Method for efficient CO2 degasification

Patent metadata

Field	Value
Publication number	US-9873650-B2
Application number	US-201615204315-A
Country	US
Kind code	B2
Filing date	Jul 7, 2016
Priority date	May 26, 2016
Publication date	Jan 23, 2018
Grant date	Jan 23, 2018

Abstract

A method including acidifying a solution including dissolved inorganic carbon; vacuum stripping a first amount of a carbon dioxide gas from the acidified solution; stripping a second amount of the carbon dioxide gas from the acidified solution; and collecting the first amount and the second amount of the carbon dioxide gas. A system including; a first desorption unit including a first input connected to a dissolved inorganic carbon solution source to and a second input coupled to a vacuum source; and a second desorption unit including a first input coupled to the solution output from the first desorption unit and a second input coupled to a sweep gas source.

First claim

What is claimed is:

1. A method comprising:
acidifying a solution including dissolved inorganic carbon with aqueous HCl from an electrodialysis unit to form an acidified solution, wherein the electrodialysis unit receives a salt water solution and outputs the aqueous HCl and aqueous NaOH;
converting the dissolved inorganic carbon into carbon dioxide gas in response to acidifying the solution with the aqueous HCl from the electrodialysis unit;
vacuum stripping a first amount of the carbon dioxide gas from the acidified solution;
after vacuum stripping the first amount of the carbon dioxide gas, stripping a second amount of the carbon dioxide gas from the acidified solution; and
collecting the first amount of the carbon dioxide gas and the second amount of the carbon dioxide gas.

2. The method of claim 1 , wherein collecting the first amount of the carbon dioxide gas and the second amount of the carbon dioxide gas comprises combining the first amount of the carbon dioxide gas and the second amount of the carbon dioxide gas.

3. The method of claim 1 , wherein the solution comprises sea water.

4. The method of claim 1 , wherein vacuum stripping comprises passing the acidified solution through a membrane contactor in the presence of a vacuum.

5. The method of claim 4 , wherein stripping a second amount of the carbon dioxide gas comprises passing the acidified solution through a second membrane contactor in the presence of a sweep gas, wherein the second membrane contactor is coupled to receive the acidified solution from the first membrane contactor.

6. The method of claim 5 , wherein the sweep gas comprises a partial pressure of carbon dioxide gas that is less than a partial pressure of carbon dioxide gas in the acidified solution.

7. The method of claim 5 , wherein the sweep gas comprises at least one of carbon monoxide or hydrogen.

8. The method of claim 7 , wherein collecting the first amount of the carbon dioxide gas and the second amount of the carbon dioxide gas comprises combining the first amount of the carbon dioxide gas and the second amount of the carbon dioxide gas and the combination includes an amount of the sweep gas.

9. The method of claim 7 , wherein collecting the second amount of carbon dioxide comprises collecting an amount of the sweep gas, the method further comprising separating the carbon dioxide from an amount of the sweep gas.

10. The method of claim 1 , wherein the collected first amount of carbon dioxide and second amount of carbon dioxide are electrolyzed with steam.

11. The method of claim 1 , further comprising hydrogenating the collected first amount of carbon dioxide and second amount of carbon dioxide to methanol.

12. The method of claim 3 , further comprising:
filtering the sea water with a nanofiltration unit to remove ions and organic matter from the sea water; and
removing calcium and magnesium ions from the seawater using a precipitation unit coupled to receive the seawater from the nanofiltration unit, and coupled to receive the aqueous NaOH from the electrodialysis unit, wherein the salt water includes the sea water.

13. The method of claim 1 , wherein the electrodialysis unit is coupled to perform operations comprising:
receiving the salt water solution with a brine solution compartment disposed in the electrodialysis unit;
applying a voltage across electrodes in the electrodialysis unit;
outputting the saltwater solution from the brine solution compartment with a lower salt concentration in response to the voltage applied across the electrodes;
receiving the aqueous HCl with an acidified solution compartment disposed in the electrodialysis unit;
applying the voltage across the electrodes in the electrodialysis unit; and
outputting the aqueous HCl, with a higher HCl concentration, from the acidified solution compartment to acidify the solution, wherein chlorine ions in the brine solution compartment traveled to the acidified solution compartment in response to the voltage across the electrodes.

14. The method of claim 13 , wherein the electrodialysis unit is coupled to perform operations further comprising:
receiving the aqueous NaOH with a basified solution compartment disposed in the electrodialysis unit;
applying the voltage across the electrodes in the electrodialysis unit; and
outputting the aqueous NaOH from the basified solution compartment with a higher NaOH concentration in response to the voltage applied across the electrodes.

15. The method of claim 14 , wherein in response to the voltage, the chlorine ions flow through an anion exchange membrane disposed between the brine solution compartment and the acidified solution compartment, and wherein in response to the voltage, hydrogen ions and hydroxyl ions flow through a bipolar membrane disposed between the acidified solution compartment and the basified solution compartment.

16. The method of claim 15 , wherein applying the voltage across the electrodes in the electrodialysis unit includes collecting sodium ions at a negatively charged terminal, and wherein the brine solution compartment, the acidified solution compartment, and the basified solution compartment are included in a first cell in a plurality of cells in the electrodialysis unit.

17. The method of claim 13 , further comprising neutralizing the acidified solution with the aqueous NaOH output from the basified solution compartment in the electrodialysis unit, after stripping a second amount of the carbon dioxide gas from the acidified solution.

18. The method of claim 1 , further comprising:
removing ions from the solution with a resin tower; and
outputting the salt water solution from the resin tower to the electrodialysis unit.

19. The method of claim 18 , further comprising removing water from the salt water with a reverse osmosis unit coupled between the resin tower and the electrodialysis unit.

Assignees

• X Dev Llc

Inventors

• Eisaman Matthew D
• Karnitz Stephen D
• Rivest Jessica L B

Classifications

• C25B1/23

  Carbon monoxide or syngas · CPC title

• B01D61/025 Primary

  Reverse osmosis; Hyperfiltration · CPC title

• B01D19/0005

  with one or more auxiliary substances · CPC title

• B01D19/0031

  by filtration · CPC title

• C01B31/20

  Chemistry & Metallurgy · mapped topic