Image formation method, decorative sheet, decorative sheet molding, process for producing in-mold molded product, in-mold molded product, and ink set

Patent metadata

Field	Value
Publication number	US-9855693-B2
Application number	US-201414471056-A
Country	US
Kind code	B2
Filing date	Aug 28, 2014
Priority date	Aug 30, 2013
Publication date	Jan 2, 2018
Grant date	Jan 2, 2018

Abstract

The object of the present invention is to provide an image formation method that can give an image that is excellent in terms of adhesion to a substrate, blocking resistance of a resulting printed material, and molding suitability, in particular vacuum forming properties, and that can suppress post-molding cracking of a molding. Disclosed is an image formation method comprising, in order, Step a: a step of applying Liquid A to a substrate, Step b: a step of irradiating the applied Liquid A with actinic radiation so as to carry out complete curing or semi-curing up to a degree of cure of at least 90%, Step c: a step of applying Liquid B to a cured layer of the completely cured or semi-cured Liquid A, and Step d: a step of completely curing Liquid A and Liquid B.

First claim

What is claimed is:

1. An image formation method comprising, in order,
Step a: a step of applying Liquid A to a substrate,
Step b: a step of irradiating the applied Liquid A with actinic radiation so as to carry out complete curing or semi-curing up to a degree of cure of at least 90% to form a cured or semi-cured layer,
Step c: a step of applying Liquid B to the cured or semi-cured layer, and
Step d: a step of completely curing any remaining Liquid A and Liquid B,
Liquid A comprising N-vinylcaprolactam, a first aromatic ring-containing monofunctional acrylate, an aliphatic hydrocarbon ring-containing monofunctional acrylate, a first polysiloxane compound, an acrylic resin having a glass transition temperature of 40° C. to 90° C., a first photopolymerization initiator, and a pigment, the content of the acrylic resin having the glass transition temperature of 40° C. to 90° C. in Liquid A being at least 0.5 mass % but no greater than 5 mass %, and
Liquid B comprising N-vinylcaprolactam, a second aromatic ring-containing monofunctional acrylate, a second polysiloxane compound, a thermoplastic resin having a glass transition temperature of 70° C. to 110° C., and a second photopolymerization initiator, the content of the thermoplastic resin having the glass transition temperature of 70° C. to 110° C. in Liquid B being at least 20 mass % but no greater than 50 mass %.

2. The image formation method according to claim 1 , wherein Step a is carried out by inkjet printing.

3. The image formation method according to claim 1 , wherein Step c is carried out by roll coater printing and/or screen printing.

4. The image formation method according to claim 1 , wherein an interval between Step c and Step d is no greater than 10 seconds.

5. The image formation method according to claim 1 , wherein Liquid A further comprises a difunctional aliphatic urethane acrylate oligomer, and the content of the difunctional aliphatic urethane acrylate oligomer in Liquid A is at least 0.5 mass % but no greater than 3.0 mass %.

Assignees

• Fujifilm Corp

Inventors

• Umebayashi Tsutomu

Classifications

• B29C45/14688 Primary

  Coating articles provided with a decoration · CPC title

• C09D11/54

  Inks based on two liquids, one liquid being the ink, the other liquid being a reaction solution, a fixer or a treatment solution for the ink · CPC title

• B29C2035/0827

  using UV radiation · CPC title

• B29C2035/0833

  using actinic light · CPC title

• C09D11/40

  Ink-sets specially adapted for multi-colour inkjet printing · CPC title