness of the lithium anode and the thickness of the first electrically conducting layer are chosen such that the first electrically conducting material is consumed to form the film separating the solid electrolyte and the lithium anode.

Assignees

• Commissariat à l'Energie Atomique et aux Energies Alternatives

Inventors

• Oukassi Sami
• SALOT Raphaël
• Martin Steve

Classifications

• H01M4/045 Primary

  Electrochemical coating; Electrochemical impregnation · CPC title

• H01M50/117

  Inorganic material · CPC title

• H01M2/0277

  Electricity · mapped topic

• H01M4/70

  characterised by shape or form · CPC title

• H01M4/667

  in the form of layers, e.g. coatings · CPC title