Process for manufacturing a surface-treated compacted material processable on a single screw plastics conversion equipment

Patent metadata

Field	Value
Publication number	US-9856378-B2
Application number	US-201013378911-A
Country	US
Kind code	B2
Filing date	Jun 22, 2010
Priority date	Jun 23, 2009
Publication date	Jan 2, 2018
Grant date	Jan 2, 2018

Abstract

The present invention relates to the field of processing thermoplastic polymers, particularly the present invention relates to a process for manufacturing compacted material suitable for the use in thermoplastic polymers without a compounding step, comprising the steps of a) providing at least one primary powder material; b) providing at least one molten surface treatment polymer; c) simultaneously or subsequently feeding the at least one primary powder material and the at least one molten surface treatment polymer into the high speed mixer unit of a cylindrical treatment chamber; d) mixing the at least one primary powder material and the at least one molten surface treatment polymer in the high speed mixer, e) transferring the mixed material obtained from step d) to a cooling unit, as well as the compacted material obtained by this process and its use in thermoplastic polymers.

First claim

The invention claimed is:

1. A process for manufacturing a surface-treated compacted material in the form of non-uniform conglomerates having a mean particle size of 10 μm to 10 mm, the process comprising the following steps:
a) providing at least one primary inorganic powder material at a temperature of between 20° C. and 300° C., wherein the at least one primary inorganic powder material is calcium carbonate that is optionally treated with a fatty acid;
b) providing at least one molten surface treatment polymer selected from the group consisting of an ethylene copolymer, an ethylene-1-octene copolymer, a metallocene based polypropylene, a polypropylene homopolymer, and an amorphous polypropylene homopolymer;
c) simultaneously or subsequently feeding the at least one primary inorganic powder material from step a) and the at least one molten surface treatment polymer from step b), and optionally at least one surface treatment agent, into a single screw high speed mixer;
d) mixing the at least one primary inorganic powder material and the at least one molten surface treatment polymer in the single screw high speed mixer at 400 to 4000 rpm so that the surface treatment polymer forms layers around and totally coats particles of the primary inorganic powder material;
e) optionally transferring the coated particles of the primary inorganic powder material obtained in step d) to a second single screw high speed mixer and mixing the same; and
f) cooling the coated particles of the primary inorganic powder material obtained from step d) or e) to directly obtain a surface-treated compacted material in the form of non-uniform conglomerates of the coated particles, wherein the non-uniform conglomerates have a mean particle size of 10 μm to 10 mm, and wherein the surface-treated compacted material (i) comprises 5 to 25 wt % of the surface treatment polymer and 75 to 95 wt % of the at least one primary inorganic powder, (ii) has a screen residue of more than 80 wt. % on a 45 μm screen, and (iii) is free flowing according to DIN-53492.

2. The process according to claim 1 , wherein at least one surface treatment agent is fed simultaneously with or after the feeding of the at least one primary inorganic powder material into the single screw high speed mixer.

3. The process according to claim 2 , wherein the temperature of the surface treatment agent is between 20° C. and 300° C.

4. The process according to claim 2 , wherein the temperature of the surface treatment agent is between 60° C. and 250° C.

5. The process according to claim 2 , wherein the temperature of the surface treatment agent is between 60° C. and 120° C.

6. The process according to claim 2 , wherein the surface treatment agent is stearic acid, zinc oxide, a synthetic paraffin wax, a polyethylene metallocene wax or a polypropylene wax.

7. The process according to claim 2 , wherein the surface-treated compacted material comprises 9.5 wt % of the surface treatment polymer, 0.5 wt % of the surface treatment agent, and 90 wt % of the at least one primary inorganic powder.

8. The process according to claim 2 , wherein the at least one surface treatment agent is present in the surface-treated compacted material at 0.5 to 5 wt %.

9. The process according to claim 1 , wherein the at least one molten surface treatment polymer is added to and mixed with the surface-treated material of step d) in the second single screw high speed mixer.

10. The process according claim 1 , wherein the temperature of the primary inorganic powder material is between 60° C. and 250° C.

11. The process according to claim 1 , wherein the inorganic powder is natural ground calcium carbonate (GCC), precipitated calcium carbonate (PCC), or a mixture of GCC and PCC.

12. The process according to claim 1 , wherein the inorganic powder is ground calcium carbonate (GCC) selected from marble, chalk, calcite and limestone.

13. The process according to claim 1 , wherein the inorganic powder is precipitated calcium carbonate (PCC) selected from aragonitic PCC, vateritic PCC, calcitic PCC, rhombohedral PCC, scalenohedral PCC, or any mixture thereof.

14. The process according to claim 1 , wherein the single screw high speed mixer operates at 1000 to 4000 rpm in step d).

15. The process according to claim 1 , wherein the single screw high speed mixer operates at 600 to 1300 rpm in step d).

16. The process according to claim 1 , wherein the single screw high speed mixer has a length:diameter ratio of 1:1 to 6:1.

17. The process according to claim 1 , wherein the single screw high speed mixer has a length:diameter ratio of 2:1 to 5:1.

18. The process according to claim 1 , wherein the single screw high speed mixer has a length:diameter ratio of 3:1 to 4:1.

19. The process according to claim 1 , wherein the at least primary inorganic powder material is calcium carbonate and is present in the surface-treated compacted material at 86 to 92 wt %.

20. The process according to claim 1 , wherein the surface-treated compacted material has a screen residue of more than 90 wt. % on a 45 μm screen.

21. The process according to claim 1 , wherein the at least one primary inorganic powder material and the at least one molten surface treatment polymer are mixed in the single screw high speed mixer in step d) at a peripheral speed of 4.7 to 18.8 m/s.

22. The process according to claim 1 , wherein the at least one primary inorganic powder material and the at least one molten surface treatment polymer are mixed in the single screw high speed mixer in step d) at a peripheral speed of 4.8 to 36.1 m/s.

23. The process according to claim 1 , wherein the at least one primary inorganic powder material and the at least one molten surface treatment polymer are mixed in the single screw high speed mixer in step d) at a peripheral speed of 4.7 to 10.2 m/s.

Assignees

• Ammann Ernst
• Knerr Michael
• Haldemann Peter
• Hersche Emil
• Omya Int Ag

Inventors

• Ammann Ernst
• Knerr Michael
• Haldemann Peter
• Hersche Emil

Classifications

• B29K2105/16

  Fillers · CPC title

• C08K3/26

  Carbonates; Bicarbonates · CPC title

• C09C3/10

  Treatment with macromolecular organic compounds {(C09C3/006 takes precedence)} · CPC title

• C08J3/223

  Packed additives · CPC title

• C08K3/18

  Oxygen-containing compounds, e.g. metal carbonyls · CPC title