Print media for inkjet printing

Patent metadata

Field	Value
Publication number	US-9855780-B2
Application number	US-201415109931-A
Country	US
Kind code	B2
Filing date	Jan 30, 2014
Priority date	Jan 30, 2014
Publication date	Jan 2, 2018
Grant date	Jan 2, 2018

Abstract

A print medium having a base substrate including a blend of cellulosic fibers, a sizing material present in an effective amount from about 0 Kg/Ton of the print medium to about 1 Kg/Ton of the print medium, and a multivalent cation salt present in a synergistic amount from about 4 Kg/Ton of the print medium to about 25 Kg/Ton of the print medium.

First claim

What is claimed is:

1. A print medium for inkjet printing comprising:
a base substrate comprising a blend of cellulosic fibers;
a sizing material present in an effective amount from about 0.25 Kg/Ton of the print medium to about 0.75 Kg/Ton of the print medium; and
a multivalent cation salt present in a synergistic amount from about 8 Kg/Ton of the print medium to about 24 Kg/Ton of the print medium.

2. The print medium of claim 1 , wherein the sizing material is alkyl succinic anhydride (ASA).

3. The print medium of claim 1 , wherein the multivalent cation salt is calcium chloride.

4. The print medium of claim 1 , wherein the synergistic amount of the multivalent cation salt ranges from about 8 Kg/Ton to about 20 Kg/Ton of the print medium.

5. The print medium of claim 1 , wherein the print medium has a Hercules Size Test (HST) in a range of about 0-10 seconds.

6. The print medium of claim 1 , wherein the print medium has a black optical density (KOD) of at least 1.15.

7. The print medium of claim 1 , wherein the effective amount of the sizing material achieves HST of about 0.3-4.5 seconds.

8. The print medium of claim 1 , wherein the sizing material is selected from a group consisting of starches, starch derivatives, carboxy methylcellulose (CMC), methyl cellulose, alginates, waxes, wax emulsions, alkylketene dimer (AKD), alkyl succinic anhydride (ASA), alkenyl ketene dimer emulsion (AnKD), emulsions of ASA with cationic starch, emulsions of AKD with cationic starch, ASA incorporating alum, polyvinyl alcohol, gelatin, acrylamide polymers, acrylic polymers, acrylic copolymers, vinyl acetate latex, polyesters, vinylidene chloride latex, styrene-butadiene, acrylonitrile butadiene copolymers, styrene acrylic copolymers, and combinations thereof.

9. The print medium of claim 1 , wherein the multivalent cation salt is selected from a group consisting of calcium chloride (CaCl 2 ), magnesium chloride (MgCl 2 ), aluminum chloride (AlCl 3 ), magnesium sulfate (MgSO 4 ), calcium acetate (Ca(C 2 H 3 O 2 ) 2 ), calcium propionate Ca(C 2 H 5 COO) 2 , calcium lactate C 6 H 10 CaO 6 .xH 2 O, calcium nitrate Ca(NO 3 ) 2 , and combinations thereof.

10. A method of preparing a print medium for inkjet printing, the method comprising:
obtaining a base substrate comprising a blend of hardwood (HW) fibers and softwood (SW) fibers in a ratio ranging from about 100% (HW):0% (SW) to about 30% (HW):70% (SW);
selecting a sizing material in an effective amount ranging from about 0.25 Kg/Ton to 0.75 Kg/Ton of the print medium;
selecting a multivalent cation salt in a synergistic amount ranging from about 8 Kg/Ton to 24 Kg/Ton of the print medium; and
adding the sizing material and the multivalent cation salt to the base substrate at a size press during a papermaking process to form the print medium.

11. The method of claim 10 , wherein the sizing material is selected from a group consisting of starches, starch derivatives, carboxy methylcellulose (CMC), methyl cellulose, alginates, waxes, wax emulsions, alkylketene dimer (AKD), alkyl succinic anhydride (ASA), alkenyl ketene dimer emulsion (AnKD), emulsions of ASA or AKD With cationic starch, ASA incorporating alum, polyvinyl alcohol, gelatin, acrylamide polymers, acrylic polymers or copolymers, vinyl acetate latex, polyesters, vinylidene chloride latex, styrene-butadiene, acrylonitrile butadiene copolymers, styrene acrylic copolymers, and various combinations thereof.

12. The method of claim 10 , wherein the multivalent cation salt is selected from a group consisting of calcium chloride (CaCl 2 ), magnesium chloride (MgCl 2 ), aluminum chloride (AlCl 3 ), magnesium sulfate (MgSO 4 ), calcium acetate (Ca(C 2 H 3 O 2 ) 2 ), calcium propionate Ca(C 2 H 5 COO) 2 , calcium lactate C 6 H 10 CaO 6 .xH 2 O, calcium nitrate Ca(NO 3 ) 2 and combinations thereof.

Assignees

• Hewlett Packard Development Co Lp

Inventors

• Stoffel Jr John L
• Courtenay Silke
• Oswald Thomas Roger

Classifications

• B41M5/5227

  characterised by organic non-macromolecular additives, e.g. UV-absorbers, plasticisers, surfactants · CPC title

• D21H17/66

  Salts, e.g. alums · CPC title

• D21H17/16

  Addition products thereof with hydrocarbons · CPC title

• B41M5/0035 Primary

  Uncoated paper (paper making D21) · CPC title