Continuous coalescence processes

Patent metadata

Field	Value
Publication number	US-9874825-B2
Application number	US-201715464633-A
Country	US
Kind code	B2
Filing date	Mar 21, 2017
Priority date	Apr 4, 2013
Publication date	Jan 23, 2018
Grant date	Jan 23, 2018

Abstract

Processes for continuously coalescing particles from an aggregated particle slurry are disclosed. The aggregated particle slurry is heated, then coalesced by raising the pH. The coalesced particles are homogenized and exit as a coalesced particle slurry. A multi-screw extruder is used for the coalescing. These processes are useful for providing coalesced particles such as toner compositions.

First claim

The invention claimed is:

1. Coalesced particles useful for producing toner compositions, wherein the coalesced particles are produced by a continuous process comprising:
(a) feeding an aggregated particle slurry into a multi-zone extruder for a predetermined residence time;
(b) heating the aggregated particle slurry to a temperature of from about 70° C. to about 98° C. in a first zone of the multi-zone extruder;
(c) adding a caustic solution to raise the pH of the aggregated particle slurry and form a coalesced particle slurry in a second zone of the multi-zone extruder downstream of the first zone;
(d) homogenizing the particles in the coalesced particle slurry in a third zone of the multi-zone extruder downstream of the second zone;
(e) measuring circularity of the particles in the coalesced particle slurry and changing the residence time within the multi-zone extruder until the circularity of the particles in the coalesced particle slurry are of a predetermined value; and
(f) removing the coalesced particle slurry of the predetermined particle circularity from an outlet port of the multi-zone extruder, wherein the particle circularity enables the coalesced particles to be useful for producing toner compositions.

2. The coalesced particles of claim 1 , wherein the aggregated particle slurry of step (a) contains from about 30 weight percent (wt.-%) to about 50 wt.-% solids, and from 50 wt.-% to about 70 wt.-% of a solvent.

3. The coalesced particles of claim 2 , wherein the solvent is water.

4. The coalesced particles of claim 1 , wherein the aggregated particle slurry of step (a) has an acidic pH.

5. The coalesced particles of claim 4 , wherein the particle slurry of step (a) has a pH of about 3.0 to 4.5.

6. The coalesced particles of claim 4 , wherein an effective amount of caustic solution is added to the aggregated particle slurry of step (c), for changing its pH from acidic to a value of from about 7.0 to 7.9.

7. The coalesced particles of claim 1 , wherein the aggregated particles of step (a) have an average diameter ranging from about 3 microns to about 25 microns.

8. The coalesced particles of claim 1 , wherein the aggregated particle slurry of step (a) has a GSDv value ranging from about 1.05 to about 1.55.

9. The coalesced particles of claim 1 , wherein the aggregated particle slurry of step (a) has a GSDn value ranging from about 1.05 to about 1.55.

10. The coalesced particles of claim 1 , wherein the aggregated particle slurry of step (a) has a temperature ranging from about 20° C. to about 50° C.

11. The coalesced particles of claim 1 , wherein the particles in the aggregated particle slurry of step (b) have a circularity ranging from about 0.93 to about 0.95.

12. The coalesced particles of claim 1 , wherein the aggregated particle slurry of step (b) is heated to a temperature ranging from about 80° C. to about 90° C.

13. The coalesced particles of claim 1 , wherein the particles in the aggregated particle slurry of step (f) have a circularity ranging from about 0.96 to about 1.0.

14. The coalesced particles of claim 1 , wherein the aggregated particles of step (a) have an average diameter ranging from about 4 microns to about 14 microns.

15. The coalesced particles of claim 1 , wherein the aggregated particle slurry comprises an aggregating agent, a resin, an emulsifying agent, a colorant, a wax, a coagulant, a charge additive, and a surface additive.

16. The coalesced particles of claim 15 , wherein the wax particles range in size of from about 50 nanometers to about 500 nanometers.

17. The coalesced particles of claim 15 , wherein the wax particles range in size of from about 100 nanometers to about 400 nanometers.

18. The coalesced particles of claim 15 , wherein the aggregated particle slurry contains from about 1 wt.-% to about 30 wt.-% of solids.

19. The coalesced particles of claim 15 , wherein the aggregated particle slurry contains from about 2 wt.-% to about 20 wt.-% of solids.

20. The coalesced particles of claim 15 , wherein the aggregating agent comprises a surfactant.

Assignees

• Xerox Corp

Inventors

• Chung Joo T
• Cheng Chieh-Min
• Malachowski Steven M
• Young Eric Joseph
• Godshall Eric David
• Marion Brian Joseph

Classifications

• G03G9/0827

  characterised by their shape, e.g. degree of sphericity · CPC title

• G03G9/081 Primary

  by mixing the toner components in a liquefied state; melt kneading; reactive mixing · CPC title

• G03G9/0819

  characterised by the dimensions of the particles · CPC title

• B01F23/53

  using driven stirrers · CPC title

• B01F27/725

  with two or more helices in respective separate casings, e.g. one casing inside the other · CPC title