Multistage resid hydrocracking

Patent metadata

Field	Value
Publication number	US-9873839-B2
Application number	US-201615229530-A
Country	US
Kind code	B2
Filing date	Aug 5, 2016
Priority date	Jun 23, 2009
Publication date	Jan 23, 2018
Grant date	Jan 23, 2018

Abstract

Processes for upgrading resid hydrocarbon feeds are disclosed. The upgrading processes may include: hydrocracking a resid in a first reaction stage to form a first stage effluent; hydrocracking a deasphalted oil fraction in a second reaction stage to form a second stage effluent; fractionating the first stage effluent and the second stage effluent to recover at least one distillate hydrocarbon fraction and a resid hydrocarbon fraction; feeding the resid hydrocarbon fraction to a solvent deasphalting unit to provide an asphaltene fraction and the deasphalted oil fraction.

First claim

What is claimed:

1. A system for upgrading resid, comprising:
a first reaction stage for hydrocracking a resid to form a first stage effluent;
a second reaction stage for hydrocracking a deasphalted oil fraction to form a second stage effluent;
a separation system for receiving the first stage effluent and the second stage effluent and fractionating the first stage effluent and the second stage effluent to recover at least one distillate hydrocarbon fraction and a liquid hydrocarbon fraction;
an atmospheric distillation column for separating the liquid hydrocarbon fraction to recover at least a second distillation hydrocarbon fraction and a second liquid hydrocarbon fraction;
a vacuum distillation column for separating a portion of the second liquid hydrocarbon fraction to recover at least a third distillate hydrocarbon fraction and a resid hydrocarbon fraction;
a direct heat exchanger for cooling a portion of the second liquid hydrocarbon fraction with at least a portion of the resid hydrocarbon fraction; and
a solvent deasphalting unit for receiving the resid hydrocarbon fraction and providing an asphaltene fraction and the deasphalted oil fraction.

2. The system of claim 1 , wherein the second reaction stage is configured to operate at an operating temperature and an operating pressure greater than an operating temperature and an operating pressure of the first reaction stage.

3. The system of claim 1 , wherein the separation system further comprises a high pressure high temperature separator configured to separate the first stage effluent and the second stage effluent and produce the at least one distillate hydrocarbon fraction and the liquid hydrocarbon fraction.

4. The system of claim 3 , wherein the separation system further comprises a gas cooling, purification, and recycle compression system configured to purify the at least one distillate hydrocarbon and produce a condensed liquid.

5. The system of claim 1 , wherein the first reaction stage and the second reaction stage are configured to operate in parallel.

6. The system of claim 1 , wherein the first reaction stage and the second reaction stage are configured to operate in series.

7. The system of claim 1 , wherein the resid hydrocarbon fraction comprises hydrocarbons with a normal boiling point of at least 340° C.

8. The system of claim 1 , wherein the first reaction stage comprises a single ebullated bed reactor.

9. The system of claim 1 , wherein the second reaction stage comprises at least one of an ebullated bed reactor and a fixed bed reactor.

10. A system for upgrading resid, comprising:
a first reactor containing a first hydrocracking catalyst for hydrocracking a resid hydrocarbon with hydrogen at conditions of temperature and pressure to crack at least a portion of the resid and produce a first effluent;
a second reactor containing a second hydrocracking catalyst for hydrocracking a deasphalted oil fraction with hydrogen at conditions of temperature and pressure to crack at least a portion of the deasphalted oil and produce a second effluent;
a separation system for receiving the first reactor effluent and the second reactor effluent and separating the first and second reactor effluents in a high pressure high temperature separator to provide a gas phase product and a liquid phase product;
an atmospheric distillation tower for separating the liquid phase product to recover a fraction comprising hydrocarbons boiling in a range of atmospheric distillates and a first bottoms fraction comprising hydrocarbons having a normal boiling point of at least 340° C.;
a vacuum distillation tower for separating the bottoms fraction to recover a fraction comprising hydrocarbons boiling in a range of vacuum distillates and a second bottoms fraction comprising hydrocarbons having a boiling temperature of at least 480° C.;
a direct heat exchanger for cooling a portion of the second bottoms fraction with at least a portion of the resid hydrocarbon fraction; and
a solvent deasphalting unit for receiving the resid hydrocarbon fraction and providing an asphaltene fraction and the deasphalted oil fraction.

11. The system of claim 10 , further comprising:
a heat exchanger for cooling the gas phase product to recover a hydrogen-containing gas fraction and a distillate fraction and feeding the distillate fraction to the separation system for separating the liquid phase product.

12. The system of claim 1 , further comprising a flow conduit for recycling at least a portion of the recovered hydrogen to at least one of the first reactor and the second reactor.

13. The system of claim 10 , wherein the second reactor is configured to operate at an operating temperature and an operating pressure greater than an operating temperature and an operating pressure of the first reactor.

14. The system of claim 10 , wherein the second reactor is configured to operate at an operating temperature and an operating pressure less than an operating temperature and an operating pressure of the first reactor.

15. The system of claim 10 , wherein the separation system further comprises a gas cooling, purification, and recycle compression system configured to purify the at least one gas phase product and produce a condensed liquid.

16. The system of claim 10 , wherein the first reactor and the second reactor are configured to operate in parallel.

17. The system of claim 10 , wherein the first reactor and the second reactor are configured to operate in series.

18. The system of claim 10 , wherein the first reactor comprises a single ebullated bed reactor.

19. The system of claim 10 , wherein the second reactor comprises at least one of an ebullated bed reactor and a fixed bed reactor.

Assignees

• Lummus Technology Inc

Inventors

• Baldassari Mario C
• Mukherjee Ujjal K
• Gupta Avinash

Classifications

• C10G2300/301

  Boiling range · CPC title

• C10G2300/107

  Atmospheric residues having a boiling point of at least about 538 °C · CPC title

• C10G2300/202

  Heteroatoms content, i.e. S, N, O, P · CPC title

• C10G21/003

  Solvent de-asphalting · CPC title

• C10G2300/42

  Hydrogen of special source or of special composition · CPC title