Process for continuous recovering (meth)acrylic acid and apparatus for the process

Patent metadata

Field	Value
Publication number	US-9861908-B2
Application number	US-201414914218-A
Country	US
Kind code	B2
Filing date	Aug 13, 2014
Priority date	Aug 30, 2013
Publication date	Jan 9, 2018
Grant date	Jan 9, 2018

Abstract

This disclosure relates to a method of continuous recovery of (meth)acrylic acid and an apparatus used for the recovery method. The method of continuous recovery of (meth)acrylic acid according to the present invention may effectively remove scum, thus enabling stable operation of the continuous process.

First claim

The invention claimed is:

1. A method of continuous recovery of (meth)acrylic acid, comprising:
an extraction process wherein a (meth)acrylic acid aqueous solution is contacted with an extraction solvent in an extraction column to obtain a (meth)acrylic acid extract solution through an upper outlet of the extraction column and a raffinate solution passing through a lower stationary section of the extraction column through the lower outlet; and
a distillation process wherein a feed containing the (meth)acrylic acid extract solution is distilled to obtain (meth)acrylic acid,
wherein the raffinate solution containing scum that is accumulated at an interface between an organic phase and an aqueous phase formed by phase separation of the raffinate solution in the lower stationary section of the extraction column is discharged through a side stream located at any one point of the lower stationary section and filtered, and a filtrate is inflowed through a side stream located at any other point of the lower stationary section.

2. The method according to claim 1 , wherein the extraction process is conducted such that the interface between the organic phase and the aqueous phase formed by phase separation of the raffinate solution is formed at the side stream located at any one point of the lower stationary section of the extraction column.

3. The method according to claim 1 , wherein discharging of the raffinate solution containing scum and filtering through the side streams of the extraction column are conducted continuously or discontinuously.

4. The method according to claim 1 , wherein the outflow direction of the raffinate solution containing scum through the side stream of the extraction column and the inflow direction of the filtrate through the side stream of the extraction column are opposite to each other.

5. The method according to claim 1 , wherein the filtering is conducted using a filter having pores with an average diameter of 50 μm or less.

6. The method according to claim 1 , wherein the method further comprises:
an absorption process wherein a mixed gas including (meth)acrylic acid, organic by-products, and water vapor, which is produced by a synthesis reaction of (meth)acrylic acid, is contacted with an absorption solvent including water to obtain a (meth)acrylic acid aqueous solution; and
the extraction process is carried out on the (meth)acrylic acid aqueous solution obtained through the absorption process; and
the distillation process is carried out on a feed containing the (meth)acrylic acid extract solution obtained through the extraction process to obtain (meth)acrylic acid.

7. The method according to claim 1 , wherein the method further comprises:
an absorption process wherein a mixed gas including (meth)acrylic acid, organic by-products, and water vapor, which is produced by a synthesis reaction of (meth)acrylic acid, is contacted with an absorption solvent including water to obtain a (meth)acrylic acid aqueous solution; and
the extraction process is carried out on a part of the (meth)acrylic acid aqueous solution obtained through the absorption process; and
the distillation process is carried out on a feed containing the remainder of the (meth) acrylic acid aqueous solution obtained through the absorption process and the (meth)acrylic acid extract obtained through the extraction process to obtain (meth)acrylic acid.

8. The method according to claim 6 , further comprising a step of filtering the raffinate solution obtained through the lower outlet of the extraction column.

9. The method according to claim 8 , wherein the filtering of the raffinate solution obtained through the lower outlet of the extraction column is conducted using a filter having pores with an average diameter of 10 μm or less.

10. The method according to claim 8 , wherein the filtrate obtained through the filtering is recycled to the absorption process and used as the absorption solvent.

Assignees

• Lg Chemical Ltd

Inventors

• Song Jong Hun
• Baek Se Won
• Yoo Sul Hee
• Min Yoon Jae

Classifications

• B01D11/04

  of solutions which are liquid · CPC title

• B01D3/00

  Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping ({evaporation in general, e.g. of liquids for gas phase reactions B01B1/005;} gas chromatography B01D15/08; destructive distillation C10B; preparation of alcoholic beverages by distillation C12H6/02) · CPC title

• C07C51/44 Primary

  by distillation · CPC title

• C07C57/04

  Acrylic acid; Methacrylic acid · CPC title

• B01D3/40

  Extractive distillation · CPC title