Additive composition for polymer-modified asphalt, polymer-modified asphalt composition comprising the same, and method for preparing the same

Patent metadata

Field	Value
Publication number	US-9862820-B2
Application number	US-201514797892-A
Country	US
Kind code	B2
Filing date	Jul 13, 2015
Priority date	Jul 15, 2014
Publication date	Jan 9, 2018
Grant date	Jan 9, 2018

Abstract

One aspect of the present invention provides an additive composition for polymer-modified asphalt including a block copolymer having a radial structure and a copolymer of an aromatic vinyl compound of which two ends have different molecular weights and a conjugated diene compound, and a method of preparing the same. When asphalt is prepared using the additive composition for polymer-modified asphalt, properties of the existing polymer-modified asphalt may be maintained while content of sulfur may be reduced, viscosity may decrease, and thereby processability and pavement performance may be improved.

First claim

What is claimed is:

1. An additive composition for polymer-modified asphalt, comprising:
a first copolymer compound having a radial structure and represented by the following Formula 1; and
a second copolymer compound represented by the following Formula 2:
(A-B) n X  [Formula 1]

A-B-B′-A′  [Formula 2]

wherein each of A and A′ is an aromatic vinyl compound, a molecular weight of A′ is higher than a molecular weight of A, each of B and B′ is a conjugated diene compound, n is one of the integers from 3to 6, X is a residue of a coupling agent, a molecular weight of the first copolymer compound is higher than a molecular weight of the second copolymer compound, and the molecular weight of the first copolymer compound is equal to or less than two times the molecular weight of the second copolymer compound.

2. The composition of claim 1 , wherein a content of the first copolymer compound is 5 to 50 wt % based on a total weight of the additive composition for polymer-modified asphalt.

3. The composition of claim 1 , wherein a molecular weight of the A′ is equal to or less than two times of the molecular weight of the A.

4. The composition of claim 1 , wherein the aromatic vinyl compound is one selected from the group consisting of styrene, α-methylstyrene, o-methylstyrene, p-methylstyrene, p-tert-butylstyrene, and a polymerized unit of at least one thereof.

5. The composition of claim 1 , wherein vinyl content of the B and the B′ each are 10 to 50 mol %.

6. The composition of claim 1 , wherein the conjugated diene compound is one selected from the group consisting of 1,3-butadiene, isoprene, and a polymerized unit of at least one thereof.

7. The composition of claim 1 , wherein the coupling agent is a diester compound, a triester compound or a mixture thereof.

8. The composition of claim 1 , wherein the coupling agent is one selected from the group consisting of dialkyl carbonate, dialkyl malonate, dialkyl phthalate, dialkyl succinate, dialkyl glutarate, dialkyl adipate, dialkyl pimelate, dialkyl suberate, dialkyl sebacate, dialkyl azelate, dialkyl brassylate, dialkyl tetradecandioate, dicarboxylate, tricarboxylate and a mixture of two or more thereof.

9. A polymer-modified asphalt composition, comprising:
asphalt; and
the additive composition for polymer-modified asphalt according to claim 1 .

10. The composition of claim 9 , wherein a weight ratio of the asphalt to the additive composition for polymer-modified asphalt is 100:1 to 10.

Assignees

• Korea Kumho Petrochemical Co Ltd

Inventors

• Kim Jae Yun
• Kim Tae Hee
• Jung Yeong Min

Classifications

• C08L95/00

  Compositions of bituminous materials, e.g. asphalt, tar, pitch · CPC title

• C08L95/005

  Aqueous compositions, e.g. emulsions · CPC title

• C08L2555/22

  Asphalt produced above 140°C, e.g. hot melt asphalt · CPC title

• C08L53/02 Primary

  of vinyl-aromatic monomers and conjugated dienes · CPC title

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title