Use of polymers as heterogeneous hydrogen donors for hydrogenation reactions

Patent metadata

Field	Value
Publication number	US-9862658-B2
Application number	US-201514934590-A
Country	US
Kind code	B2
Filing date	Nov 6, 2015
Priority date	Nov 6, 2014
Publication date	Jan 9, 2018
Grant date	Jan 9, 2018

Abstract

The present disclosure covers the use of polymers or copolymers having a naphthalene-type unit in their structure as heterogeneous hydrogen transfer agents for hydrogenation, hydrotreatment or reduction reactions. These heterogeneous hydrogen transfer agents may or may not be supported on metallic oxides and may be used in the presence of reducing agents such as hydrogen or methane. These hydrogen donors, being solid at the reaction temperature, may be recovered from the reaction mixture and reused, and are thermally and chemically stable at temperatures up to above 450° C.

First claim

Having thus described the invention, what we claim is:

1. A method for hydrogenation of organic compounds or mixtures of organic compounds, comprising:
a. hydrogenating an organic compound or mixture of organic compounds in the presence of at least one hydrogen donor;

wherein the hydrogen donor comprises at least one solid polymer or at least one copolymer containing a unit with two or more fused aromatic, alicyclic, or heterocyclic rings, or combinations thereof.

2. The method of claim 1 , wherein the promotion of hydrogen transfer reactions takes place at temperatures between 0 and 500° C.

3. The method of claim 1 , wherein said polymers or copolymers are physically and chemically stable at temperatures above the temperatures of the promoted hydrogen transfer reactions.

4. The method of claim 1 , wherein a hydrogen transfer reactions takes place in the presence or absence of a reducing agent.

5. The method of claim 1 , wherein a hydrogen transfer reaction takes place in the presence of hydrogen.

6. The method of claim 1 , wherein said polymers or copolymers are used without any solid support material.

7. The method of claim 1 , wherein said polymers or copolymers are supported on, anchored to or in physical mixture with appropriate solid materials.

8. The method of claim 1 , wherein said polymers or copolymers are used alone or in combination with catalysts.

Assignees

• Inst Mexicano Del Petróleo
• Mexicano Inst Petrol

Inventors

• Alemán Vázquez Laura Olivia
• Cano Domínguez José Luis
• Garciá Gutiérrez José Luis

Classifications

• C07C2601/16

  the ring being unsaturated · CPC title

• C07C2601/14

  The ring being saturated · CPC title

• C07C5/10 Primary

  of aromatic six-membered rings · CPC title

• C08G63/197

  containing condensed aromatic rings · CPC title

• C07C13/18

  with a cyclohexane ring · CPC title