Electrode material, electrode, and lithium ion battery

Patent metadata

Field	Value
Publication number	US-9865876-B2
Application number	US-201514666935-A
Country	US
Kind code	B2
Filing date	Mar 24, 2015
Priority date	Oct 30, 2013
Publication date	Jan 9, 2018
Grant date	Jan 9, 2018

Abstract

An electrode material, an electrode, and a lithium ion battery in which it is possible to improve not only the amount of gas generated in the battery during charge and discharge but also the deterioration of battery components without reducing the charge and discharge capacity are provided. The electrode material is an electrode material including carbonaceous electrode active material complex particles which include a carbonaceous material on surfaces of electrode active material particles, in which an oxygen content rate in the carbonaceous material is 5.0% by mass or less, and a coating ratio of the carbonaceous material on the surfaces of the carbonaceous electrode active material complex particles is 60% or more.

First claim

What is claimed is:

1. An electrode material comprising carbonaceous electrode active material complex particles including a carbonaceous material film on surfaces of electrode active material particles, wherein
the water content of the carbonaceous electrode active material complex particles is 5% by mass or less,
the oxygen content of the carbonaceous material film is 4.2% by mass or less,
a coating ratio of the carbonaceous material film on the surfaces of the carbonaceous electrode active material complex particles is 60% or more,
the content of carbon in the carbonaceous electrode active material complex particles is in a range of 0.3% by mass to 8.0% by mass,
the electrode active material particles include one or more selected from the group consisting of lithium cobaltate, lithium nickelate, lithium manganate, lithium titanate, and Li x A y D z PO 4 as a main component, wherein A represents one or more selected from the group consisting of Co, Mn, Ni, Fe, Cu, and Cr; D represents one or more selected from the group consisting of Mg, Ca, S, Sr, Ba, Ti, Zn, B, Al, Ga, In, Si, Ge, Sc, Y, and rare earth elements; 0<x<2; 0<y<1.5; and 0≦z<1.5, and
the amount of oxygen in the carbonaceous material film is determined such that the electrode active material in the carbonaceous electrode active material complex particles is dissolved using a hydrochloric solution to obtain a carbonaceous substance, and the carbonaceous substance is washed using pure water and is vacuum-dried, and the amount of oxygen of the obtained dried substance is measured using an oxygen and nitrogen analyzer.

2. An electrode comprising the electrode material according to claim 1 .

3. A lithium ion battery comprising a cathode made of the electrode according to claim 2 .

4. The electrode material according to claim 1 , wherein the coating ratio of the carbonaceous material film on the surfaces of the carbonaceous electrode active material complex particles is 80% or more.

5. The electrode material according to claim 1 , wherein the water content of the carbonaceous electrode active material complex particles is 2.5% by mass or less.

6. The electrode material according to claim 1 , wherein an average particle diameter of primary particles of the electrode active material particles is in a range of 0.01 μm to 2 μm.

7. The electrode material according to claim 1 , wherein a specific surface area of the carbonaceous electrode active material complex particles is in a range of 1 m 2 /g to 80 m 2 /g.

8. The electrode material according to claim 1 , wherein the content of carbon in the carbonaceous electrode active material complex particles is in a range of 0.5% by mass to 5.0% by mass.

9. The electrode material according to claim 1 , wherein a shape of the electrode active material is spherical.

10. The electrode material according to claim 1 , wherein the electrode material is obtained by a process comprising the steps of:
preparing electrode active material or precursor of the active material, an organic compound and water,
mixing the electrode active material or the precursor, the organic compound and the water to form a slurry wherein a ratio of the particle diameter D90 of the electrode active material or the precursor to the particle diameter D10 of the electrode active material or the precursor is in a range of 5 to 30,
drying the slurry by spraying the slurry in the atmosphere of 70° C. to 250° C.,
firing the dried slurry at 500° C. to 1000° C. in a non-oxidative atmosphere for 0.1 hours to 40 hours, and
firing the fired slurry at 500° C. to 1000° C. in a reducing atmosphere for 0.1 hours to 40 hours.

11. The electrode material according to claim 10 , wherein the organic compound is at least one selected from the group consisting of polyvinyl alcohol, polyvinyl pyrrolidone, cellulose, starch, gelatin, carboxymethyl cellulose, methyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, polyacrylic acid, polystyrene sulfonate, polyacrylamide, polyvinyl acetate, glucose, fructose, galactose, mannose, maltose, sucrose, lactose, glycogen, pectin, alginic acid, glucomannan, chitin, hyaluronic acid, chondroitin, agarose, polyethers, divalent alcohols and trivalent alcohols.

12. The electrode material according to claim 10 , wherein the non-oxidative atmosphere is nitrogen or argon atmosphere.

13. The electrode material according to claim 10 , wherein the reducing atmosphere is a hydrogen atmosphere.

14. The electrode material according to claim 10 , wherein the shape of the electrode active material is spherical.

Assignees

• Sumitomo Osaka Cement Co Ltd

Inventors

• Mine Hiroyuki
• Kitagawa Takao

Classifications

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• Y02T10/7011

  Cross-Sectional Technologies · mapped topic

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title