Nematic liquid crystal composition, liquid crystal display element using same

Patent metadata

Field	Value
Publication number	US-9879181-B2
Application number	US-201414517077-A
Country	US
Kind code	B2
Filing date	Oct 17, 2014
Priority date	Apr 6, 2011
Publication date	Jan 30, 2018
Grant date	Jan 30, 2018

Abstract

A nematic liquid crystal composition according to the invention is used for a liquid crystal display element for an active matrix drive for TV applications or the like for which a high speed and a wide viewing angle are required. The liquid crystal composition has a negative dielectric anisotropy having a large absolute value and also has a sufficiently low viscosity. Therefore, the liquid crystal composition has excellent characteristic properties, that is, a high speed response, good display quality and a suppressed display defect, and is therefore suitable as a practical liquid crystal composition. Further, a liquid crystal display element produced using the liquid crystal composition can be used favorably as a liquid crystal display element of a VA type or the like.

First claim

The invention claimed is:

1. A liquid crystal composition, comprising:
as a first component, a compound-represented by formula (I) with a content of 5% to 25%,

as a second component, one or more compounds selected from a group of compounds represented by both formulas (II-1) and (II-2):

wherein, R 1 and R 2 each independently represent an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, or an alkenyloxy group having 2 to 10 carbon atoms, one —CH 2 — or two or more non-adjacent —CH 2 — present in R 1 and R 2 may be each independently substituted with —O— and/or —S—, one, or two or more hydrogen atoms present in R 1 and R 2 may be each independently substituted with a fluorine atom or a chlorine atom, and
wherein ring A and ring B each independently represent a trans-1,4-cyclohexylene group, a 1,4-phenylene group, a 2-fluoro-1,4-phenylene group, a 3-fluoro-1,4-phenylene group, a 3,5-difluoro-1,4-phenylene group, a 2,3-difluoro-1,4-phenylene group, a 1,4-cyclohexenylene group, a 1,4-bicyclo[2.2.2]octylene group, a piperidine-1,4-diyl group, a naphthalene-2,6-diyl group, a decahydronaphthalene-2,6-diyl group, or a 1,2,3,4-tetrahydronaphthalene-2,6-diyl group, except ring B cannot be the trans-1,4-cyclohexylene group or the 1,4-cyclohexenylene group, and p represents 0, 1, or 2, and q represents 1 or 2, the second component having a negative dielectric anisotropy (Δ∈) with an absolute value of greater than 3,
as a third component, one or more compounds selected from a group of compounds represented by formula (III-G) to formula (III-H):

wherein, R 5 represents an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 2 to 5 carbon atoms and R 6 represents an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkenyloxy group having 2 to 5 carbon atoms; and
wherein the second component is included at a content of 20% to 80% by mass.

2. The liquid crystal composition according to claim 1 , wherein Δ∈ at 25° C. is in a range of −2.0 to −6.0, a refractive index anisotropy (Δn) at 25° C. is in a range of 0.08 to 0.13, viscosity (η) at 20° C. is in a range of 10 to 30 mPa·s, and a nematic phase-isotropic liquid phase transition temperature (T ni ) is in a range of 60° C. to 120° C.

3. The liquid crystal composition according to claim 1 , wherein a content of the second component is 40% to 70% by mass.

4. The liquid crystal composition according to any one of claims 1 , 2 and 3 comprising: as the second component, a group of compounds comprising at least one formulation of each of formulas (II-1A), (II-1B) and (II-2A):

wherein R 3 and R 4 each independently represent an alkyl group having 1 to 10 carbon atoms or an alkenyl group having 2 to 10 carbon atoms, and one or two or more hydrogen atoms present in R 3 and R 4 may be each independently substituted with a fluorine atom.

5. The liquid crystal composition according to claim 1 further comprising: one or more compounds selected from a group of compounds represented by formulae (III-A) to (III-E) and (III-I) to (III-J):

wherein, R 5 represents an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 2 to 5 carbon atoms and R 6 represents an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkenyloxy group having 2 to 5 carbon atoms, with the proviso that, cases in which R 5 is a methyl group and R 6 is a propyl group, and in which R 5 is a propyl group and R 6 is a methyl group in formula (III-F) are excluded.

6. The liquid crystal composition according to claim 4 , simultaneously comprising formula (I), formulas (II-1A), (II-2A), and formula (III-A):

wherein, R 5 represents an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 2 to 5 carbon atoms and R 6 represents an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkenyloxy group having 2 to 5 carbon atoms, with the proviso that, cases in which R 5 is a methyl group and R 6 is a propyl group are excluded.

7. The liquid crystal composition according to claim 4 , simultaneously comprising formula (I), formulas (II-1B), (II-2A), and formula (III-A):

wherein, R 5 represents an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 2 to 5 carbon atoms and R 6 represents an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkenyloxy group having 2 to 5 carbon atoms, with the proviso that, cases in which R 5 is a methyl group and R 6 is a propyl group are excluded.

8. The liquid crystal composition according to claim 4 , simultaneously comprising formula (I), formulas (II-1A), (II-1B), (II-2A), and formula (III-A):

wherein, R 5 represents an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 2 to 5 carbon atoms and R 6 represents an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkenyloxy group having 2 to 5 carbon atoms, with the proviso that, cases in which R 5 is a methyl group and R 6 is a propyl group are excluded.

9. The liquid crystal composition according to claim 1 , wherein a content of the liquid crystal compound having a chlorine atom is less than 10%.

10. The liquid crystal composition according to claim 1 , wherein a content of the liquid crystal compound having an alkenyl group is less than 10%.

11. The liquid crystal composition according to claim 1 additionally comprising a polymerizable compound.

12. A liquid crystal display element using the liquid crystal composition described in claim 1 .

13. A liquid crystal display element for an active matrix drive using the liquid crystal composition described in claim 1 .

14. A liquid crystal display element for a VA mode, a PSA mode, a PSVA mode, an IPS mode, or an ECB mode using the liquid crystal composition described in claim 1 .

15. The liquid crystal composition according to claim 1 , wherein 100% by mass of the liquid crystal composition consists of:
the first component;
the second component; and
one or more compounds selected from a group of compounds represented by formula (III-A) to formula (III-J):

wherein, R 5 represents an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 2 to 5 carbon atoms and R 6 represents an alkyl group having

Assignees

• Dainippon Ink & Chemicals

Inventors

• Sudo Go
• Kawakami Shotaro

Classifications

• Y10T428/10

  Cross-Sectional Technologies · mapped topic

• C09K2019/301

  Cy-Cy-Ph · CPC title

• C09K19/3066 Primary

  in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers · CPC title

• C09K2019/122

  Ph-Ph · CPC title

• C09K2019/3013

  Cy-Ph-Cy · CPC title