Regeneration of a heterogeneous catalyst in ethene oligomerization

Patent metadata

Field	Value
Publication number	US-9856184-B2
Application number	US-201615056147-A
Country	US
Kind code	B2
Filing date	Feb 29, 2016
Priority date	Mar 3, 2015
Publication date	Jan 2, 2018
Grant date	Jan 2, 2018

Abstract

The invention relates to the in situ regeneration of heterogeneous oligomerization catalysts which are used in the liquid phase oligomerization of ethene.

First claim

The invention claimed is:

1. A process for oligomerizing ethene over a heterogeneous catalyst and for regenerating said catalyst, the process comprising the steps of:
a) effecting the oligomerization in an oligomerization operation in which ethene, at least partly dissolved in a liquid solvent, is contacted with the heterogeneous catalyst;
b) effecting the regeneration of the heterogeneous catalyst in a regeneration operation in which the heterogeneous catalyst in the absence of ethene, hydrogen and oxygen is purged with a liquid purge medium, wherein the heterogeneous catalyst is a solid containing at least two components, the first component containing at least one element selected from Ni, Cr, Fe, or Ti, and being in metallic and/or oxidic and/or hydridic form;
c) alternating the oligomerization operation and regeneration operation over time, such that a time-limited oligomerization operation is followed by a time-limited regeneration operation, and the latter in turn by a time-limited oligomerization operation;
d) locating the heterogeneous catalyst in one same location;
e) supplying thermal energy to the location of the heterogeneous catalyst in order to impose a set temperature thereon; and
f) setting the set temperature in the regeneration operation higher than the set temperature in the oligomerization operation.

2. The process according to claim 1 , wherein both the liquid solvent and the liquid purge medium are selected from the alkenes having three to twelve carbon atoms or from the alkenes having three to ten carbon atoms or from mixtures thereof, this enumeration including the cycloalkenes.

3. The process according to claim 2 , wherein the liquid solvent and the liquid purge medium are identical.

4. The process according to claim 3 , wherein the liquid solvent and the liquid purge medium are one of the following substances or a mixture of two or more of these substances: propane, isobutane, pentane, cyclopentane, hexane, cyclohexane, heptane, cycloheptane.

5. The process according to claim 1 wherein the set temperature in oligomerization operation is between 20° C. and 130° C., and in that the set temperature in regeneration operation is between 80° C. and 1 50° C.; additionally with the proviso that the set temperature chosen in regeneration operation is higher than the set temperature in oligomerization operation.

6. The process according to claim 5 , wherein the oligomerization operation is effected under the following conditions:
Pressure: 0.1 MPa to 5 MPa
WHSV: 2 h −1 to 50 h −1
Ethene content in overall solution: 1% by weight to 50% by weight

and in that the regeneration operation is effected under the following conditions:
Pressure: 0.1 MPa to 5 MPa
WHSV: 2 h −1 to 50 h −1
Ethene content in overall solution: 0% by weight to 1% by weight.

7. The process according to claim 1 wherein the duration of a regeneration operation is shorter than the duration of the preceding oligomerization operation, in that the duration of the regeneration operation is less than 20% of the duration of the preceding oligomerization operation.

8. The process according to claim 1 wherein the location of the heterogeneous catalyst where the regeneration operation and the oligomerization operation are effected is a reactor through which a temperature control medium flows for the purpose of supplying thermal energy, and in that the set temperature is set by the feed temperature of the temperature control medium.

9. The process according to claim 1 wherein the liquid purge medium is circulated in regeneration operation, and in that the liquid purge medium circulated, away from the location of the heterogeneous catalyst, is purified with the aid of a separation apparatus to free it of at least some components dissolved in the liquid purge medium.

10. The process according to claim 9 , wherein the separation apparatus is a filter or a membrane or a cold trap, or a combination of two or more of these separation apparatuses.

11. The process according to claim 2 , wherein the liquid purge medium is an alkene having three to twelve carbon atoms, or a mixture of two or more such alkenes, or a mixture of one or more such alkenes with at least one alkane having three to seven carbon atoms, wherein the liquid purge medium in regeneration operation is drawn off from the location of the catalyst and—optionally after purification—conducted to a second heterogeneous catalyst remote from the catalyst to be regenerated, and in that at least one alkene present in the liquid purge medium is subjected to a chemical reaction over the second catalyst, a second oligomerization, an isomerization or an etherification or an oxidative dehydrogenation.

12. The process according to claim 2 , wherein the liquid purge medium is an alkane having three to seven carbon atoms or a mixture of two or more such alkanes, wherein the purge medium in regeneration operation is drawn off from the location of the heterogeneous catalyst and conducted to a second heterogeneous catalyst remote from the catalyst to be regenerated, and in that at least one alkane present in the purge medium is subjected to a chemical reaction over the second catalyst, a dehydrogenation to give alcohols and/or acid derivatives.

13. The process according to claim 1 , wherein the second component comprises at least one metal oxide selected from Al 2 O 3 , SiO 2 , TiO 2 , or ZrO 2 .

14. The process according to claim 1 , wherein less than 5% by weight of the ethene converted in oligomerization operation is converted to oligomers or polymers of ethene having sixteen or more than sixteen carbon atoms.

15. The process according to claim 1 , wherein the conversion of ethene is determined continuously in oligomerization operation, and in that there is then a changeover from oligomerization operation to regeneration operation when the conversion of ethene has dropped to a value between 95% and 100%.

16. The process according to claim 2 wherein the duration of a regeneration operation is shorter than the duration of the preceding oligomerization operation, in that the duration of the regeneration operation is less than 20% of the duration of the preceding oligomerization operation.

17. The process according to claim 2 wherein the location of the heterogeneous catalyst where the regeneration operation and the oligomerization operation are effected is a reactor through which a temperature control medium flows for the purpose of supplying thermal energy, and in that the set temperature is set by the feed temperature of the temperature control medium.

18. The process according to claim 2 wherein the liquid purge medium is circulated in regeneration operation, and in that the liquid purge medium circulated, away from the location of the heterogeneous catalyst, is purified with the aid of a separation apparatus to free it of at least some components dissolved in the liquid purge medium.

19. The process according to claim 3 , wherein the liquid purge medium is an alkene having three to twelve carbon atoms or a mixture of two or more such alkenes or a mixture of one or more such alkenes with at least one alkane having three to seven carbon atoms, wherein the liquid purge medium in regeneration operation is drawn off from the location of the catalyst and—optionally after purification—conducted to a second heterogeneous catalyst remote from the catalyst to be regenerated, and in that at least one alkene present in the liquid purge medium is subjected to a chemical reaction over the second heterogeneous catalys

Assignees

• Evonik Degussa Gmbh

Inventors

• Stochniol Guido
• Peitz Stephan
• Maschmeyer Dietrich
• Reeker Helene

Classifications

• B01J38/56 Primary

  Hydrocarbons · CPC title

• C07C41/06

  by addition of organic compounds only · CPC title

• C07C11/08

  with four carbon atoms · CPC title

• C07C2/12

  with crystalline alumino-silicates {or with catalysts comprising} molecular sieves · CPC title

• C07C2/24 Primary

  with metals · CPC title