Porous inorganic membranes and method of manufacture

Patent metadata

Field	Value
Publication number	US-9878272-B2
Application number	US-201113115349-A
Country	US
Kind code	B2
Filing date	May 25, 2011
Priority date	May 28, 2010
Publication date	Jan 30, 2018
Grant date	Jan 30, 2018

Abstract

A method is provided for making a porous inorganic membrane by using a mixture of an inorganic material, organic polymer particles and a solvent to form a slurry, the particles being non-spherical, distributing the slurry onto a surface, drying the slurry to remove the solvent and firing the dried slurry to produce the porous inorganic membrane. Examples of organic polymer particles include particles of acrylic. A substrate with a porous inorganic membrane disposed on the substrate is also provided, the inorganic membrane having an average thickness of from about 0.5 micron to about 30 microns, a porosity of from about 30% to about 65%, a median pore size (d50) of from about 0.01 micron to about 1 micron, and a value of (d90−d10)/d50 less than about 2, as measured by mercury porosimetry. An example of a substrate includes an inorganic porous support.

First claim

What is claimed is:

1. A method for making a porous inorganic filtration membrane comprising the steps of:
mixing an inorganic material, multi-lobed organic polymer particles and a solvent to form a slurry, wherein the multi-lobed organic polymer particles comprise 40% or more of the volume of non-solvent materials in the slurry;
distributing the slurry onto a surface;
drying the slurry to remove the solvent; and
firing the dried slurry to produce the porous inorganic membrane, wherein lobes from the multi-lobed organic polymer particles are in contact with each other such that, after the firing, pores formed by the multi-lobed organic polymer particles are connected together.

2. A method for making a single modal porous inorganic filtration membrane comprising the steps of:
mixing an inorganic material, multi-lobed organic polymer particles and a solvent to form a slurry, wherein the multi-lobed organic polymer particles comprise 40% or more of the volume of non-solvent materials in the slurry;
distributing the slurry onto a surface;
drying the slurry to remove the solvent; and
firing the dried slurry to produce the porous inorganic membrane,
wherein the porous inorganic membrane comprises a single modal pore size distribution; and
wherein lobes from the multi-lobed organic polymer particles are in contact with each other such that, after the firing, pores formed by the multi-lobed organic polymer particles are connected together.

3. The method of claim 2 wherein the inorganic material comprises alumina, silica, zeolite, or combinations thereof.

4. The method of claim 2 wherein the organic polymer particles comprise acrylic.

5. The method of claim 4 wherein the acrylic comprises from 40% to about 60% of the volume of the non-solvent materials in the slurry.

6. The method of claim 2 wherein the surface is a porous support and the slurry is distributed on the porous support to form a coating on the porous support.

7. The method of claim 6 wherein the porous support comprises a ceramic porous support.

8. The method of claim 2 wherein the porous inorganic membrane has a thickness of from about 1 micron to about 10 microns.

9. The method of claim 2 wherein the drying of the slurry comprises drying the slurry at a temperature of from about 25° C. to about 120° C.

10. The method of claim 9 wherein the drying of the slurry comprises drying the slurry in an environment of air or N2 at a humidity of from about 60% to about 90%.

11. The method of claim 2 wherein the dried slurry is fired for about 20 hours to about 45 hours at a temperature of about 1100° C. to about 1400° C.

12. The method of claim 2 wherein the porous inorganic membrane has a porosity of from about 40% to about 55%.

13. The method of claim 2 wherein the porous inorganic membrane has a pore size distribution as measured by mercury porosimetry comprising a mono-modal distribution wherein (d90−d10)/d50 is less than about 2 and the pores having a size of d90 or less comprise about 90% of the total pore volume, the pores having a size of d50 or less comprise about 50% of the total pore volume and the pores having a size of d10 or less comprise about 10% of the total pore volume.

14. The method of claim 2 wherein the solvent is an aqueous solvent.

15. A method for producing a porous support with a single modal porous inorganic filtration coating comprising the steps of:
mixing an inorganic material, an acrylic emulsion and a solvent to form a slurry, wherein the acrylic emulsion comprises multi-lobed acrylic particles and the multi-lobed acrylic particles comprise 40% or more of the volume of non-solvent materials in the slurry;
coating the porous support with the slurry;
drying the slurry on the porous support to remove the solvent; and
firing the dried slurry on the porous support to produce the porous support with the porous inorganic coating,
wherein the porous inorganic coating comprises a single modal pore size distribution; and
wherein lobes from the multi-lobed acrylic particles are in contact with each other such that, after the firing, pores formed by the multi-lobed acrylic particles are connected together.

16. The method of claim 15 wherein the inorganic material comprises alumina.

17. The method of claim 15 wherein the porous inorganic membrane has a thickness of from about 1 micron to about 10 microns.

18. The method of claim 15 wherein the acrylic emulsion comprises from 40% to about 60% of the volume of the non-solvent materials in the slurry.

19. The method of claim 15 wherein the porous support is in the form of a honeycomb monolith.

20. The method of claim 15 wherein the porous support comprises a ceramic comprising cordierite, alpha-alumina, mullite, aluminum titinate, titania, zirconia, ceria or combinations thereof.

21. The method of claim 15 wherein the slurry further comprises a dispersant, a binder, an anti-cracking agent, an anti-foaming agent, or combinations thereof.

Assignees

• Bookbinder Dana Craig
• Calabrese Gary S
• Gu Yunfeng
• Wang Jianguo
• Corning Inc

Inventors

• Bookbinder Dana Craig
• Calabrese Gary S
• Gu Yunfeng
• Wang Jianguo

Classifications

• B01D29/05 Primary

  supported · CPC title

• B01D67/0046 Primary

  by slurry techniques, e.g. die or slip-casting · CPC title

• B01D71/028

  Molecular sieves (carbon B01D71/021) · CPC title

• B01D71/02

  Inorganic material · CPC title

• B01D71/024

  Oxides · CPC title