Plastic article for automotive glazing

Patent metadata

Field	Value
Publication number	US-9862806-B2
Application number	US-201113224767-A
Country	US
Kind code	B2
Filing date	Sep 2, 2011
Priority date	Sep 6, 2010
Publication date	Jan 9, 2018
Grant date	Jan 9, 2018

Abstract

A plastic article is provided wherein a plastic substrate is coated with multiple resin layers including a primer layer comprising a polymer having a UV-absorptive functional group incorporated therein and a weather resistant hardcoat layer comprising a reaction product of alkoxysilyl-containing benzophenone and/or a hydrolyzate thereof.

First claim

The invention claimed is:

1. An automotive glazing, comprising a substrate and at least two resin layers on a surface of the substrate, wherein said at least two resin layers include a first or primer layer disposed adjacent the substrate surface and a second or hard top layer disposed on the first layer,
the first layer comprises a cured resin layer comprising a vinyl copolymer having alkoxysilyl and UV-absorptive groups and particulate silicon dioxide, wherein said cured resin layer is a cured product of a coating composition, said coating composition consisting of one or more organic solvents and
(i) a vinyl copolymer resin which is a copolymerization product of (a) 1 to 30% by weight of a vinyl monomer containing an organic UV-absorptive group, (b) 1 to 30% by weight of an alkoxysilyl-containing vinyl monomer, and (c) 40 to 98% by weight of another vinyl monomer, and, per 100 parts by weight of said vinyl copolymer resin,
(ii) 1 to 50 parts by weight of a dehydrating agent per 100 parts by weight of the vinyl copolymer resin content in the coating composition, and
(iii) 1 to 50 parts by weight of particulate silicon dioxide per 100 parts by weight of the vinyl copolymer resin,

wherein the organic UV absorptive group in said first layer does not bleed out, and
the second layer is a cured resin layer of a UV-absorptive coating composition comprising:
(1) (A) at least one hydrolysable silicon compound having the general formula (1):
R 1 a Si(OR 3 ) (4-a)   (1)

wherein R 1 is a C 1 -C 18 organic group, R 3 is each independently a C 1 -C 6 organic group, and a is an integer of 0 to 2, or a (partial) hydrolytic condensate thereof, and (B) a reactive UV absorber comprising an alkoxysilyl-containing benzophenone or a (partial) hydrolytic condensate thereof,
(2) 5 to 300 parts by weight of particulate silicon dioxide per 100 parts by weight of components (A) and (B) combined,
wherein components (1) and (2) are hydrolytic condensation products of components (A) and (B) and component (2) in the presence of an acidic catalyst,

(3) 3 to 100 parts by weight of a siloxane resin having the average compositional formula
(2) per 100 parts by weight of components (A), (B), and (2) combined:
R 2 b Si(OR 3 ) c (OH) d O (4-b-c-d)/2   (2)

wherein R 2 is each independently a C 1 -C 18 organic group, R 3 is each independently a C 1 -C 6 organic group, b, c, and d are numbers in the range: 0.8≦b≦1.5, 0≦c≦0.3, 0.001≦d≦0.5, and 0.801≦b+c+d<2, the siloxane resin being solid at or below 40° C. and having a weight average molecular weight of at least 2000, and
(4) 0.0001 to 30% by weight of a cure catalyst based on the solids content of components (1), (2), and (3),
wherein said dehydrating agent ensures that hydrolyzable silyl groups: remain stable in a solution from which said first or primer layer is formed; form crosslinks with hydrolyzable silyl groups and/or SiOH groups in the vinyl copolymer in the solution from which said first or primer layer is formed; and effectively bond with hydrolyzable silyl groups and/or SiOH groups in the second or hard top layer after coating formation.

2. The automotive glazing of claim 1 , wherein component (B) is a reactive UV absorber comprising an alkoxysilyl-containing benzophenone having the general formula (I):

wherein A 1 to A 10 are each independently hydrogen, hydroxyl, C 1 -C 5 alkyl, or a group of the general formula (II):
—O—(CH 2 ) m+2 —SiR 11 n (OR 12 ) 3-n   (II)

wherein R 11 and R 12 are each independently C 1 -C 5 alkyl, m is an integer of 1 to 5, and n is an integer of 0 to 2, at least one of A 1 to A 10 being a group of formula (II).

3. The automotive glazing of claim 1 , wherein the UV-absorptive coating composition further comprises (5) the reaction product of a titanium tetraalkoxide with a β-diketone and/or a hydrolytic condensate of a mixture of a titanium tetraalkoxide and a β-diketone.

4. The automotive glazing of claim 1 wherein the substrate comprises a polycarbonate resin.

5. The automotive glazing of claim 1 , wherein said dehydrating agent is selected from the group consisting of orthoformic esters, orthoacetic esters, and carbodiimides.

6. The automotive glazing of claim 5 , wherein said dehydrating agent is an orthoformic ester selected from the group consisting of methyl orthoformate, ethyl orthoformate, and propyl orthoformate.

Assignees

• Fukushima Motoo
• Higuchi Koichi
• Komori Hisatoshi
• Yamaya Masaaki
• Okumura Kazumasa
• Chigita Koichi
• Maruyama Yuya
• Takai Tomokazu
• Isobe Yasumitsu
• Kawamura Nobuya
• Nagai Takayuki
• Shinetsu Chemical Co
• Toyota Jidoshokki Kk
• Toyota Motor Co Ltd

Inventors

• Fukushima Motoo
• Higuchi Koichi
• Komori Hisatoshi
• Yamaya Masaaki
• Okumura Kazumasa
• Chigita Koichi
• Maruyama Yuya
• Takai Tomokazu
• Isobe Yasumitsu
• Kawamura Nobuya
• Nagai Takayuki

Classifications

• C08J7/0423

  with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder · CPC title

• C08J7/0427 Primary

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• C08J2400/108

  containing hydrolysable silane groups · CPC title

• C08J2433/04

  esters · CPC title

• Y10T428/31909

  Next to second addition polymer from unsaturated monomers · CPC title