Multilayer optical adhesives and methods of making same

Patent metadata

Field	Value
Publication number	US-9862124-B2
Application number	US-201414335326-A
Country	US
Kind code	B2
Filing date	Jul 18, 2014
Priority date	Jul 18, 2014
Publication date	Jan 9, 2018
Grant date	Jan 9, 2018

Abstract

A multilayer optical adhesive including a first viscoelastic or elastomeric adhesive layer and a second viscoelastic or elastomeric adhesive layer. A crosslinked or soluble resin layer may be disposed between the first viscoelastic or elastomeric adhesive layer and the second viscoelastic or elastomeric adhesive layer or the first viscoelastic or elastomeric adhesive layer may be immediately adjacent to the second viscoelastic or elastomeric adhesive layer. An interface between immediately adjacent layers is structured and there is a difference in refractive indices across the interface.

First claim

What is claimed is:

1. An optical adhesive comprising:
a first viscoelastic or elastomeric adhesive layer having a first refractive index n 1 ;
a first crosslinked or soluble resin layer immediately adjacent the first viscoelastic or elastomeric adhesive layer, the first crosslinked or soluble resin layer having a second refractive index n 2 different from the first refractive index n 1 ;
a second viscoelastic or elastomeric adhesive layer immediately adjacent the first crosslinked or soluble resin layer opposite the first viscoelastic or elastomeric adhesive layer;
wherein a first interface between the first viscoelastic or elastomeric adhesive layer and the first crosslinked or soluble resin layer is structured and wherein each of the first viscoelastic or elastomeric adhesive layer, the first crosslinked or soluble resin layer and the second viscoelastic or elastomeric adhesive layer are substantially transmissive,
wherein the first interface includes a grating having a peak to valley height h and a pitch and wherein h multiplied by |n 1 −n 2 | is in a range of about 150 nm to about 350 nm and the pitch is in a range of about 2 microns to about 50 microns.

2. The optical adhesive of claim 1 , wherein a second interface between the first crosslinked or soluble resin layer and the second viscoelastic or elastomeric adhesive layer is structured.

3. The optical adhesive of claim 1 , wherein the first viscoelastic or elastomeric adhesive layer is a first viscoelastic optically clear adhesive and the second viscoelastic or elastomeric adhesive layer is a second viscoelastic optically clear adhesive.

4. The optical adhesive of claim 1 , wherein a refractive index contrast across the first interface is at least 0.001 and less than about 0.5.

5. The optical adhesive of claim 1 , wherein the first crosslinked or soluble resin layer is substantially continuous.

6. The optical adhesive of claim 1 , wherein the first crosslinked or soluble resin layer is discontinuous.

7. The optical adhesive of claim 6 , wherein the first crosslinked or soluble resin layer comprises a plurality of discrete objects in a pattern.

8. The optical adhesive of claim 1 , wherein the first crosslinked or soluble resin layer comprises a first sublayer immediately adjacent the first viscoelastic or elastomeric resin layer and a second sublayer immediately adjacent the first sublayer and immediately adjacent the second viscoelastic or elastomeric adhesive layer, wherein the first sublayer has a first refractive index and the second sublayer has a second refractive index different from the first refractive index of the first sublayer and a second interface between the first sublayer and the second sublayer is structured.

9. The optical adhesive of claim 1 , further comprising a second crosslinked or soluble resin layer immediately adjacent the second viscoelastic or elastomeric adhesive layer opposite the first crosslinked or soluble resin layer.

10. The optical adhesive of claim 9 , further comprising a third viscoelastic or elastomeric adhesive layer immediately adjacent the second crosslinked or soluble resin layer opposite the second viscoelastic or elastomeric adhesive layer.

11. The optical adhesive of claim 10 , wherein at least two of the first interface, a second interface between the first crosslinked or soluble resin layer and the second viscoelastic or elastomeric adhesive layer, a third interface between the second crosslinked or soluble resin layer and the second viscoelastic or elastomeric adhesive layer, and a fourth interface between the third viscoelastic or elastomeric adhesive layer and the second crosslinked or soluble resin are structured.

12. The optical adhesive of claim 11 , wherein the first, second, third and fourth interfaces includes a first grating extending in a first direction and a second grating extending in a second direction different from the first direction.

13. The optical adhesive of claim 1 , wherein at least one of the first viscoelastic or elastomeric adhesive layer, the first crosslinked or soluble resin layer, and the second viscoelastic or elastomeric adhesive layer includes a plurality of particles having a mean diameter in the range of about 0.5 microns to about 30 microns, and wherein an absolute value of a refractive index difference between particles in the plurality of particles and a medium in which they are located is in the range of about 0.001 to about 0.1.

Assignees

• 3M Innovative Properties Co

Inventors

• Radcliffe Marc D
• Hennen Daniel W
• Sitter Brett J
• Steiner Michael L
• Hoffend Jr Thomas R
• Sherman Audrey A
• Stradinger John J
• Benson Jr Olester

Classifications

• B29D11/0073

  Optical laminates · CPC title

• B29L2011/00

  Optical elements, e.g. lenses, prisms · CPC title

• B29C41/22 Primary

  Making multilayered or multicoloured articles · CPC title

• C09J7/20 Primary

  characterised by their carriers · CPC title

• C09J7/00 Primary

  Adhesives in the form of films or foils · CPC title