Amic acids and imides derived from terpolymers

Patent metadata

Field	Value
Publication number	US-9868798-B2
Application number	US-201515126173-A
Country	US
Kind code	B2
Filing date	Mar 17, 2015
Priority date	Mar 17, 2014
Publication date	Jan 16, 2018
Grant date	Jan 16, 2018

Abstract

The present invention provides amic acids and imides derived from a polymer comprising: (a) maleic anhydride, (b) a first C 1 -C 7 alkyl vinyl ether monomer, and (c) a second C 8 -C 30 alkyl vinyl ether monomer, wherein the polymer contains an amic acid or an imide group. The polymers containing an amic acid or an imide group of the invention may be employed in a wide variety of compositions, particularly in oral care compositions. Non-limiting generic structures of the amidic polymers are set out below: (I) wherein R 1 -R 3 , M, a, b, c, d, e, and f are defined herein.

First claim

We claim:

1. The polymer comprising:
(a) a first repeating unit selected from the group consisting of:

and combinations thereof, and
(b) a second repeating unit selected from the group consisting of:

and combinations thereof, wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, R 3 is a C 1 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium salts, and combinations thereof.

2. The polymer according to claim 1 , further comprising a repeating unit selected from the group consisting of:

and combinations thereof; wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium salts, and combinations thereof.

3. The polymer according to claim 2 , wherein R 1 is CH 3 , R 2 is C 12 H 25 , R 3 is selected from the group consisting of C 4 H 9 , C 8 H 17 , C 12 H 25 , and C 16 H 33 , and M is H or Na.

4. The polymer according to claim 2 , wherein the polymer is represented by the following structure:

wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, R 3 is a C 1 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium salts, and combinations thereof, wherein a, b, c, d, e, and f are molar amounts, the sum of which equals 100%, providing that c and d are not both zero at the same time.

5. The polymer according to claim 4 , wherein the polymer is represented by the following structure:

wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, R 3 is a C 1 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium salts, and combinations thereof, wherein a, b, c, d, e, and f are molar amounts, the sum of which equals 100%, providing that c and d are not both zero at the same time and e and f are not both zero at the same time.

6. The polymer according to claim 4 , selected from the group consisting of:

7. A composition comprising a polymer comprising: (a) maleic anhydride, (b) a first C 1 -C 7 alkyl vinyl ether monomer, and (c) a second C 8 -C 30 alkyl vinyl ether monomer, wherein the polymer contains an amic acid or an imide group.

8. The composition according to claim 7 , comprising:
(a) a first repeating unit selected from the group consisting of:

and combinations thereof, and
(b) a second repeating unit selected from the group consisting of:

and combinations thereof, wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, R 3 is a C 1 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium salts, and combinations thereof.

9. The composition according to claim 8 , further comprising a repeating unit selected from the group consisting of:

and combinations thereof; wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals alkaline earth metals, ammonium salts, and combinations thereof.

10. The composition according to claim 9 , wherein R 1 is CH 3 , R 2 is C 12 H 25 , R 3 is selected from the group consisting of C 4 H 9 , C 8 H 7 , C 2 H 25 , and C 16 H 33 , and M is H or Na.

11. The composition according to claim 9 , wherein the polymer is represented by the following structure:

wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, R 3 is a C 1 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium salts, and combinations thereof, wherein a, b, c, d, e, and f are molar amounts, the sum of which equals 100%, providing that c and d are not both zero at the same time.

12. The composition according to claim 11 , wherein the polymer is represented by the following structure:

wherein R 1 is a C 1 -C 7 alkyl group, R 2 is a C 8 -C 30 alkyl group, R 3 is a C 1 -C 30 alkyl group, and M is selected from the group consisting of hydrogen, alkali metals, alkaline earth metals, ammonium salts, and combinations thereof, wherein a, b, c, d, e, and f are molar amounts, the sum of which equals 100%, providing that c and d are not both zero at the same time and e and f are not both zero at the same time.

13. The composition according to claim 11 , selected from the group consisting of:

14. The composition according to claim 7 , wherein the composition is selected from the group consisting of adhesives, aerosols, agricultural agents, anti-soil redeposition agents, battery agents, beverages, biocides, cementing agents, cleaning agents, coating agents, conductive materials, cosmetic agents, dental agents, detergents, dispersants, drugs, electronics, encapsulations, foods, hair sprays, household-industrial agents, inks and coatings, interlaminate adhesives, lithographic solutions, membrane additive agents, metal working fluids, oilfield agents, paints, paper agents, personal care agents, pharmaceuticals, pigments, plasters, plastics, printing agents, reactive biocides, reactive rheology modifiers, refractive index modifiers, sequestrants, soil release agents, static control agents, and wood-care agents.

15. The composition according to claim 14 , wherein the personal care agent composition is selected from the group consisting of adhesives, antiperspirants and deodorants, cosmetics, drug delivery systems, facial compositions, hair compositions, modified natural oils, oil compositions, oral care agents, pharmaceutical compositions, pigments, skin and tissue compositions, sun care products, tablet coatings, thermal protection, toothpaste compositions, transdermal patches, wear resistance, and wrinkle reduction.

Assignees

• Isp Investments Llc

Inventors

• Musa Osama M
• Nacharaju Krishnamurthy
• Grigoras Cristian

Classifications

• A61Q5/00

  Preparations for care of the hair · CPC title

• C08F22/36

  Amides or imides · CPC title

• C08F8/32 Primary

  by reaction with amines · CPC title

• A61K8/8164

  Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride) · CPC title

• A61Q19/10

  Washing or bathing preparations · CPC title