Apparatus for measuring hydroxyl radicals and liquid treatment apparatus

Patent metadata

Field	Value
Publication number	US-9873619-B2
Application number	US-201314758046-A
Country	US
Kind code	B2
Filing date	Sep 12, 2013
Priority date	Dec 28, 2012
Publication date	Jan 23, 2018
Grant date	Jan 23, 2018

Abstract

According to one embodiment, an apparatus for measuring hydroxyl radicals that measures hydroxyl radicals produced by irradiating a liquid to be treated flowing through a channel in which an ultraviolet lamp is arranged with ultraviolet rays, the apparatus includes a diverting unit, a reagent adding unit, and a measuring unit. The diverting unit has a diverting channel that diverts the liquid to be treated before being irradiated with the ultraviolet rays from the channel and part of which is arranged at a position enabling the liquid to be treated within the channel to be irradiated with the ultraviolet rays. The reagent adding unit adds a hydroxyl radical measuring reagent to the diverted liquid to be treated. The measuring unit irradiates the diverted liquid to be treated with the ultraviolet rays and measures the amount of hydroxyl radicals produced based on a change in the hydroxyl radical measuring reagent between before and after the irradiation with the ultraviolet rays.

First claim

The invention claimed is:

1. An apparatus for measuring hydroxyl radicals produced by irradiating a liquid flowing in a main channel with ultraviolet rays from an ultraviolet lamp placed in the main channel, the apparatus comprising:
a diverging unit including a divergent channel, that is made of a UV transmitting material, diverging from the main channel such that a part of the liquid flowing in the main channel is diverted for hydroxyl radicals measurement, the divergent channel including a portion extending into the main channel to oppose the ultraviolet lamp positioned in the main channel such that the part of the liquid is irradiated with an ultraviolet ray from the ultraviolet lamp and the divergent channel extending back out of the main channel such that the irradiated liquid is guided outside of the main channel;
a reagent adder placed in the divergent channel upstream of the portion, the reagent adder configured to add a hydroxyl radical measuring reagent to the part of the liquid before the ultraviolet ray irradiation; and
an analyzer placed in the divergent channel downstream of where the divergent channel exits the main channel, the analyzer configured to measure an amount of hydroxyl radicals produced from the part of the liquid by the ultraviolet ray irradiation, based on a change in the hydroxyl radical measuring reagent before and after the ultraviolet ray irradiation.

2. The apparatus of claim 1 , wherein the analyzer includes a spectroscopic analyzer configured to continuously perform spectroscopic analysis of the part of the liquid.

3. The apparatus of claim 2 , wherein the hydroxyl radical measuring reagent is a terephthalic acid solution.

4. The apparatus of claim 1 , wherein the portion of the divergent channel extends in an extending direction of the ultraviolet lamp in the main channel.

5. The apparatus of claim 1 , wherein the portion of the divergent channel extends in a direction crossing an extending direction of the ultraviolet lamp in the main channel.

6. A liquid treatment apparatus, comprising:
a water flowing barrel connected to an external pipe and forming a main channel through which a liquid introduced from the external pipe flows;
an ultraviolet irradiation unit provided in the water flowing barrel and including an ultraviolet lamp configured to irradiate the liquid with ultraviolet rays;
a diverting unit including a divergent channel, that is made of a UV transmitting material, diverging from the main channel such that a part of the liquid flowing in the water flowing barrel is diverted from the main channel for hydroxyl radicals measurement, the divergent channel including a portion extending into the water flowing barrel and extending back out of the water flowing barrel such that the part of the liquid is irradiated with an ultraviolet ray from the ultraviolet lamp and the irradiated liquid is guided outside of the water flowing barrel;
a reagent adder placed in the divergent channel upstream of the portion, the reagent adder configured to add a hydroxyl radical measuring reagent to the part of the liquid before the ultraviolet ray irradiation; and
an analyzer placed in the divergent channel downstream of where the divergent channel exits the water flowing barrel, the analyzer configured to measure an amount of hydroxyl radicals produced from the part of the liquid by the ultraviolet ray irradiation, based on a change in the hydroxyl radical measuring reagent before and after the ultraviolet ray irradiation.

Assignees

• Toshiba Kk

Inventors

• Murayama Seiichi
• Abe Norimitsu
• Ide Takeshi
• Arimura Ryoichi
• Kubo Kie
• Takeuchi Kenji
• Soma Takahiro

Classifications

• C02F2305/023

  Reactive oxygen species, singlet oxygen, OH radical · CPC title

• C02F1/78

  with ozone {(C02F1/4672 takes precedence)} · CPC title

• G01N2021/6417

  Spectrofluorimetric devices · CPC title

• G01N21/631

  using photolysis and investigating photolysed fragments · CPC title

• C02F2209/00

  Controlling or monitoring parameters in water treatment · CPC title