Metal oxide nanorod arrays on monolithic substrates

Patent metadata

Field	Value
Publication number	US-9855549-B2
Application number	US-201214347850-A
Country	US
Kind code	B2
Filing date	Sep 28, 2012
Priority date	Sep 28, 2011
Publication date	Jan 2, 2018
Grant date	Jan 2, 2018

Abstract

A metal oxide nanorod array structure according to embodiments disclosed herein includes a monolithic substrate having a surface and multiple channels, an interface layer bonded to the surface of the substrate, and a metal oxide nanorod array coupled to the substrate surface via the interface layer. The metal oxide can include ceria, zinc oxide, tin oxide, alumina, zirconia, cobalt oxide, and gallium oxide. The substrate can include a glass substrate, a plastic substrate, a silicon substrate, a ceramic monolith, and a stainless steel monolith. The ceramic can include cordierite, alumina, tin oxide, and titania. The nanorod array structure can include a perovskite shell, such as a lanthanum-based transition metal oxide, or a metal oxide shell, such as ceria, zinc oxide, tin oxide, alumina, zirconia, cobalt oxide, and gallium oxide, or a coating of metal particles, such as platinum, gold, palladium, rhodium, and ruthenium, over each metal oxide nanorod. Structures can be bonded to the surface of a substrate and resist erosion if exposed to high velocity flow rates.

First claim

What is claimed is:

1. A metal oxide nanorod array structure comprising:
a honeycomb monolithic substrate having a surface and multiple channels;
an interface layer bonded to the surface of the substrate; and
a metal oxide nanorod array coupled to the substrate surface via the interface layer, wherein the metal oxide nanorod is formed of TiO 2 , CeO 2 , ZnO, SnO 2 , Al 2 O 3 , ZrO 2 , Co 3 O 4 , or Ga 2 O 3 .

2. The nanorod array structure of claim 1 , wherein the metal oxide nanorod array is vertically aligned relative to the surface of the substrate.

3. The nanorod array structure of claim 2 , wherein the metal oxide nanorod is formed of titania (TiO 2 ).

4. The nanorod array structure of claim 3 , wherein the titania is brookite titania.

5. The nanorod array structure of claim 1 , wherein the substrate is formed of plastic, silicon, ceramic or stainless steel.

6. The nanorod array structure of claim 4 , wherein the substrate is formed of ceramic.

7. The nanorod array structure of claim 6 , wherein the ceramic includes one of the following: cordierite, alumina, tin oxide, and titania.

8. The nanorod array structure of claim 1 , wherein the metal oxide nanorod includes one of the following: ceria (CeO 2 ), zinc oxide (ZnO), tin oxide (SnO2), alumina (Al 2 O 3 ), zirconia (ZrO 2 ), cobalt oxide (Co 3 O 4 ), and gallium oxide (Ga 2 O 3 ).

9. The nanorod array structure of claim 1 , further including a perovskite ABO 3 (A=La, Ba, Sr, and/or Pb, B=Co, Cr, Fe, Mn, or Ni) shell over each metal oxide nanorod.

10. The nanorod array structure of claim 9 , wherein the perovskite is a lanthanum-based transition metal oxide, LaMO 3 (M=Co, Cr, Fe, Mn, and Ni).

11. The nanorod array structure of claim 10 , wherein the lanthanum-based transition metal oxide is lanthanum strontium cobaltate.

12. The nanorod array structure of claim 10 , wherein the lanthanum-based transition metal oxide is lanthanum strontium manganate.

13. The nanorod array structure of claim 1 , further including a metal oxide shell over each metal oxide nanorod.

14. The nanorod array structure of claim 13 , wherein the shell includes one of the following metal oxides: ceria (CeO 2 ), zinc oxide (ZnO), tin oxide (SnO 2 ), alumina (Al 2 O 3 ), zirconia (ZrO 2 ), cobalt oxide (CO 3 O 4 ), and gallium oxide (Ga 2 O 3 ).

15. The nanorod array structure of claim 1 , further including an alkaline oxide shell over each metal oxide nanorod.

16. The nanorod array structure of claim 15 , wherein the alkaline oxide shell includes at least one of the following oxides: barium oxide and potassium oxide.

17. The nanorod array structure of claim 1 , further including a coating of metal particles over each metal oxide nanorod, the metal including at least one of the following: platinum, gold, palladium, rhodium, and ruthenium.

18. The nanorod array structure of claim 9 , further including a coating of metal particles over each metal oxide nanorod, the metal including at least one of the following: platinum, gold, palladium, rhodium, and ruthenium.

Assignees

• Univ Connecticut

Inventors

• Gao Pu-Xian
• Guo Yanbing
• Ren Zheng

Classifications

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J35/733

  Perovskite-type · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/45

  Nanoparticles · CPC title