Electrode, power storage device, electronic device, and vehicle

Patent metadata

Field	Value
Publication number	US-9852850-B2
Application number	US-201514802326-A
Country	US
Kind code	B2
Filing date	Jul 17, 2015
Priority date	Jul 18, 2014
Publication date	Dec 26, 2017
Grant date	Dec 26, 2017

Abstract

A power storage device with high capacity is provided. Alternatively, a power storage device with excellent cycle characteristics is provided. Alternatively, a power storage device with high charge and discharge efficiency is provided. Alternatively, a power storage device with a long lifetime is provided. A negative electrode active material is provided over a negative electrode current collector, and the negative electrode active material layer is formed in such a manner that first layers and second layers are alternately stacked. The first layer includes at least an element selected from Si, Mg, Ca, Ga, Al, Ge, Sn, Pb, Sb, Bi, Ag, Zn, Cd, As, Hg, and In. The second layer includes oxygen and the same element as the one included in the first layer.

First claim

What is claimed is:

1. An electrode comprising:
a current collector; and
an active material layer,
wherein the active material layer comprises first to fourth layers,
wherein the second layer is provided between the first layer and the third layer,
wherein the third layer is provided between the second layer and the fourth layer,
wherein the first layer is in contact with the current collector,
wherein the first layer comprises a first element which is selected from, Mg, Ca, Ga, Al, Ge, Sn, Pb, Sb, Bi, Ag, Zn, Cd, As, Hg, and In,
wherein the third layer comprises a second element which is selected from, Mg, Ca, Ga, Al, Ge, Sn, Pb, Sb, Bi, Ag, Zn, Cd, As, Hg, and In,
wherein the second layer comprises the first element or the second element,
wherein the second layer comprises at least one of oxygen, nitrogen, sulfur, phosphorus, and fluorine,
wherein the fourth layer comprises the first element or the second element, and
wherein the fourth layer comprises at least one of oxygen, nitrogen, sulfur, phosphorus, and fluorine.

2. The electrode according to claim 1 ,
wherein the first layer comprises Sn, and
wherein the third layer comprises Sn.

3. The electrode according to claim 1 ,
wherein the second layer comprises oxide of the first element or the second element, and
wherein the fourth layer comprises oxide of the first element or the second element.

4. The electrode according to claim 1 ,
wherein the second layer comprises nitride of the first element or the second element, and
wherein the fourth layer comprises nitride of the first element or the second element.

5. The electrode according to claim 1 ,
wherein the first layer has a thickness greater than or equal to 2 nm and less than or equal to 50 nm, and
wherein the third layer has a thickness greater than or equal to 2 nm and less than or equal to 50 nm.

6. The electrode according to claim 1 ,
wherein the second layer has a thickness greater than or equal to 1.6 nm and less than or equal to 60 nm, and
wherein the fourth layer has a thickness greater than or equal to 1.6 nm and less than or equal to 60 nm.

7. An electrode according to claim 1 ,
wherein the current collector is a negative electrode current collector, and
wherein the active material layer is a negative electrode active material layer.

8. A power storage device comprising:
a positive electrode; and
a negative electrode, the negative electrode comprising a negative electrode current collector and a negative electrode active material layer,
wherein the negative electrode active material layer comprises first to fourth layers,
wherein the second layer is provided between the first layer and the third layer,
wherein the third layer is provided between the second layer and the fourth layer,
wherein the first layer is in contact with the current collector,
wherein the first layer comprises Sn,
wherein the third layer comprises Sn,
wherein the second layer and the fourth layer comprises Sn,
wherein the second layer and the fourth layer comprises at least one of oxygen, nitrogen, sulfur, phosphorus, and fluorine, and
wherein the negative electrode active material layer is provided between the negative electrode current collector and the positive electrode.

9. A power storage device according to claim 8 ,
wherein the second layer and the fourth layer comprises tin oxide.

10. A power storage device according to claim 8 ,
wherein the second layer and the fourth layer comprises tin nitride.

11. A power storage device according to claim 8 ,
wherein the first layer has a thickness greater than or equal to 2 nm and less than or equal to 50 nm, and
wherein the third layer has a thickness greater than or equal to 2 nm and less than or equal to 50 nm.

12. A power storage device according to claim 8 ,
wherein the second layer has a thickness greater than or equal to 1.6 nm and less than or equal to 60 nm, and
wherein the fourth layer has a thickness greater than or equal to 1.6 nm and less than or equal to 60 nm.

13. An electronic device comprising:
the power storage device according to claim 8 ; and
a display device, a microphone, a speaker, an operation button, a housing, or a sensor.

14. A vehicle comprising:
the power storage device according to claim 8 ; and
a steering wheel or a display device.

15. A power storage device comprising:
a positive electrode; and
a negative electrode, the negative electrode comprising a negative electrode current collector and a negative electrode active material layer,
wherein the negative electrode active material layer comprises first to fourth layers,
wherein the second layer is provided between the first layer and the third layer,
wherein the third layer is provided between the second layer and the fourth layer,
wherein the first layer is in contact with the current collector,
wherein the first layer comprises a first element which is selected from Si, and Sn,
wherein the third layer comprises a second element which is selected from Si, and Sn,
wherein the second layer and the fourth layer comprises the first element or the second element,
wherein the second layer and the fourth layer comprises nitride of the first element or the second element, and
wherein the negative electrode active material layer is provided between the negative electrode current collector and the positive electrode.

16. A power storage device according to claim 15 ,
wherein the first layer has a thickness greater than or equal to 2 nm and less than or equal to 50 nm, and
wherein the third layer has a thickness greater than or equal to 2 nm and less than or equal to 50 nm.

17. A power storage device according to claim 15 ,
wherein the second layer has a thickness greater than or equal to 1.6 nm and less than or equal to 60 nm, and
wherein the fourth layer has a thickness greater than or equal to 1.6 nm and less than or equal to 60 nm.

18. A power storage device according to claim 15 ,
wherein the first layer and the third layer include amorphous silicon, and
wherein the second layer and the fourth layer include oxygen and silicon.

Assignees

• Semiconductor Energy Lab

Inventors

• Inoue Nobuhiro
• Tajima Ryota
• Kuriki Kazutaka
• Ichijo Mitsuhiro
• Hiura Yoshikazu
• Sugikawa Mai

Classifications

• H01M4/366

  as layered products · CPC title

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title

• H01M4/386

  Silicon or alloys based on silicon · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• Y02T10/7022

  Cross-Sectional Technologies · mapped topic