Integrated methane refrigeration system for liquefying natural gas

Patent metadata

Field	Value
Publication number	US-9863697-B2
Application number	US-201514695521-A
Country	US
Kind code	B2
Filing date	Apr 24, 2015
Priority date	Apr 24, 2015
Publication date	Jan 9, 2018
Grant date	Jan 9, 2018

Abstract

Described herein is a method and system for liquefying a natural gas feed stream to produce an LNG product. The natural gas feed stream is liquefied, by indirect heat exchange with a gaseous methane or natural gas refrigerant circulating in a gaseous expander cycle, to produce a first LNG stream. The first LNG stream is expanded, and the resulting vapor and liquid phases are separated to produce a first flash gas stream and a second LNG stream. The second LNG stream is then expanded, with the resulting vapor and liquid phases being separated to produce the second flash gas stream and a third LNG stream, all or a portion of which forms the LNG product. Refrigeration is recovered from the second flash gas by using said stream to sub-cool the second LNG stream or a supplementary LNG stream.

First claim

The invention claimed is:

1. A method of liquefying a natural gas feed stream to produce a liquefied natural gas (LNG) product, the method comprising:
(a) liquefying the natural gas feed stream, by indirect heat exchange with a methane or natural gas refrigerant circulating as gaseous refrigerant in a gaseous expander cycle, to produce a first LNG stream;
(b) expanding the first LNG stream to further cool and partially vaporize the first LNG stream, and separating the resulting vapor and liquid phases to produce a first flash gas stream and a second LNG stream;
(c) expanding the second LNG stream to further cool and partially vaporize the second LNG stream, and separating the resulting vapor and liquid phases to produce a second flash gas stream and a third LNG stream, the LNG product comprising the third LNG stream or a portion thereof; and
(d) recovering refrigeration from the second flash gas stream by using the second flash gas stream to sub-cool, by indirect heat exchange
a first supplementary LNG stream, at least a portion of which is then expanded and separated to produce additional vapor and liquid for forming, respectively, the second flash gas stream and the third LNG stream.

2. The method of claim 1 , wherein the method further comprises:
(e) expanding the third LNG stream to further cool and partially vaporize the third LNG stream, and separating the resulting vapor and liquid phases to produce a third flash gas stream and a fourth LNG stream, the LNG product comprising the fourth LNG stream or a portion thereof; and
(f) recovering refrigeration from the third flash gas stream by using the third flash gas stream to sub-cool, by indirect heat exchange
a second supplementary LNG stream, formed from a sub-cooled portion of the first supplementary LNG stream, at least a portion of which is then expanded and separated to produce additional vapor and liquid for forming, respectively, the third flash gas stream and the fourth LNG stream.

3. The method of claim 2 , wherein step (d) comprises sub-cooling the first supplementary LNG stream by indirect heat exchange with both the second flash gas stream and the third flash gas stream.

4. The method of claim 1 , wherein the method further comprises recycling at least a portion of one or more of the flash gas streams by:
compressing said at least a portion of the flash gas stream(s) so as to form one or more recycle gas streams; and
liquefying one or more of said one or more recycle gas streams to produce one or more liquefied recycle streams.

5. The method of claim 4 , wherein the recycle gas stream(s) are liquefied: by indirect heat exchange with the methane or natural gas refrigerant circulating as gaseous refrigerant in a gaseous expander cycle; and/or by indirect heat exchange with at least a portion of one or more of the flash gas streams.

6. The method of claim 5 , wherein the methane or natural gas refrigerant and/or at least a portion of one or more of the flash gas streams provide all of the cooling duty for liquefying the recycle gas stream(s).

7. The method of claim 4 , wherein the method further comprises expanding and separating one or more of said one or more liquefied recycle streams to produce additional vapor and liquid for forming, respectively, the first flash gas stream and second LNG stream.

8. The method of claim 4 , wherein step (d) comprises sub-cooling, expanding and separating the first supplementary LNG stream in accordance with step (d), and wherein the first supplementary LNG stream comprises one or more of said one or more liquefied recycle streams.

9. The method of claim 1 , wherein at least a portion of methane or natural gas refrigerant circulating as gaseous refrigerant in the gaseous expander cycle is cooled, prior to being expanded to form cold gaseous refrigerant that is used in step (a) for liquefying the natural gas feed stream, by indirect heat exchange with at least a portion of one or more of the flash gas streams.

10. The method of claim 1 , wherein the methane or natural gas refrigerant circulates as gaseous refrigerant in a closed-loop gaseous expander cycle.

11. A system for liquefying a natural gas feed stream to produce a liquefied natural gas (LNG) product, the system comprising:
a first liquefier heat exchanger arranged and operable to receive the natural gas feed stream and a methane or natural gas refrigerant, and to liquefy the natural gas feed stream, by indirect heat exchange with the methane or natural gas refrigerant, to produce a first LNG stream;
a refrigeration circuit arranged and operable to circulate the methane or natural gas refrigerant as gaseous refrigerant in a gaseous expander cycle, the refrigeration circuit being connected to the first liquefier heat exchanger so as to pass the circulating gaseous refrigerant through the first liquefier heat exchanger;
a pressure reduction device and phase separation vessel arranged and operable to receive the first LNG stream, expand the first LNG stream so as to further cool and partially vaporize said stream, and separate the resulting vapor and liquid phases to produce a first flash gas stream and a second LNG stream;
a pressure reduction device and phase separation vessel arranged and operable to receive the second LNG stream, expand the second LNG stream so as to further cool and partially vaporize said stream, and separate the resulting vapor and liquid phases to produce a second flash gas stream and a third LNG stream, the LNG product comprising the third LNG stream or a portion thereof; and
a first sub-cooler heat exchanger arranged and operable to receive the second flash gas stream and recover refrigeration therefrom, the first sub-cooler heat exchanger being further arranged and operable to
receive and sub-cool, by indirect heat exchange with the second flash gas stream, a first supplementary LNG stream, prior to at least a portion of said stream being received by a pressure reduction device and phase separation vessel arranged and operable to expand and separate said at least a portion of the first supplementary LNG stream so to produce additional vapor and liquid for forming, respectively, the second flash gas stream and third LNG stream.

12. A system according to claim 11 , wherein the first sub-cooler heat exchanger is arranged and operable to receive the second flash gas stream and at least a portion of the second LNG stream, and to sub-cool said at least a portion of the second LNG stream, by indirect heat exchange with the second flash gas stream, prior to said second LNG stream being received by the pressure reduction device arranged and operable to expand said stream.

13. A system according to claim 11 , wherein the first liquefier heat exchanger is arranged such that in operation the only refrigerant that it receives is either the methane or natural gas refrigerant, or the methane or natural gas refrigerant and the at least a portion of one or more of the flash gas streams, so that in operation the methane or natural gas refrigerant, or the methane or natural gas refrigerant and the at least a portion of one or more of the flash gas streams, provides all of the cooling duty for liquefying the natural gas feed stream.

14. A system according to claim 11 , wherein the system further comprises:
a pressure reduction device and phase separation vessel arranged and operable to receive the third LNG stream, expand the third LNG stream so as to further cool and partially vaporize said stream, and separate the resulting vapor and liquid phases to produce a third flash gas stream and a fourth LNG stream, the LNG product comprising the fourth LNG stream or a portion

Assignees

• Air Prod & Chem

Inventors

• Roberts Mark Julian
• Liu Yang
• Chen Fei

Classifications

• F25J2230/08

  Cold compressor, i.e. suction of the gas at cryogenic temperature and generally without afterstage-cooler · CPC title

• F25J1/0022 Primary

  Hydrocarbons, e.g. natural gas · CPC title

• F25J1/0092

  Mixtures of hydrocarbons comprising possibly also minor amounts of nitrogen · CPC title

• F25J1/0202

  in a quasi-closed internal refrigeration loop (F25J1/0208, F25J1/0219, F25J1/0224 take precedence) · CPC title

• F25J1/0037

  of a return stream · CPC title