Polishing material particles, method for producing polishing material, and polishing processing method

Patent metadata

Field	Value
Publication number	US-9868885-B2
Application number	US-201414910986-A
Country	US
Kind code	B2
Filing date	Jul 28, 2014
Priority date	Aug 7, 2013
Publication date	Jan 16, 2018
Grant date	Jan 16, 2018

Abstract

Disclosed are polishing material particles which have polishing performance suitable for precision polishing and also have a high polishing speed and high monodispersibility; a polishing material containing the polishing material particles; and a polishing processing method using the polishing material. The polishing material particles are spherical particles having an average aspect ratio of 1.00 to 1.15, wherein the particle diameter (D 50 (nm)) of the polishing material particles as determined from a particle diameter cumulative distribution curve falls within the range from 50 to 1500 nm. The average content of cerium or the total content of cerium and at least one element selected from lanthanum (La), praseodymium (Pr), neodymium (Nd), samarium (Sm) and europium (Eu) in the polishing material particles is 81 mol % or more relative to the total content of all of rare earth elements that constitute the polishing material particles.

First claim

The invention claimed is:

1. A particulate abrasive produced by a synthetic process using an aqueous rare-earth salt solution and a precipitant, wherein
the particulate abrasive has a spherical shape and an average aspect ratio of 1.00 to 1.15;
the particulate abrasive has a particle size D 50 (nm) of 50 to 1500 nm determined by a cumulative particle size distribution curve; and
an average molar proportion of cerium to all rare-earth elements in the particulate abrasive, or a sum of molar proportions of cerium and at least one element selected from lanthanum (La), praseodymium (Pr), neodymium (Nd), samarium (Sm), and europium (Eu) to all rare-earth elements in the particulate abrasive, is 81 mol % or more.

2. The particulate abrasive according to claim 1 , wherein the particle size D 50 (nm) determined by the cumulative particle size distribution curve ranges from 300 to 500 nm.

3. The particulate abrasive according to claim 1 , wherein a maximum particle size D max (nm) determined by the cumulative particle size distribution curve ranges from 1.20 to 1.60 times the particle size D 50 (nm).

4. The particulate abrasive according to claim 1 , wherein a particle size D 10 (nm) determined by the cumulative particle size distribution curve ranges from 0.70 to 0.95 times the particle size D 50 (nm).

5. The particulate abrasive according to claim 1 , wherein a particle size D 90 (nm) determined by the cumulative particle size distribution curve ranges from 1.10 to 1.35 times the particle size D 50 (nm).

6. The particulate abrasive according to claim 1 , wherein the particulate abrasive has an elemental composition satisfying the following requirements 1a to 3a:
1a) the particulate abrasive comprises at least one element selected from yttrium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium, in addition to cerium;
2a) the molar proportion of cerium in the particulate abrasive is 81 mol % or more; and
3a) the molar proportion of the at least one element selected from yttrium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium in the particulate abrasive is 19 mol % or less.

7. The particulate abrasive according to claim 1 , wherein the particulate abrasive has an elemental composition satisfying the following requirements 1b to 3b:
1b) the particulate abrasive comprises at least one element selected from yttrium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium, in addition to cerium;
2b) the molar proportion of cerium in the particulate abrasive is 90 mol % or more; and
3b) the molar proportion of the at least one element selected from yttrium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium in the particulate abrasive is 10 mol % or less.

8. The particulate abrasive according to claim 1 , wherein the molar proportion of cerium ranges from 95 to 100 mol %.

9. A method for producing the particulate abrasive according to claim 1 , the method at least comprising:
Step A of preparing an aqueous precipitant solution involving dissolving a precipitant in an aqueous solvent at room temperature into a predetermined concentration and heating the aqueous solution in a closed vessel;
Step B of preparing an aqueous rare-earth salt solution containing at least cerium (Ce);
Step C of preparing a reaction mixture involving placing the aqueous rare-earth salt solution prepared in Step B into an open vessel and feeding the aqueous precipitant solution cooled to room temperature from the closed vessel to the open vessel;
Step D of generating a particulate abrasive precursor involving heating the reaction mixture with stirring in the open vessel;
Step E of separating the particulate abrasive precursor generated in Step D from the reaction mixture; and
Step F of producing a particulate abrasive involving calcining the particulate abrasive precursor separated in Step E in an oxidizing atmosphere.

10. A method for producing an abrasive that comprises the particulate abrasive according to claim 1 , the method at least comprising:
Step 1 of preparing an aqueous rare-earth salt solution containing at least cerium (Ce);
Step 2 of placing the aqueous rare-earth salt solution prepared in Step 1 into a pressure vessel and heating the solution to 100° C. or higher;
Step 3 of preparing a reaction mixture involving feeding, under pressure, a precipitant solution contained in an open vessel kept at 65° C. or lower to the aqueous rare-earth salt solution contained in the pressure vessel and heated to 100° C. or higher in Step 2 ;
Step 4 of generating a particulate abrasive precursor involving heating the reaction mixture to 100° C. or higher with stirring in the pressure vessel;
Step 5 of separating the particulate abrasive precursor generated in Step 4 from the reaction mixture; and
Step 6 of producing a particulate abrasive involving calcining the particulate abrasive precursor separated in Step 5 in an oxidizing atmosphere.

11. The method for producing the abrasive according to claim 10 , wherein the aqueous rare-earth salt solution has an elemental composition satisfying the following requirements 1c to 3c:
1c) the aqueous rare-earth salt solution comprises at least one element selected from lanthanum (La), praseodymium (Pr), neodymium (Nd), samarium (Sm), europium (Eu), yttrium (Y), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu), in addition to cerium;
2c) in the aqueous rare-earth salt solution, a sum of molar proportions of cerium and the at least one element selected from lanthanum, praseodymium, neodymium, samarium, and europium to all rare-earth elements to be contained in the particulate abrasive is 81 mol % or more; and
3c) in the aqueous rare-earth salt solution, a molar proportion of the at least one element selected from yttrium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium to all rare-earth elements to be contained in the particulate abrasive is 19 mol % or less.

12. The method for producing the abrasive according to claim 10 , wherein the aqueous rare-earth salt solution has an elemental composition satisfying the following requirements 1d to 3d:
1d) the aqueous rare-earth salt solution comprises at least one element selected from yttrium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium, in addition to cerium;
2d) in the aqueous rare-earth salt solution, the molar proportion of cerium to all rare-earth elements to be contained in the particulate abrasive is 81 mol % or more; and
3d) in the aqueous rare-earth salt solution, the molar proportion of the at least one element selected from yttrium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium to all rare-earth elements to be contained in the particulate abrasive is 19 mol % or less.

13. The method for producing the abrasive according to claim 10 , wherein the aqueous rare-earth salt solution has an elemental composition satisfying the following requirements 1e to 3e:
1e) the aqueous rare-earth salt solution comprises at least one element selected from yttrium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium, in addition to cerium;
2e) in the aqueous rare-earth salt solution, the molar proportion of cerium to all rare-earth elements to be contained in the particulate abrasive is 90 mol % or more; and
3e) in the aqueous rare-earth salt solution, the molar proportion of the at least one element selected from yttrium, gadolinium

Assignees

• Konica Minolta Inc

Inventors

• Mizoguchi Keisuke
• Maezawa Akihiro
• Ito Natsuki
• Takahashi Atsushi
• Wakamatsu Hideaki
• Nagai Yuuki
• Inui Chie

Classifications

• C01P2004/03

  obtained by SEM · CPC title

• B24C11/00

  Selection of abrasive materials {or additives} for abrasive blasts (polishing compositions C09G) · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C09G1/02

  containing abrasives or grinding agents {(abrasives as such C09K3/14; polishing of semi-conductors H10P52/40)} · CPC title

• C01P2004/32

  Spheres · CPC title