Reactor multi-pass grids for improved catalyst hydrodynamics

Patent metadata

Field	Value
Publication number	US-9873641-B2
Application number	US-201414225465-A
Country	US
Kind code	B2
Filing date	Mar 26, 2014
Priority date	Mar 29, 2013
Publication date	Jan 23, 2018
Grant date	Jan 23, 2018

Abstract

A process and device for the flow of catalyst in a reactor is presented. The device includes a series of grids within a reactor vessel, where each grid includes small openings for the passage of gas and some catalyst particles, and larger openings for the more continuous passage of catalyst. The grids span horizontally across the vessel, and are spaced vertically apart to provide for the flow of catalyst down through the reactor.

First claim

The invention claimed is:

1. A process for the production of olefins from oxygenates comprising:
passing a catalyst downward through a reactor for contacting a solid catalyst with fluid reactants;
passing fluid reactants comprising oxygenates upward through the reactor in a counter current mode with respect to the catalyst;
contacting the catalyst in the reactor with a plurality of grids disposed within the reactor and extend horizontally across the reactor, and with a vertical spacing between pairs of grids,
directing, at each grid, at least a portion of the catalyst to flow at least partially across the reactor through contact with a plurality of small openings in each grid of sufficient size to allow gas through and the catalyst particles through, wherein the small openings each have a first open area;
directing, at each grid, at least a portion of the catalyst to flow freely downward by passing at least a portion of the catalyst though at least one large opening in each grid wherein the large opening has a second open area greater than the first open area; and

reacting the fluid reactants comprising oxygenates through the contact of the fluid reactants with the catalyst at reaction conditions effective to convert the oxygenates into olefins and generating an effluent comprising olefins.

2. The process of claim 1 wherein the directing of the catalyst to flow flows freely downward through the at least one large opening occurs over between 15% and 35% of the cross-sectional area of each grid.

3. The process of claim 1 wherein the directing of the catalyst to flow flows freely downward through the at least one large opening occurs over between 15% and 25% of the cross-sectional area of each grid.

4. The process of claim 1 wherein the fluid reactants comprising oxygenates includes oxygenates selected from the group consisting of alcohols, ethers, aldehydes, ketones, carboxylic acids, and mixtures thereof.

5. The process of claim 1 wherein the directing of the catalyst to flow flows freely downward through the large openings in the grids occurs across a substantially rectangular area having a width between 5 and 50 mm and which spans across the grid.

6. The process of claim 1 wherein the directing of the catalyst to flow flows freely downward through the large openings in the grids occurs in a space between the reactor wall and the grid.

7. The process of claim 1 wherein the catalyst comprises a molecular sieve comprising silicoaluminophosphates.

8. The process of claim 1 wherein the catalyst particle flow is directed by at least three grids stacked within a vessel in a vertical arrangement, and where each grid has at least two large opening that are substantially rectangular, and where the openings span the width of the grid, and wherein the large openings are displaced in a horizontal direction relative to the large openings of a neighboring grid.

9. A process for converting oxygenates to olefins, comprising:
passing a catalyst downward through a reactor, wherein the reactor includes a plurality of reactor grids
controlling the flow of catalyst particles through the reactor by contacting the flow of catalyst particles with a structure having a cross-sectional area and disposed in a substantially perpendicular orientation relative to the movement of catalyst
wherein the flow of catalyst particles is restricted by a plurality of small openings in the structure wherein each small opening has a small dimension between 5 and 25 mm; and
wherein the flow of catalyst particles unrestricted by at least one large opening in the structure wherein the large opening has a minimum small dimension of at least 75 mm and wherein the large opening comprises between 15% and 35% of the cross-sectional area of the structure; and

contacting a fluid stream comprising oxygenates over the catalyst at reaction conditions in the reactor to generate a process stream comprising olefins.

10. The process of claim 9 wherein in each reactor grid the large opening comprises between 20% and 30% of the cross-sectional area.

11. The process of claim 9 wherein in each reactor grid the at least one large opening comprises two openings, and wherein each of the two large openings comprise between 5% and 20% of the cross-sectional area of the structure.

12. The process of claim 9 wherein the grid comprises one large opening on one side of the grid and comprising between 15% and 25% of the cross sectional area of the grid, and where the remainder of the grid is comprised of small openings.

13. The process of claim 9 wherein the catalyst comprises a zeolite or non-zeolitic molecular sieve.

14. The process of claim 13 wherein the catalyst comprises a silicoaluminophosphate (SAPO).

15. The process of claim 9 wherein the reaction conditions include a temperature between 200° C. and 700° C.

16. The process of claim 9 wherein the fluid stream comprising oxygenates are selected from the group consisting of alcohols, ethers and mixtures thereof.

17. The process of claim 9 wherein the reaction conditions include a pressure between 100 kPa and 2000 kPa.

Assignees

• Uop Llc

Inventors

• Johnson Ii Richard A
• Palmas Paolo
• Senetar John J
• Kauff Daniel A
• Stine Michael

Classifications

• B01J2208/00663

  Concentration · CPC title

• C07C1/20 Primary

  starting from organic compounds containing only oxygen atoms as heteroatoms · CPC title

• B01J2208/0084

  inside the bed, e.g. baffles · CPC title

• B01J8/12

  moved by gravity in a downward flow · CPC title

• C07C11/02

  Alkenes · CPC title