Thioxanthone aromatic amine compound and organic light emitting device using the same

Patent metadata

Field	Value
Publication number	US-9859509-B2
Application number	US-201514778077-A
Country	US
Kind code	B2
Filing date	Apr 22, 2015
Priority date	Mar 26, 2015
Publication date	Jan 2, 2018
Grant date	Jan 2, 2018

Abstract

The invention provides a thioxanthone aromatic amine compound and an organic light emitting device using the compound. The thioxanthone aromatic amine compound includes a compound expressed by formula (I) or formula (II):

where Ar 1 and Ar 2 each are selected from ammonia compounds with structures respectively expressed by formula (III) to formula (VII), or hydrogen atom,

thioxanthone aromatic amine compound of the invention has single structure, determinate molecular weight, and has better solubility and film-forming property, and also has low biochemical temperature and decomposition temperature, and stable film morphology.

First claim

What is claimed is:

1. A thioxanthone aromatic amine compound comprising: a compound expressed by formula (I):

where Ar 1 and Ar 2 each are selected from the ammonia compounds with the structures respectively expressed by the formula (III) to the formula (VII), and the Ar 1 and the Ar 2 having the same structure or having different structures,

2. The thioxanthone aromatic amine compound as claimed in claim 1 , wherein the thioxanthone aromatic amine compound is one selected from the group consisting of compounds P1, P5, P9, P11, P13, P21, P23, P25, P33, P35 and P37 respectively having the following structural formulas:

3. An organic light emitting device comprising: a substrate, an anode formed on the substrate, a hole injection layer formed on the anode, a hole transport layer formed on the hole injection layer, a plurality of light-emitting layers formed on the hole transport layer, an electron transport layer formed on the plurality of light-emitting layers, and a cathode formed on the electron transport layer; a material of the plurality of the light-emitting layers is one or more the thioxanthone aromatic amine compounds as claimed in claim 1 .

4. The organic light emitting device as claimed in claim 3 , wherein a material of the anode is indium tin oxide, an electron injection layer is provided between the cathode and the electron transport layer, a material of the cathode is aluminum, and a material of the electron injection layer is lithium fluoride.

5. The organic light emitting device as claimed in claim 4 , wherein a thickness of the anode is 95 nm, a thickness of the hole injection layer is 5 nm, a thickness of the hole transport layer is 20 nm, a thickness of the plurality of light-emitting layers is 35 nm, a thickness of electron transport layer is 55 nm, a thickness of the cathode is greater than 80 nm, and a thickness of the electron injection layer is 1 nm.

6. The organic light emitting device as claimed in claim 3 , wherein a material of the hole injection layer is 2,3,6,7,10,11-hexacyano-1,4,5,8,9,12-hexaazatriphenylenehexacabonitrile (HAT-CN) whose structural formula is:

a material of the hole transport layer is 4-(2-thiazolylazo)-phenyl-2-glycine (TAPC) whose structural formula is:

a material of the plurality of light-emitting layers is 1,3-di-carbazolyl benzene (mCP) doped with a thioxanthone aromatic amine compound P2, a structural formula of the 1,3-di-carbazolyl benzene (mCP) is

a structural formula of the thioxanthone aromatic amine compound P2 is:

a material of the electron transport layer is 1,3,5-tri[(3-pyridyl)-3-phenyl] benzene (TmPyPB) whose structural formula is:

7. An organic light emitting device comprising: a substrate, an anode formed on the substrate, a hole injection layer formed on the anode, a hole transport layer formed on the hole injection layer, a plurality of light-emitting layers formed on the hole transport layer, an electron transport layer formed on the plurality of light-emitting layers, and a cathode formed on the electron transport layer; a material of the plurality of the light-emitting layers is one or more thioxanthone aromatic amine compounds as claimed in claim 1 ;
wherein, a material of the anode is indium tin oxide, an electron injection layer is provided between the cathode and the electron transport layer, a material of the cathode is aluminum, a material of the electron injection layer is lithium fluoride;
wherein, a material of the hole injection layer is 2,3,6,7,10,11-hexacyano-1,4,5,8,9,12-hexaazatriphenylenehexacabonitrile (HAT-CN) whose structural formula is:

a material of the hole transport layer is 4-(2-thiazolylazo)-phenyl-2-glycine (TAPC) whose structural formula is:

a material of the luminescent layer is 1,3-di-carbazolyl benzene (mCP) doped with a thioxanthone aromatic amine compound P2, a structural formula of the 1,3-di-carbazolyl benzene (mCP) is:

a structural formula of the thioxanthone aromatic amine compound P2 is:

a material of the electron transport layer is 1,3,5-tri[(3-pyridyl)-3-phenyl] benzene (TmPyPB) whose structural formula is:

8. The organic light emitting device as claimed in claim 7 , wherein a thickness of the anode is 95 nm, a thickness of the hole injection layer is 5 nm, a thickness of the hole transport layer is 20 nm, a thickness of the plurality of light-emitting layers is 35 nm, a thickness of electron transport layer is 55 nm, a thickness of the cathode is greater than 80 nm, and a thickness of the electron injection layer is 1 nm.

Assignees

• Shenzhen China Star Optoelect

Inventors

• Wang Yifan
• Zou Qinghua
• Su Shijian
• Liu Kunkun
• Wang Zhiheng
• Li Yunchuan

Classifications

• C07D409/10

  linked by a carbon chain containing aromatic rings · CPC title

• C07D417/14

  containing three or more hetero rings · CPC title

• C07D409/14 Primary

  containing three or more hetero rings · CPC title

• H01L51/5072

  Electricity · mapped topic

• C09K2211/1029

  containing one nitrogen atom as the heteroatom · CPC title