Polycarbonate containing photoconductors

Patent metadata

Field	Value
Publication number	US-9851647-B1
Application number	US-201615292931-A
Country	US
Kind code	B1
Filing date	Oct 13, 2016
Priority date	Oct 13, 2016
Publication date	Dec 26, 2017
Grant date	Dec 26, 2017

Abstract

A photoconductor that includes, for example, a supporting substrate, an optional ground plane layer, an optional hole blocking layer, an optional adhesive layer, a photogenerating layer, and a charge transport layer, and where the charge transport layer contains a mixture of a charge transport component and a polycarbonate AP.

First claim

What is claimed is:

1. A photoconductor comprising a photogenerating layer, and a charge transport layer, and wherein said charge transport layer contains a charge transport compound and a polycarbonate as represented by the following formula/structure

wherein m represents the number of repeating segments.

2. A photoconductor in accordance with claim 1 wherein m is from about 50 to about 500.

3. A photoconductor in accordance with claim 1 wherein said polycarbonate possesses a weight average molecular weight of from about 30,000 to about 100,000, and a number average molecular weight of from about 20,000 to about 70,000 as determined by GPC analysis.

4. A photoconductor in accordance with claim 1 further containing a supporting substrate, and situated between said substrate and said photogenerating layer a hole blocking layer, and situated between said photogenerating layer and said charge transport layer an adhesive layer.

5. A photoconductor in accordance with claim 1 further containing in the charge transport layer at least one of a hindered phenolic antioxidant and a fluoropolymer.

6. A photoconductor in accordance with claim 5 wherein said hindered phenolic antioxidant is a butylated hydroxytoluene.

7. A photoconductor in accordance with claim 5 wherein said fluoropolymer is selected from the group consisting of tetrafluoroethylene polymers, trifluorochloroethylene polymers, hexafluoropropylene polymers, vinyl fluoride polymers, vinylidene fluoride polymers, difluorodichloroethylene polymers or copolymers thereof, perfluoroalkoxy polymers, copolymers of tetrafluoroethylene and hexafluoropropylene, copolymers of hexafluoropropylene, and vinylidene fluoride, terpolymers of tetrafluoroethylene vinylidene fluoride and hexafluoropropylene, and tetrapolymers of tetrafluoroethylene vinylidene fluoride and hexafluoropropylene, and mixtures thereof.

8. A photoconductor in accordance with claim 5 wherein said fluoropolymer is a polytetrafluoroethylene.

9. A photoconductor in accordance with claim 1 wherein said charge transport compound is represented by at least one of

wherein X, Y, and Z are independently selected from the group consisting of alkyl, alkoxy, aryl, halogen, and mixtures thereof.

10. A photoconductor in accordance with claim 1 wherein said charge transport compound is represented by the following formula/structure

wherein x is alkyl, halogen, or mixtures thereof.

11. A photoconductor in accordance with claim 1 wherein said charge transport compound is selected from the group consisting of N,N′-bis(methylphenyl)-1,1-biphenyl-4,4′-diamine, tetra-p-tolyl-biphenyl-4,4′-diamine, N,N′-diphenyl-N,N′-bis(4-methoxyphenyl)-1,1-biphenyl-4,4′-diamine, N,N′-bis(4-butylphenyl)-N,N′-di-p-tolyl-[p-terphenyl]-4,4′-diamine, N,N′-bis(4-butylphenyl)-N,N′-di-m-tolyl-[p-terphenyl]-4,4′-diamine, N,N′-bis(4-butylphenyl)-N,N′-di-o-tolyl-[p-terphenyl]-4,4′-diamine, N,N′-bis(4-butylphenyl)-N,N′-bis-(4-isopropylphenyl)-[p-terphenyl]-4,4′-diamine, N,N′-bis(4-butylphenyl)-N,N′-bis-(2-ethyl-6-methylphenyl)-[p-terphenyl]-4,4′-diamine, N,N′-bis(4-butylphenyl)-N,N′-bis-(2,5-dimethylphenyl)-[p-terphenyl]-4,4′-diamine, and N,N′-diphenyl-N,N′-bis(3-chlorophenyl)-[p-terphenyl]-4,4′-diamine.

12. A photoconductor in accordance with claim 11 wherein said charge transport layer further includes an antioxidant and a fluoropolymer.

13. A photoconductor in accordance with claim 1 wherein said photogenerating layer is comprised of at least one photogenerating pigment.

14. A photoconductor in accordance with claim 1 wherein said photogenerating layer is comprised of at least one of a titanyl phthalocyanine, a hydroxygallium phthalocyanine, a halogallium phthalocyanine, a bisperylene, and mixtures thereof.

15. A photoconductor comprising in sequence a supporting substrate, a hole blocking layer thereover, a photogenerating layer, and a charge transport layer comprised of a mixture of an aryl amine hole transport compound, an antioxidant, a fluoropolymer, and a polycarbonate as represented by the following formula/structure

wherein m represents the number of repeating segments or groups.

16. A photoconductor in accordance with claim 15 wherein the value of m is from about 50 to about 500, said aryl amine is a charge transport compound selected from the group consisting of N,N′-bis(methylphenyl)-1,1-biphenyl-4,4′-diamine, tetra-p-tolyl-biphenyl-4,4′-diamine, N,N′-diphenyl-N,N′-bis(4-methoxyphenyl)-1,1-biphenyl-4,4′-diamine, N,N′-bis(4-butylphenyl)-N,N′-di-p-tolyl-[p-terphenyl]-4,4′-diamine, N,N′-bis(4-butylphenyl)-N,N′-di-m-tolyl-[p-terphenyl]-4,4′-diamine, N,N′-bis(4-butylphenyl)-N,N′-di-o-tolyl-[p-terphenyl]-4,4′-diamine, N,N′-bis(4-butylphenyl)-N,N′-bis-(4-isopropylphenyl)-[p-terphenyl]-4,4′-diamine, N,N′-bis(4-butylphenyl)-N,N′-bis-(2-ethyl-6-methylphenyl)-[p-terphenyl]-4,4′-diamine, N,N′-bis(4-butylphenyl)-N,N′-bis-(2,5-dimethylphenyl)-[p-terphenyl]-4,4′-diamine, and N,N′-diphenyl-N,N′-bis(3-chlorophenyl)-[p-terphenyl]-4,4′-diamine, said antioxidant is a hindered phenolic component, and wherein said photoconductor has minimal wear characteristics of from about 10 to about 20 nanometers per kilocycle.

17. A photoconductor in accordance with claim 15 wherein said hole blocking layer is comprised of an aminosilane of at least one of 3-aminopropyl triethoxysilane, N,N-dimethyl-3-aminopropyl triethoxysilane, N-phenylaminopropyl trimethoxysilane, triethoxysilylpropylethylene diamine, trimethoxysilylpropylethylene diamine, trimethoxysilylpropyldiethylene triamine, N-aminoethyl-3-aminopropyl trimethoxysilane, N-2-aminoethyl-3-aminopropyl trimethoxysilane, N-2-aminoethyl-3-aminopropyl tris(ethylethoxy)silane, p-aminophenyl trimethoxysilane, N,N′-dimethyl-3-aminopropyl triethoxysilane, 3-aminopropylmethyl diethoxysilane, 3-aminopropyl trimethoxysilane, N-methylaminopropyl triethoxysilane, methyl[2-(3-trimethoxysilylpropylamino)ethylamino]-3-proprionate, (N,N′-dimethyl 3-amino)propyl triethoxysilane, N,N-dimethylaminophenyl triethoxysilane, trimethoxysilyl propyldiethylene triamine, and mixtures thereof.

18. A photoconductor comprising a supporting substrate, an optional hole blocking layer thereover, a photogenerating layer, and a hole transport layer comprised of a mixture of a hole transport compound, an optional fluoropolymer, an optional antioxidant, and a polycarbonate as encompassed by the following formula/structure, and which photoconductor possesses a wear rate reduction of from about 5 percent to about 25 percent

wherein m represents the number of repeating segments or groups.

19. A photoconductor in accordance with claim 18 wherein said antioxidant and said fluoropolymer are present.

20. A photoconductor in accordance with claim 18 wherein said wear rate reduction is expressed as a wear rate of from about 10 to about 20 nanometers per kilocycle.

21. A photoconductor in accordance with claim 1 wherein said photoconductor has minimal wear characteristics of from about 10 to about 20 nanometer

Assignees

• Xerox Corp

Inventors

• Wu Jin
• Dinh Kenny-Tuan
• Zhang Lanhui
• Kelly Jimmy E
• Thomas Mark S
• Fu Min-Hong
• Ma Lin
• Silvestri Markus R
• Livecchi Marc J
• Hedrick Robert W
• Ferrarese Linda L

Classifications

• G03G5/142

  Inert intermediate layers · CPC title

• G03G5/0564

  Polycarbonates · CPC title

• G03G5/047 Primary

  characterised by the charge-generation layers or charge transport layers {(G03G5/0433 and G03G5/0436 take precedence)} · CPC title

• G03G5/075

  obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds (G03G5/078 takes precedence) · CPC title

• G03G5/0609

  containing oxygen · CPC title