Additive manufacturing of short and mixed fibre-reinforced polymer

Patent metadata

Field	Value
Publication number	US-9862140-B2
Application number	US-201514802105-A
Country	US
Kind code	B2
Filing date	Jul 17, 2015
Priority date	Jul 17, 2015
Publication date	Jan 9, 2018
Grant date	Jan 9, 2018

Abstract

Additive manufacturing of a fiber-reinforced polymer (FRP) product using an additive manufacturing print head; a reservoir in the additive manufacturing print head; short carbon fibers in the reservoir, wherein the short carbon fibers are randomly aligned in the reservoir; an acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin in the reservoir, wherein the short carbon fibers are dispersed in the acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin; a tapered nozzle in the additive manufacturing print head operatively connected to the reservoir, the tapered nozzle produces an extruded material that forms the fiber-reinforced polymer product; baffles in the tapered nozzle that receive the acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin with the short carbon fibers dispersed in the acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin; and a system for driving the acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin with the short carbon fibers dispersed in the acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin from the reservoir through the tapered nozzle wherein the randomly aligned short carbon fibers in the acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin are aligned by the baffles and wherein the extruded material has the short carbon fibers aligned in the acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin that forms the fiber-reinforced polymer product.

First claim

The invention claimed is:

1. An apparatus for additive manufacturing a fibre-reinforced polymer product, comprising:
an additive manufacturing print head;
a reservoir in said additive manufacturing print head; short carbon fibers in said reservoir, wherein said short carbon fibers are randomly aligned in said reservoir;
an acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin in said reservoir, wherein said short carbon fibers are dispersed in said acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin;
a tapered nozzle in said additive manufacturing print head operatively connected to said reservoir, said tapered nozzle producing an extruded material that forms the fibre-reinforced polymer product;
baffles in said tapered nozzle that receive said acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin with said short carbon fibers dispersed in said acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin;
a system for driving said acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin with said short carbon fibers dispersed in said acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin from said reservoir through said tapered nozzle wherein said randomly aligned short carbon fibers in said acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin are aligned by said baffles and wherein said extruded material has said short carbon fibers aligned in said acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin that forms said fibre-reinforced polymer product;
holes in said tapered nozzle for allowing flow of said acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin out of said tapered nozzle; and
a sheath around said tapered nozzle for the collection said acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin that flows out of said holes in said tapered nozzle.

2. The apparatus for additive manufacturing a fibre-reinforced polymer product of claim 1 further comprising a curing system operatively connected to said additive manufacturing print head that directs curing energy onto said extruded material.

3. The apparatus for additive manufacturing a fibre-reinforced polymer product of claim 2 wherein said curing system operatively connected to said additive manufacturing print head that directs curing energy onto said extruded material is an ultra violet light curing system that directs ultra violet light energy onto said extruded material.

4. The apparatus for additive manufacturing a fibre-reinforced polymer product of claim 2 wherein said curing system operatively connected to said additive manufacturing print head that directs curing energy onto said extruded material is a heat curing system that directs heat energy onto said extruded material.

5. The apparatus for additive manufacturing a fibre-reinforced polymer product of claim 1 wherein said tapered nozzle has a taper in over the range of 1-45 degrees symmetrical.

6. The apparatus for additive manufacturing a fibre-reinforced polymer product of claim 1 wherein said tapered nozzle has a first taper section and a second non-tapered section.

7. The apparatus for additive manufacturing a fibre-reinforced polymer product of claim 1 wherein said system for driving said acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin and said short carbon fibers through said tapered nozzle in a manner to rheologically match said resin and said short carbon fibers.

8. The apparatus for additive manufacturing a fibre-reinforced polymer product of claim 7 further comprising an inorganic filler with said acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin and said short carbon fibers.

9. The apparatus for additive manufacturing a fibre-reinforced polymer product of claim 8 wherein said inorganic filler is silica.

10. The apparatus for additive manufacturing a fibre-reinforced polymer product of claim 1 wherein said acrylate, methacrylate, epoxy, cyanate ester or isocyanate resin is an epoxy resin.

Assignees

• Lawrence Livermore Nat Securty Llc
• L Livermore Nat Security Llc

Inventors

• Lewicki James
• Duoss Eric B
• Rodriguez Jennifer Nicole
• Worsley Marcus A
• King Michael J

Classifications

• B29C64/165

  using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber · CPC title

• B29K2307/04

  Carbon · CPC title

• B33Y30/00

  Apparatus for additive manufacturing; Details thereof or accessories therefor · CPC title

• B29C64/209 Primary

  Heads; Nozzles · CPC title

• B33Y10/00 Primary

  Processes of additive manufacturing · CPC title