Method for producing means with thermal resistance for applying at a surface of a heat exposed component

Patent metadata

Field	Value
Publication number	US-9862647-B2
Application number	US-201414488783-A
Country	US
Kind code	B2
Filing date	Sep 17, 2014
Priority date	Sep 20, 2013
Publication date	Jan 9, 2018
Grant date	Jan 9, 2018

Abstract

The invention refers to a method for producing means with thermal resist for applying at a surface of a heat exposed component. The method includes providing at least one mixture of at least two different inorganic powder materials:
with different chemical composition and thermal expansion coefficient, where at least one of the powder materials experiences volume changes due to crystallographic phase change at a given temperature, and/or\ where at least one of the two powder materials experiences volume changes due to chemical composition change,

forming the at least one mixture into a green body shape,

sintering the green body to obtain a ceramic body and

cooling the ceramic body and causing micro-cracking during heating and

or/sintering and/or cooling to obtain the means with thermal resist. The forming is performed such that a first mixture forming a first layer onto which a second mixture is applied forming a second layer differs in porosity from that first layer to obtain a layered green body.

First claim

The invention claimed is:

1. A method for producing means shaped as a tile with thermal resistance for applying at a surface of a heat exposed component; the method comprising:
providing at least two mixtures of at least two different inorganic powder materials with different chemical composition and thermal expansion coefficient,
forming the at least two mixtures into a green body,
sintering the green body formed from the at least two mixtures to obtain a ceramic body shaped as a tile,
cooling the ceramic body shaped as a tile, and
causing micro-cracking during heating and/or the sintering and/or the cooling to obtain the means shaped as a tile with thermal resistance,
wherein said forming is performed such that a first mixture forming a first layer is applied onto a second mixture forming a second layer to form the green body, the second layer differing in porosity from the first layer.

2. The method according to claim 1 , wherein the providing of the at least two mixtures is performed such that the at least two different inorganic powder materials differ from each other in at least one of the following properties: thermal expansion coefficient, crystallographic phase change, and chemical composition change during sintering and/or cooling.

3. The method according to claim 1 , further comprising:
after the causing of the micro-cracking and the cooling, performing at least one heat treatment cycle of further sintering that exposes the means with thermal resistance to a temperature of 1200° C. to 1600° C. and subsequent cooling for adjusting length and density of micro cracks.

4. The method according to claim 1 , wherein a volume change of the at least one powder material takes place during the sintering to cause the micro cracking.

5. The method according to claim 1 , wherein said forming of the at least two mixtures into a green body is performed such that the resulting means with thermal resistance has a rectangular plate-like shape having a thickness of between 3 mm to 6 mm and a surface area of between 1 cm 2 to 30 cm 2 .

6. The method according to claim 1 , further comprising after cooling, shaping the sintered ceramic body for applying on a surface of the heat exposed component.

7. The method according to claim 1 , wherein at least two different inorganic powder materials are selected from the following materials: Al 2 O 3 , ZrO 2 , BeO, TiO 2 , Al 2 TiO 5 , BaTiO 3 , SiO 2 , HfO, HfO 2 , MgO, Carbides and Nitrides of Al, Carbides and Nitrides of Zr, Carbides and Nitrides of Hf, Carbides and Nitrides of Si, Carbides and Nitrides of Mg, Carbides and Nitrides of Ti.

8. The method according to claim 1 , wherein the means shaped as a tile with thermal resistance are joined onto the surface of the heat exposed component by brazing.

9. The method according to claim 1 , wherein the heat exposed component is a component of a gas turbine arrangement being exposed to hot gases.

10. The method according to claim 1 , wherein said forming of the at least two mixtures into a green body is performed such that the resulting means with thermal resistance has a rectangular plate-like shape having a thickness between 1 mm to 10 mm and a surface area of between 1 cm 2 to 30 cm 2 .

11. The method according to claim 1 , wherein the means shaped as a tile with thermal resistance has a porosity of 1% to 40% by volume.

12. The method according to claim 1 , wherein the forming is performed such that a third mixture forming a third layer is applied onto the second layer to form the green body such that the first layer forms a top of the green body, and the third layer forms a bottom of the green body and the second layer is between the first and third layers, the second layer having a porosity that is greater than a porosity of the first layer and is also greater than a porosity of the third layer.

13. A method for producing means shaped as a tile with thermal resistance for applying at a surface of a heat exposed component; the method comprising:
providing at least two mixtures of at least two different inorganic powder materials where at least one of the powder materials experiences volume changes due to crystallographic phase change at a given temperature,
forming the at least two mixtures into a green body,
sintering the green body formed from the at least two mixtures to obtain a ceramic body shaped as a tile,
cooling the ceramic body shaped as a tile, and
causing micro-cracking during heating and/or the sintering and/or the cooling to obtain the means shaped as a tile with thermal resistance,
wherein said forming is performed such that a first mixture forming a first layer is applied onto a second mixture forming a second layer to form the green body, the second layer differing in porosity from the first layer.

14. The method according to claim 13 , wherein the volume changes due to crystallographic phase change at a given temperature based on a change of monoclinic to tetragonal crystal structure of the at least one of the at least two different inorganic powder materials.

15. The method according to claim 13 , wherein at least two different inorganic powder materials are selected from the following materials: ZrO 2 monoclinic, ZrO 2 cubic, ZrO 2 tetragonal, Al 2 O 3 alpha, Al 2 O 3 gamma, and Al 2 O 3 theta.

16. The method according to claim 13 , wherein the means shaped as a tile with thermal resistance has a porosity of 1% to 40% by volume; and the method also comprises:
after the causing of the micro-cracking and the cooling, performing at least one heat treatment cycle of further sintering that exposes the means with thermal resistance to a temperature of 1200° C. to 1600° C. and subsequent cooling for adjusting length and density of micro cracks.

17. The method according to claim 13 , wherein the forming is performed such that a third mixture forming a third layer is applied onto the second layer to form the green body such that the first layer forms a top of the green body, and the third layer forms a bottom of the green body and the second layer is between the first and third layers, the second layer having a porosity that is greater than a porosity of the first layer and is also greater than a porosity of the third layer.

18. A method for producing means with thermal resistance for applying at a surface of a heat exposed component; the method comprising:
providing at least two mixtures of at least two different inorganic powder materials where at least one of the at least two different inorganic powder materials experiences volume changes due to chemical composition change,
forming the at least two mixtures into a green body,
sintering the green body formed from the at least two mixtures to obtain a ceramic body shaped as a tile,
cooling the ceramic body shaped as a tile, and
causing micro-cracking during heating and/or the sintering and/or the cooling to obtain the means with thermal resistance,
wherein said forming is performed such that a first mixture forming a first layer is applied onto a second mixture forming a second layer to form the green body, the second layer differing in porosity from the first layer.

19. The method according to claim 18 , wherein the at least two different inorganic powder materials comprises at least a first inorganic powder material that comprises particles or agglomerates experiencing a non-reversible phase change during sintering resulting in a volume decrease, and at least a second inorganic powder material that comprises particles or agglomerates experiencing a non-reversible phase

Assignees

• Alstom Technology Ltd
• Ansaldo Energia Ip Uk Ltd

Inventors

• Stuer Michael
• Bossmann Hans-Peter

Classifications

• C04B35/10

  based on aluminium oxide · CPC title

• C04B2235/9607

  Thermal properties, e.g. thermal expansion coefficient · CPC title

• C04B37/001

  directly with other burned ceramic articles · CPC title

• C04B2235/95

  Products characterised by their size, e.g. microceramics · CPC title

• C04B35/48

  based on zirconium or hafnium oxides, zirconates, {zircon} or hafnates · CPC title