Method for the production of ethylene oxide

Patent metadata

Field	Value
Publication number	US-9856227-B2
Application number	US-201715409784-A
Country	US
Kind code	B2
Filing date	Jan 19, 2017
Priority date	Mar 15, 2013
Publication date	Jan 2, 2018
Grant date	Jan 2, 2018

Abstract

A method for the production of ethylene oxide wherein the partial pressure of water vapor at the inlet of the reactor is at least about 8 kPa using a high purity carrier comprising alpha-alumina, a promoting amount of at least one Group IA metal, and a promoting amount of rhenium.

First claim

What is claimed is:

1. A method of producing ethylene oxide comprising:
a) providing to a reactor a reactor inlet gas mixture comprising ethylene, oxygen, one or more gas phase promoters, water and carbon dioxide, wherein the one or more gas phase promoters are organic chlorides, the components of the gas mixture subsequently being contacted within the reactor under epoxidation reaction conditions with a catalyst comprising a catalytically effective amount of silver supported on a high purity carrier, a promoting amount of at least one Group IA metal, and a promoting amount of rhenium;
b) yielding from the reactor a reactor outlet gas mixture comprising ethylene oxide, ethylene, oxygen, water and carbon dioxide;
c) providing at least a portion of the reactor outlet gas mixture to an ethylene oxide absorber to produce an ethylene oxide stream and a treated gas stream comprising water and carbon dioxide;
d) providing at least a portion of the treated gas stream to a carbon dioxide absorber unit;
e) operating the carbon dioxide absorber unit to produce a recycle gas stream comprising carbon dioxide and water; and
f) combining at least a portion of the recycle gas stream from the carbon dioxide absorber unit with fresh feeds comprising oxygen and ethylene and at least a portion of a remaining portion, if any, of the treated gas stream, to form the reactor inlet gas mixture, wherein:
(i) a partial pressure of water vapor at the reactor inlet is at least 13 kPa; and
(ii) the partial pressure of water vapor at the reactor inlet is continuously maintained at a value of at least 13 kPa over a period corresponding to the production of at least 250 kmole of ethylene oxide per cubic meter of catalyst.

2. The method of claim 1 , wherein the at least one Group IA metal comprises cesium and/or lithium.

3. The method of claim 1 , wherein the at least one Group IA metal comprises cesium and lithium.

4. The method of claim 1 , wherein the rate of ethylene oxide production per volume of catalyst is maintained or increased as compared to the rate of ethylene oxide production per volume of catalyst of the same catalyst under the same epoxidation reaction conditions except that the partial pressure of water vapor at the reactor inlet is less than 13 kPa.

5. The method of claim 4 , wherein the rate of ethylene oxide production per volume of catalyst is increased as compared to the rate of ethylene oxide production per volume of the same catalyst under the same epoxidation reaction conditions except that the partial pressure of water vapor at the reactor inlet is less than 13 kPa.

6. The method of claim 4 , wherein the selectivity of the reaction to ethylene oxide is maintained or increased as compared to the selectivity of the same catalyst under the same epoxidation reaction conditions except that the partial pressure of water vapor at the reactor inlet is less than 13 kPa.

7. The method of claim 6 , wherein the selectivity of the reaction to ethylene oxide is increased as compared to the selectivity of the same catalyst under the same epoxidation reaction conditions except that the partial pressure of water vapor at the reactor inlet is less than 13 kPa.

8. The method of claim 1 , wherein the partial pressure of water vapor at the reactor inlet is no more than 60 kPa.

9. The method of claim 1 , wherein the catalyst is a high selectivity catalyst.

Assignees

• Dow Technology Investments Llc

Inventors

• Zhang Liping
• Mcadon Mark H
• Frank Ernest R

Classifications

• C07C29/106

  of oxiranes · CPC title

• C07C29/00

  Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring · CPC title

• C07C213/02

  by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups · CPC title

• C07C41/02

  from oxiranes · CPC title

• C07C43/10

  of polyhydroxy compounds · CPC title