Rubber composition and tire produced by using the same

Patent metadata

Field	Value
Publication number	US-9868847-B2
Application number	US-201113989243-A
Country	US
Kind code	B2
Filing date	Nov 24, 2011
Priority date	Nov 24, 2010
Publication date	Jan 16, 2018
Grant date	Jan 16, 2018

Abstract

In order to provide a rubber composition which is improved in dispersibility of silica in rubber compositions and can be improved as well in heat build-up and processability without causing increasing a viscosity of unvulcanized rubber and retarding a vulcanization rate, and a tire prepared by using the same, the rubber composition is endowed with a constitution in which at least one rubber component selected from natural rubber and/or diene base synthetic rubbers is compounded with a white filler and at least one of monoalkanolamides represented by the following Formula (I):

[in Formula (I) described above, R 1 represents an alkyl group or an alkenyl group having 1 to 13 carbon atoms, and the alkyl group and alkenyl group may be any of a linear type, a branched type and a cyclic type; and R 2 represents a hydroxyalkyl group or a hydroxyalkyl group having an oxyalkylene unit].

First claim

The invention claimed is:

1. A rubber composition comprising a blend of at least one rubber component selected from natural rubber and/or diene base synthetic rubbers, 5 to 200 parts by mass, based on 100 parts by mass of the rubber component, of silica and/or aluminum hydroxide, and 0.5 to 15 parts by mass, based on 100 parts by mass of the rubber component, of at least one of monoalkanolamides represented by the following Formula (I), wherein a compounding amount of the monoalkanolamide represented by Formula (I) is 0.5 to 20 parts by mass based on 100 parts by mass of the silica and/or the aluminum hydroxide:

wherein in Formula (I), R 1 represents an alkyl group or an alkenyl group having 1 to 13 carbon atoms, and the alkyl group and alkenyl group may be any of a linear type, a branched type and a cyclic type; and R 2 represents a hydroxyalkyl group or a hydroxyalkyl group having an oxyalkylene unit, and
wherein the total amount of the natural rubber and/or diene base synthetic rubbers and the silica and/or aluminum hydroxide is 67.34% to 79.37% by mass based on the entire mass of the rubber composition.

2. The rubber composition as described in claim 1 , wherein in Formula (I), R 1 is at least one selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, isobutyl, t-butyl, pentyl, isopentyl, hexyl, isoheptyl, 2-ethylhexyl, octyl, nonyl, isononyl, decyl, undecyl, dodecyl, tridecyl or isotridecyl.

3. The rubber composition as described in claim 1 , wherein in Formula (I), R 1 is an alkyl group or an alkenyl group having 6 to 13 carbon atoms.

4. The rubber composition as described in claim 1 , wherein the silica and/or the aluminum hydroxide is present in an amount of 20 to 120 parts by mass and the at least one of monoalkanolamides represented by Formula (I) is present in an amount of 1 to 10 parts by mass, based on 100 parts by mass of the rubber component.

5. The rubber composition as described in claim 1 , wherein R 2 in Formula (I) is represented by the following Formulas (II); R 3 is an alkylene group having 1 to 6 carbon atoms; and n is a number of 1 to 5:
—(R 3 O) n —H  (II).

6. The rubber composition as described in a claim 1 , further comprising a silane coupling agent.

7. The rubber composition as described in claim 6 , wherein the silica and/or the aluminum hydroxide is silica, and the silane coupling agent is present in an amount of 1 to 20 parts by mass based on 100 parts by mass of silica.

8. The rubber composition as described in claim 7 , wherein the silica and/or the aluminum hydroxide is silica, and the silane coupling agent is present in an amount of 6 to 20 parts by mass based on 100 parts by mass of silica.

9. The rubber composition as described in claim 1 , wherein the silica and/or the aluminum hydroxide is silica.

10. The rubber composition as described in claim 1 , wherein the at least one of monoalkanolamides represented by Formula (I) is present in an amount of 2 to 12 parts by mass based on 100 parts by mass of the silica and/or the aluminum hydroxide.

11. The rubber composition as described in claim 1 , wherein the diene base synthetic rubber is at least one selected from the group consisting of polyisoprene rubber (IR), polybutadiene rubber (BR), styrene-butadiene copolymer rubber (SBR), butyl rubber (IIR) and ethylene-propylene copolymers.

12. The rubber composition as described in claim 1 , wherein the at least one of monoalkanolamides represented by Formula (I) is at least one selected from the group consisting of lauric acid monoisopropanolamide, hexanoic acid monoethanolamide, octanoic acid monoethanolamide, decanoic acid monoethanolamide, lauric acid monoethanolamide, tetradecanoic acid monoethanolamide and POE (2) lauric acid monoethanolamide.

13. A rubber composition comprising a vulcanized composition of the rubber composition as described in claim 1 .

14. A tire prepared by using the rubber composition as described in claim 1 for a tire member.

15. A method of reducing a viscosity of unvulcanized rubber, wherein at least one rubber component selected from natural rubber and/or diene base synthetic rubbers is compounded with 5 to 200 parts by mass, based on 100 parts of the rubber component, of silica and/or aluminum hydroxide and 0.5 to 15 parts by mass, based on 100 parts of the rubber component, of at least one of monoalkanolamides represented by the following Formula (I), wherein a compounding amount of the monoalkanolamide represented by Formula (I) is 0.5 to 20 parts by mass based on 100 parts by mass of the silica and/or the aluminum hydroxide:

wherein in Formula (I), R 1 represents an alkyl group or an alkenyl group having 1 to 13 carbon atoms, and the alkyl group and alkenyl group may be any of a linear type, a branched type and a cyclic type; and R 2 represents a hydroxyalkyl group or a hydroxyalkyl group having an oxyalkylene unit, and
wherein the total amount of the natural rubber and/or diene base synthetic rubbers and the silica and/or aluminum hydroxide is 67.34% to 79.37% by mass based on the entire mass of the rubber composition.

16. The method of reducing a viscosity of unvulcanized rubber as described in claim 15 , wherein in Formula (I), R 1 is at least one selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, isobutyl, t-butyl, pentyl, isopentyl, hexyl, isoheptyl, 2-ethylhexyl, octyl, nonyl, isononyl, decyl, undecyl, dodecyl, tridecyl and isotridecyl.

17. The method of reducing a viscosity of unvulcanized rubber as described in claim 15 , wherein in Formula (I), R 1 is an alkyl group or an alkenyl group having 6 to 13 carbon atoms.

Assignees

• Yagi Reiko
• Fujiki Kumi
• Takano Tetsuo
• Tsuchihashi Masaaki
• Bridgestone Corp
• Kao Corp

Inventors

• Yagi Reiko
• Fujiki Kumi
• Takano Tetsuo
• Tsuchihashi Masaaki

Classifications

• C08L7/00

  Compositions of natural rubber · CPC title

• B60C1/00

  Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition · CPC title

• C08L9/00

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08K5/20 Primary

  Carboxylic acid amides · CPC title

• C08L21/00

  Compositions of unspecified rubbers · CPC title