Method for producing hydrocarbon products

Patent metadata

Field	Value
Publication number	US-9873645-B2
Application number	US-201414916161-A
Country	US
Kind code	B2
Filing date	Sep 3, 2014
Priority date	Sep 5, 2013
Publication date	Jan 23, 2018
Grant date	Jan 23, 2018

Abstract

The invention relates to a method for producing hydrocarbon products which comprises preparing a hydrocarbon stream (C4) which predominantly comprises branched and unbranched hydrocarbons each having four carbon atoms. A first and a second partial stream (i-C4, n-C4) are obtained from this stream (C4), the first partial stream (i-C4) predominantly comprising branched hydrocarbons with four carbon atoms and the second partial stream (n-C4) predominantly comprising unbranched hydrocarbons with four carbon atoms. The method further comprises the steam cracking of at least part of the first partial stream (i-C4) at a first, higher cracking severity and at least part of the second partial stream (n-C4), at a second, lower, cracking severity.

First claim

The invention claimed is:

1. Method for producing hydrocarbon products, which comprises:
a) preparing a hydrocarbon stream (C4), which predominantly comprises branched and unbranched hydrocarbons each having four carbon atoms,
characterised by
b) recovering a first and a second partial stream (i-C4, n-C4) from the hydrocarbon stream (C4), the first partial stream (i-C4) predominantly comprising branched hydrocarbons with four carbon atoms and the second partial stream (n-C4) predominantly comprising unbranched hydrocarbons with four carbon atoms, and
c) steam cracking at least a part of the first partial stream (i-C4) or a stream derived therefrom at a first cracking severity and at least a part of the second partial stream (n-C4)) or a stream derived therefrom at a second cracking severity, the first cracking severity resulting in a conversion of iso-butane in the first partial stream of more than 91% and up to 99% and the second cracking severity resulting in a conversion of n-butane in the second partial stream of less than 92% and more than 50%.

2. Method according to claim 1 , wherein the first partial stream (i-C4) is at least partially subjected to a hydrogenation process before the steam cracking at the first cracking severity.

3. Method according to claim 1 , wherein the hydrocarbon stream (C4) prepared according to a) is at least partially produced from at least one cracking gas (C) obtained by steam cracking according to c).

4. Method according to claim 1 , wherein the hydrocarbon stream (C4) prepared according to a) is at least partially produced from a cracking gas (C) which is formed by steam cracking a fresh feed (A).

5. Method according to claim 1 , wherein the hydrocarbon stream (C4) prepared according to a) is formed at least partially from an uncracked fresh feed (A).

6. Method according to claim 1 , wherein the first cracking severity results in a conversion of iso-butane in the first partial stream of more than 92% and the second cracking severity results in a conversion of n-butane in the second partial stream of less than 90%.

7. Method according to claim 1 , wherein the first cracking severity is 1 to 30%, higher than the second cracking severity.

8. Method according to claim 1 , wherein the steam cracking at the first cracking severity is carried out using a quantity of steam of 0.2 to 0.7 kg/kg, and the steam cracking at the second cracking severity is carried out using a quantity of steam of 0.2 to 0.7 kg/kg.

9. Method according to claim 1 , wherein the steam cracking at the first cracking severity and/or at the second cracking severity is carried out in each case in at least one cracking furnace ( 12 , 13 ) which is supplied with at least one other furnace feed (A) in the form of at least one recycle stream and/or at least one fresh feed.

10. Method according to claim 1 , wherein 1,3-butadiene (BD) is separated from the hydrocarbon stream (C4) before the first and second partial streams (i-C4, n-C4) are recovered according to b).

11. Method according to claim 10 , wherein, after the separation of the 1,3-butadiene (BD), isobutene contained in the hydrocarbon stream (C4) is at least partially reacted to form a tert-butylether and the tert-butylether is also separated from the hydrocarbon stream (C4).

12. Method according to claim 11 , wherein 1-butene contained in the hydrocarbon stream (C4) is at least partially hydroisomerised to 2-butene.

Assignees

• Linde Ag

Inventors

• Walter Stefanie
• Fritz Helmut
• Schmidt Gunther

Classifications

• C07C7/14891

  alcohols · CPC title

• C10G2300/4081

  Recycling aspects · CPC title

• C07C41/34

  Separation; Purification; Stabilisation; Use of additives · CPC title

• C10G2300/104

  Light gasoline having a boiling range of about 20 - 100 °C · CPC title

• C07C5/13 Primary

  with simultaneous isomerisation · CPC title