Process for the adhesive bonding of plastics pipes by means of (meth)acrylate adhesive

Patent metadata

Field	Value
Publication number	US-9868250-B2
Application number	US-201414299325-A
Country	US
Kind code	B2
Filing date	Jun 9, 2014
Priority date	Dec 9, 2011
Publication date	Jan 16, 2018
Grant date	Jan 16, 2018

Abstract

A process for the adhesive bonding of plastic pipes with and without a fitting by use of a (meth)acrylate adhesive and also corresponding pipe connections, are described.

First claim

What is claimed is:

1. A method for cohesively connecting plastic pipes to a fitting, comprising the steps of:
(a) applying a (meth)acrylate-containing adhesive onto at least one joining surface of the fitting and/or onto at least one joining surface of the pipe ends to be connected without swelling or dissolution of at least one joining surface therewith,
(b) sliding together the pipes and fitting, and
(c) allowing the adhesive to cure between the joining surface(s).

2. A method for cohesively connecting plastic pipes according to claim 1 , wherein the pipe connection is achieved by joining a first pipe end together with a second pipe end, wherein one pipe end represents a receiving pipe part and the other pipe end represents an insertion pipe part, wherein prior to sliding the pipe ends together, an adhesive is applied onto at least one of the joining surfaces to be connected together, and after the pipe ends have been slid together, the adhesive is allowed to cure.

3. The method according to claim 1 , characterized in that the adhesive is applied by an application tool, in particular by brush coating.

4. The method according to claim 1 , characterized in that the adhesive film thickness on the joining surface before assembly ranges from 0.1 mm to 3 mm.

5. The method according to claim 1 , characterized in that the pipe and fitting or pipe and pipe are slid together without twisting.

6. The method according to claim 1 , wherein the plastic pipes are made from thermoplastics.

7. The method according to claim 1 , wherein the parts to be joined are made of different plastic materials.

8. The method according to claim 1 , wherein the adhesive comprises less than 10 wt % solvent.

9. The method according to claim 1 , wherein the plastic pipes are pressure pipes.

10. The method according to claim 1 , wherein the pipe connection is used for one or more of potable water lines, industrial water lines, or for pressure drainage.

11. The method according to claim 1 , wherein the adhesive comprises at least 40 wt % methyl acrylate.

12. The method according to claim 1 , wherein the adhesive comprises at least 50 wt % methyl acrylate.

13. The method according to claim 1 , wherein the adhesive comprises at least 60 wt % methyl acrylate.

14. The method according to claim 1 , wherein the adhesive comprises at least 70 wt % methyl acrylate.

15. The method according to claim 1 , wherein the adhesive comprises at least 90 wt % methyl acrylate.

16. The method according to claim 1 , wherein the adhesive comprises less than 10 wt %, less than 5 wt %, less than 2 wt %, or no solvent.

17. The method according to claim 1 , wherein the (meth)acrylate containing adhesive comprises:
a) methyl methacrylate in quantities of 30 to 60 wt %,
b) hydroxyethyl methacrylate, hydroxypropyl methacrylate or combinations thereof in a quantity of 5 to 15 wt %,
c) methacrylic acid in quantities of 0.5 to 10 wt %,
d) one or more tougheners,
e) a peroxide-based curing agent in a quantity of 0.1 to 5 wt %,
f) a catalyst, and
g) stabilizer in a quantity of 0.1 to 15 wt %, and
h) optionally thickening agents,
wherein the “wt %” indication is based in each case on the overall composition.

18. The method according to claim 17 , wherein the composition of the (meth)acrylate-containing adhesive is in a two part format in which, a first component (a) comprises:
(i) methyl methacrylate in quantities of 20 to 60 wt %, based on component (a),
(ii) a peroxide-based curing component in a quantity of 0.1 to 5 wt %, based on component (a),
(iii) stabilizer in a quantity of 0.1 to 5 wt %, based on component (a),
(iv) a toughener in a quantity of 5 to 50 %, based on component (a),
(v) a thickening agent in a quantity of 0.5 to 20 wt %, based on component (a), and
(vi) methacrylic acid in quantities of 1 to 5 wt %, based on component (a), and a second component (b) comprises:
(i) methyl methacrylate in quantities of 10 to 90 wt %, based on component (b),
(ii) a catalyst in a total quantity of 0.01 to 5 wt %, based on component (b),
(iii) a stabilizer in a quantity of 0.1 to 5 wt %, based on component (b),
(iv) a toughener in a quantity of 5 to 50 wt %, based on component (b), and
(v) a thickening agent in a quantity of 0.5 to 20 wt %, based on component (b).

19. A pipe network made up of at least two plastic pipes with or without a fitting insert between the pipe ends, suitable for potable water lines, industrial water lines, and/or for pressure drainage, wherein the joined surfaces of the joined parts connected to one another are attached with a (meth)acrylate-containing adhesive without swelling or dissolution of the joined surfaces.

20. The pipe network according to claim 19 , wherein the (meth)acrylate-containing adhesive comprises
a) methyl methacrylate in quantities of 30 to 60 wt %,
b) hydroxyethyl methacrylate, hydroxypropyl methacrylate or combinations thereof in a quantity of 5 to 15 wt %,
c) methacrylic acid in quantities of 0.5 to 10 wt %,
d) one or more tougheners to impact resistance improving components,
e) a peroxide-based curing agent in a quantity of 0.1 to 5 wt %,
f) a catalyst, and
g) stabilizer in a quantity of 0.1 to 15 wt %, and
h) optionally thickening agents,
wherein the “wt %” indication is based in each case on the overall composition.

Assignees

• Henkel Ag & Co Kgaa
• Henkel IP & Holding GmbH

Inventors

• Beuer Bernd
• Schoettmer Bernhard
• Kneafsey Brendan

Classifications

• B29C65/526

  by printing or by transfer from the surfaces of elements carrying the adhesive, e.g. using brushes, pads, rollers, stencils or silk screens · CPC title

• B29C66/1122

  Single lap to lap joints, i.e. overlap joints (B29C66/45, B29C66/472, B29C66/52272 take precedence) · CPC title

• B29C66/71

  characterised by the composition of the plastics material of the parts to be joined (welding bar compositions B29C65/125) · CPC title

• C09J2433/00

  Presence of (meth)acrylic polymer · CPC title

• C09J5/00

  Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers · CPC title