Fibers made from polyethylene compositions, and method of making the same

Patent metadata

Field	Value
Publication number	US-9873958-B2
Application number	US-201715437245-A
Country	US
Kind code	B2
Filing date	Feb 20, 2017
Priority date	Jul 10, 2008
Publication date	Jan 23, 2018
Grant date	Jan 23, 2018

Abstract

Fibers made a polyethylene composition, and method of making the same. The polyethylene composition comprises less than or equal to 100 percent by weight of the units derived from ethylene and less than 20 percent by weight of units derived from one or more α-olefin comonomers; wherein said polyethylene composition has a density in the range of 0.930 to 0.960 g/cm 3 , a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I 2 ) in the range of 1 to 300 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, a shear viscosity in the range of 20 to 250 Pascal-s at 3000 s −1 shear rate measured at 190° C., vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of said composition; and wherein the fiber is a monocomponent meltspun fiber.

First claim

We claim:

1. A fiber comprising:
a polyethylene composition comprising less than or equal to 100 percent by weight of the units derived from ethylene and less than 20 percent by weight of units derived from one or more α-olefin comonomers;
wherein said polyethylene composition has a density in the range of 0.930 to 0.960 g/cm 3 , a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I 2 ) in the range of 1 to 300 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, a shear viscosity in the range of 20 to 250 Pascal-s at 3000 s −1 shear rate measured at 190° C., vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of said composition; and wherein the fiber is a monocomponent meltspun fiber, and wherein said fiber has an elongation measured in percent of less than 1000.

2. The fiber according to claim 1 , wherein said fiber has a denier per filament in the range of less than 50 g/9000 m.

3. The fiber according to claim 1 , wherein said fiber has a boiling water shrink measured in percent after being annealed at 120° C. in the range of less than 30.

4. The fiber according to claim 1 , wherein said fiber is a staple fiber or a continuous fiber.

5. A process for making a fiber comprising the steps of:
selecting a polyethylene composition comprising less than or equal to 100 percent by weight of the units derived from ethylene and less than 20 percent by weight of units derived from one or more α-olefin comonomers, wherein said polyethylene composition has a density in the range of 0.930 to 0.960 g/cm 3 , a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I 2 ) in the range of 1 to 300 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, a shear viscosity in the range of 20 to 250 Pascal-s at 3000 s −1 shear rate measured at 190° C., vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of said composition; and
spinning said polyethylene composition into a fiber, thereby forming a monocomponent meltspun fiber, and wherein said fiber has an elongation measured in percent of less than 1000.

6. The process for making a fiber according to claim 5 , wherein said process further comprises the step of orienting said fiber.

7. The process for making a fiber according to claim 5 , wherein said fiber is oriented via cold drawing.

8. The process for making a fiber according to claim 5 , wherein process further comprises the step of annealing said fiber.

9. The process for making a fiber according to claim 8 , wherein said annealing step is carried out at 100° C. or above.

10. The process for making a fiber according to claim 8 , wherein said fiber is annealed at a fixed length.

11. The process for making a fiber according to claim 8 , wherein said fiber is drawn at least 1.5X, wherein X is the ratio of the draw roll speed to the feed roll speed.

12. A fabric comprising:
one or more monocomponent meltspun fibers having an elongation measured in percent of less than 1000, wherein the one or more monocomponent meltspun fibers are from a polyethylene composition comprising less than or equal to 100 percent by weight of the units derived from ethylene and less than 20 percent by weight of units derived from one or more α-olefin comonomers, wherein said polyethylene composition has a density in the range of 0.930 to 0.960 g/cm 3 , a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I 2 ) in the range of 1 to 300 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, a shear viscosity in the range of 20 to 250 Pascal-s at 3000 s −1 shear rate measured at 190° C., vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of said composition.

13. The fabric according to claim 12 , wherein said fabric is selected from the group consisting of woven fabric, non-woven fabric, and combinations thereof.

14. The fabric according to claim 12 , wherein said fabric is a woven fabric, and said woven fabric has an abrasion resistance in the range of less than 5 percent by weight of abraded fiber per weight of the fabric prior to abrasion testing.

15. The fabric according to claim 12 , wherein said fabric is an article selected from the group consisting of upholstery, apparel, wall covering, carpet, diaper topsheet, diaper backsheet, medical fabric, surgical wrap, hospital gown, wipe, textile, and geotextile.

16. The fabric according to claim 12 , wherein said fabric comprises one or more fibers having a denier per filament in the range of less than 5 g/9000 m, and the fabric has one or more of the following characteristics:
a smoothness value in the range of less than 2;
a wax value in the range of greater than 7;
a hand friction value in the range of less than 3.5; and/or
a stiffness value in the range of less than 1.1.

Assignees

• Dow Global Technologies Llc

Inventors

• Pepper Randy E
• Kapur Mridula Babli
• Claasen Gert J
• Knickerbocker Edward N
• Wiker Nathan J
• Michie Jr William J
• Davis Mark B

Classifications

• C08L23/04

  Homopolymers or copolymers of ethene · CPC title

• D01D5/08

  Melt spinning methods {(D01D5/0023 takes precedence)} · CPC title

• D01D5/12

  Stretch-spinning methods ({D01D5/098 takes precedence} finishing by stretching D02J1/22) · CPC title

• Y10T442/3976

  Including strand which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous composition, water solubility, heat shrinkability, etc.] · CPC title

• C08L2205/16

  Fibres; Fibrils · CPC title