Cellulose nanofilaments and method to produce same

Patent metadata

Field	Value
Publication number	US-9856607-B2
Application number	US-201113105120-A
Country	US
Kind code	B2
Filing date	May 11, 2011
Priority date	May 11, 2010
Publication date	Jan 2, 2018
Grant date	Jan 2, 2018

Abstract

Cellulose nanofilaments from cellulose fibers, a method and a device to produce them are disclosed. The nanofilaments are fine filaments with widths in the sub-micron range and lengths up to a couple of millimeters. These nanofilaments are made from natural fibers from wood and other plants. The surface of the nanofilaments can be modified to carry anionic, cationic, polar, hydrophobic or other functional groups. Addition of these nanofilaments to papermaking furnishes substantially improves the wet-web strength and dry sheet strength much better than existing natural and synthetic polymers. The cellulose nanofilaments produced by the present invention are excellent additives for reinforcement of paper and paperboard products and composite materials, and can be used to produce superabsorbent materials.

First claim

The invention claimed is:

1. Cellulosic nanofilaments, wherein the nanofilaments are natural wood or plant fibers, the nanofilaments comprising:
a ratio of DP nanofilaments /DP initial is at least 0.75,
wherein DP nanofilaments is a degree of polymerization of the cellulosic nanofilaments and DP initial is an initial degree of polymerization of a source natural wood or plant fibers, the nanofilaments further comprising
a length of at least 100 μm, and
a width of about 30 to about 300 nm,
wherein the nanofilaments are physically detached from each other, and are substantially free of fibrillated cellulose,
wherein the nanofilaments have an apparent freeness value of over 700 ml according to Paptac Standard Testing Method C 1 , and,
wherein a suspension comprising 1% w/w nanofilaments in water at 25° C. under a shear rate of 100s −1 has a viscosity greater than 100 cps.

2. The nanofilaments according to claim 1 , wherein an aqueous suspension of over 0.1% w/w fails to settle according to a settling test described in GB 2 296 726.

3. The nanofilaments according to claim 1 , wherein an aqueous suspension of less than 0.05% w/w settles to 50% volume according to the settling test described in GB 2 296 726.

4. The nanofilaments according to claim 1 , wherein the length is between 100 μm and 500 μm.

5. The nanofilaments according to claim 1 , comprising a surface charge of at least 60meq/kg.

6. The nanofilaments according to claim 1 , wherein the ratio of DP nanofilament /DP initial is at least 0.80.

7. A mineral paper comprising at least 50% by weight of mineral filler and at least 1%, and up to 50% cellulose nanofilaments according to claim 1 .

8. The paper according to claim 7 , having mineral content up to 90%.

Assignees

• Hua Xujun
• Laleg Makhlouf
• Owston Thomas
• Fpinnovations

Inventors

• Hua Xujun
• Laleg Makhlouf
• Owston Thomas

Classifications

• D21H15/00

  Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution · CPC title

• D21B1/342

  Mixing apparatus · CPC title

• Y10T428/298

  Physical dimension · CPC title

• D21H21/10

  Retention agents or drainage improvers · CPC title

• D21H21/20 Primary

  Wet strength agents · CPC title