Thermoelectric material and thermoelectric device including the same

Patent metadata

Field	Value
Publication number	US-9871180-B2
Application number	US-201314096560-A
Country	US
Kind code	B2
Filing date	Dec 4, 2013
Priority date	Dec 31, 2012
Publication date	Jan 16, 2018
Grant date	Jan 16, 2018

Abstract

A thermoelectric material includes a stack structure including alternately stacked first and second material layers. The first material layer may include a carbon nano-material. The second material layer may include a thermoelectric inorganic material. The first material layer may include a thermoelectric inorganic material in addition to the carbon nano-material. The carbon nano-material may include, for example, graphene. At least one of the first and second material layers may include a plurality of nanoparticles. The thermoelectric material may further include at least one conductor extending in an out-of-plane direction of the stack structure.

First claim

What is claimed is:

1. A thermoelectric composite comprising:
a stack structure including alternately stacked at least two first and at least two second material layers, the at least two first material layers containing a carbon nano-material and the at least two second material layers containing a thermoelectric inorganic material, and
at least one conductor extending in an out-of-plane direction of the at least two first and the at least two second material layers, the at least one conductor directly contacting a lateral side surface of each of the at least two first and the at least two second material layers, the at least one conductor being configured to connect the lateral side surfaces of at least two first and the at least two second material layers in the out-of-plane direction,
wherein the carbon nano-material includes a plurality of graphene nanoparticles, the plurality of graphene nanoparticles are nanoscale particles, at least some of the plurality of graphene nanoparticles are arranged in an in plane direction of the at least two first material layers, and the plurality of graphene nanoparticles collectively form a layer structure,
wherein adjacent two layers in the stack structure are in direct contact with each other in the out-of-plane direction, and
wherein each of the at least two first and the at least two second material layers has a length in the in-plane direction of the at least two first material layers and a thickness in the out-of-plane direction of the at least two first material layers, the length is greater than the thickness, the at least one conductor extends in the out-of-plane direction, and the at least one conductor directly contacts the at least two first material layers and the at least two second material layers.

2. The thermoelectric composite of claim 1 , wherein the at least two first material layers further comprise a thermoelectric inorganic material.

3. The thermoelectric composite of claim 2 , wherein the thermoelectric inorganic material of the at least two first material layers include a plurality of nanoparticles.

4. The thermoelectric composite of claim 2 , wherein at least two first material layers comprise a composite of the carbon nano-material and the thermoelectric inorganic material.

5. The thermoelectric composite of claim 1 , wherein the thermoelectric inorganic material of the at least two second material layers includes a plurality of nanoparticles.

6. The thermoelectric composite of claim 1 , wherein the thermoelectric inorganic material of the at least two second material layers include at least one of an Sb—Te compound, a Bi—Te compound, a Bi—Sb—Te compound, a Co—Sb compound, a Pb—Te compound, a Ge—Tb compound, an Si—Ge compound, and an Sm—Co compound.

7. The thermoelectric composite of claim 1 , wherein the at least one conductor has a pillar shape.

8. The thermoelectric composite of claim 1 , wherein the at least one conductor comprises a carbon nanotube (CNT).

9. The thermoelectric composite of claim 8 , wherein the at least one conductor comprises a multi-walled carbon nanotube (MWCNT).

10. The thermoelectric composite of claim 8 , wherein the at least one conductor comprises a single-walled carbon nanotube (SWCNT).

11. The thermoelectric composite of claim 1 , wherein
the at least one conductor comprises a plurality of conductors spaced apart from each other, and
the stack structure fills a space between the plurality of conductors.

12. A thermoelectric device comprising the thermoelectric composite of claim 1 .

13. The thermoelectric device of claim 12 , further comprising:
an electronic device connected to both ends of the stack structure in an in-plane direction of the stack structure.

14. The thermoelectric device of claim 13 , wherein the electronic device is one of an electricity consuming device, an electricity storing device, and an electricity supplying device.

15. The thermoelectric device of claim 12 , further comprising:
an electronic device electrically connected to both ends of the stack structure in an out-of-plane direction of the stack structure.

16. The thermoelectric device of claim 15 , wherein the electronic device is one of an electricity consuming device, an electricity storing device, and an electricity supplying device.

17. The thermoelectric device of claim 12 , wherein the thermoelectric device is one of a thermoelectric electricity generation device, a thermoelectric cooling device, and a heat sensor.

18. A thermoelectric device comprising:
a thermoelectric material having a stack structure including alternately stacked at least two first and at least two second material layers, the at least two first material layers containing a carbon nano-material and the at least two second material layers containing a thermoelectric inorganic material, and at least one of the carbon nano-material and the thermoelectric inorganic material including a plurality of graphene nanoparticles, and
at least one conductor extending along lateral side surfaces of the at least two first and the at least two second material layers, the at least one conductor directly contacting the lateral side surface of each of the at least two first and the at least two second material layers, the at least one conductor being configured to connect the lateral side surfaces of the at least two first and the at least two second material layers,
wherein the plurality of graphene nanoparticles are nanoscale particles, at least some of the plurality of graphene nanoparticles are arranged in an in-plane direction of the at least two first material layers, and the plurality of graphene nanoparticles collectively form a layer structure,
wherein adjacent two layers in the stack structure are in direct contact with each other in an out-of-plane direction, and
wherein each of the at least two first and the at least two second material layers has a length in the in-plane direction of the at least two first material layers and a thickness in the out-of-plane direction, the length is greater than the thickness, the at least one conductor extends in the out-of-plane direction, and the at least one conductor directly contacts the at least two first material layers and the at least two second material layers.

19. The thermoelectric device of claim 18 , wherein the at least two first material layers comprises a composite of the carbon nano-material and a thermoelectric inorganic material.

20. The thermoelectric device of claim 18 , wherein the at least one conductor comprises a carbon nanotube (CNT).

21. The thermoelectric device of claim 18 , wherein
the at least one conductor comprises a plurality of conductors spaced apart from each other, and
the stack structure fills a space between the plurality of conductors.

Assignees

• Samsung Electronics Co Ltd
• Sungkyunkwan Univ Foundation For Corporate Collaboration

Inventors

• Choi Jae-Young
• Baik Seung-Hyun
• Kim Won-Young
• Suh Dae-Woo
• Lee Sang-Hoon
• Hong Seung-Hyun

Classifications

• Y10S977/948

  Energy storage/generating using nanostructure, e.g. fuel cell, battery · CPC title

• Y10S977/742

  Carbon nanotubes, CNTs · CPC title

• B82Y99/00

  Subject matter not provided for in other groups of this subclass · CPC title

• H01L35/14

  Electricity · mapped topic

• H01L35/26 Primary

  Electricity · mapped topic