Multifunctional cerium-based nanomaterials and methods for producing the same

Patent metadata

Field	Value
Publication number	US-9861958-B2
Application number	US-201414307031-A
Country	US
Kind code	B2
Filing date	Jun 17, 2014
Priority date	Jun 17, 2013
Publication date	Jan 9, 2018
Grant date	Jan 9, 2018

Abstract

Embodiments relate to a cerium-containing nano-coating composition, the composition including an amorphous matrix including one or more of cerium oxide, cerium hydroxide, and cerium phosphate; and crystalline regions including one or more of crystalline cerium oxide, crystalline cerium hydroxide, and crystalline cerium phosphate. The diameter of each crystalline region is less than about 50 nanometers.

First claim

What is claimed is:

1. A cerium-containing nano-coating composition, the composition comprising:
an amorphous matrix including one or more of cerium oxide, cerium hydroxide, and cerium phosphate; and
crystalline regions including one or more of crystalline cerium oxide, crystalline cerium hydroxide, and crystalline cerium phosphate;
wherein the crystalline regions are embedded in the amorphous matrix, wherein the thickness of the amorphous matrix with embedded crystalline regions is at least 100 nanometers and the diameter of each crystalline region is less than 50 nanometers.

2. The composition of claim 1 , wherein cerium is present as both trivalent cerium (Ce(III)) and tetravalent cerium (Ce(IV)).

3. The composition of claim 2 , wherein the ratio of the Ce(III) species to the Ce(IV) species is between 0.1 to 1.0.

4. The composition of claim 2 , wherein the Ce(IV) species and Ce(III) species comprise a reversible redox couple.

5. The composition of claim 4 , wherein the Ce(IV)/Ce(III) redox couple is reversible at constant environmental conditions.

6. The composition of claim 2 , wherein Ce(III) content is increasable by up to 33 atomic percent via photocatalytic reduction of Ce(IV) species at ambient conditions.

7. The composition of claim 1 , wherein the composition is capable of self-healing surface cracks.

8. The composition of claim 1 , wherein an achievable band gap differential is 2.0 eV to 4.0 eV.

9. The composition of claim 8 , wherein the band gap is increasable by exposing the composition to sunlight at ambient temperatures and pressures.

10. The composition of claim 1 , wherein the composition is capable of absorbing light having a range of threshold absorption wavelengths up to 590 nanometers.

11. The composition of claim 1 , wherein the composition is capable of photocatalytically splitting water at ambient temperatures and pressures.

12. The composition of claim 1 , wherein the embedded crystalline regions are homogenously distributed in the amorphous matrix.

Assignees

• Univ Missouri

Inventors

• O'Keefe Matthew J
• Castano Londono Carlos E
• Fahrenholtz William G

Classifications

• C23C22/56

  Treatment of aluminium or alloys based thereon · CPC title

• C23C22/83

  Chemical after-treatment · CPC title

• C22C21/10

  with zinc as the next major constituent · CPC title

• B01J37/0219

  the coating containing organic compounds · CPC title

• B01J37/035

  Precipitation on carriers · CPC title