Ni superalloy component production method

Patent metadata

Field	Value
Publication number	US-9850563-B2
Application number	US-201514614732-A
Country	US
Kind code	B2
Filing date	Feb 5, 2015
Priority date	Feb 11, 2014
Publication date	Dec 26, 2017
Grant date	Dec 26, 2017

Abstract

Producing a Ni superalloy component in which the superalloy has a γ phase matrix containing intermetallic γ′ precipitates. Providing a Ni superalloy casting of the component; solutioning the component by heat treating the casting under vacuum and/or in an inert atmosphere at a temperature above the γ′ solvus to homogenize the γ phase; quenching and ageing the solutioned component to grow intermetallic γ′ precipitates in the homogenized γ phase. Before the solutioning step: heat treating the casting to produce a thermally grown oxide on the surface, oxide adherent to supress volatilization of Ni from the surface of the casting during the solutioning heat treatment. Performing the solutioning step under a Ni vapor pressure which is sufficient to supress volatilization of Ni from the surface of the casting during the solutioning heat treatment. During the solutioning heat treatment the component is encapsulated in a container protecting the casting from Si-doped contaminants.

First claim

The invention claimed is:

1. A method of producing a Ni superalloy component in which the superalloy has a γ phase matrix containing intermetallic γ′ precipitates, the method including:
providing a Ni superalloy casting of the component,
oxidising the component by heat treating the casting to produce a thermally grown oxide on a surface thereof,
then solutioning the component by heat treating the casting under vacuum and/or in an atmosphere wherein the partial pressure of O 2 during the solutioning heat treatment is less than 0.21 atm at a temperature above the γ′ solvus to homogenise the γ phase, and
quenching and then ageing the solutioned component to grow intermetallic γ′ precipitates in the homogenised γ phase;
wherein the oxide thermally grown on the surface of the casting is sufficiently adherent and stable to substantially supress volatilisation of Ni from the surface of the casting during the solutioning heat treatment.

2. A method according to claim 1 , wherein the thermally grown oxide is Al 2 O 3 .

3. A method according to claim 1 , wherein the oxidising heat treatment is performed at a temperature above 800° C.

4. A method according to claim 1 , wherein the oxidising heat treatment is performed at a temperature below 1100° C.

5. A method according to claim 1 , wherein the oxidising heat treatment is performed for at least 1 hour.

6. A method according to claim 1 , wherein the thermally grown oxide has a thickness of at least 0.1 μm.

7. A method according to claim 1 , wherein the thermally grown oxide is removed from the Ni superalloy component following the oxidising heat treatment.

8. A method according to claim 7 , wherein further features are formed or machined into the Ni superalloy component following the removal of the thermally grown oxide.

9. A method according to claim 1 , wherein the solutioning is performed under a Ni vapour pressure which is sufficient to substantially supress volatilisation of Ni from the surface of the casting during the solutioning heat treatment.

10. A method according to claim 1 , wherein the component is a turbine blade.

11. A method of producing a Ni superalloy component in which the superalloy has a γ phase matrix containing intermetallic γ′ precipitates, the method including:
providing a Ni superalloy casting of the component,
solutioning the component by heat treating the casting under vacuum and/or in an atmosphere wherein the partial pressure of O 2 during the solutioning heat treatment is less than 0.21 atm at a temperature above the γ′ solvus to homogenise the γ phase, and
quenching and then ageing the solutioned component to grow intermetallic γ′ precipitates in the homogenised γ phase;
wherein the solutioning is performed under a Ni vapour pressure which is sufficient to substantially supress volatilisation of Ni from a surface of the casting during the solutioning heat treatment.

12. A method according to claim 11 , wherein, during the solutioning, the casting is heat treated at a temperature above the γ′ solvus in the presence of sacrificial Ni to produce the Ni vapour pressure.

13. A method of producing a Ni superalloy component in which the superalloy has a γ phase matrix containing intermetallic γ′ precipitates, the method including:
providing a Ni superalloy casting of the component,
solutioning the component by heat treating the casting under vacuum and/or in an atmosphere wherein the partial pressure of O 2 during the solutioning heat treatment is less than 0.21 atm at a temperature above the γ′ solvus to homogenise the γ phase, and
quenching and then ageing the solutioned component to grow intermetallic γ′ precipitates in the homogenised γ phase;
wherein during the solutioning heat treatment, the component is encapsulated in a container which protects the casting from Si-doped contaminants.

14. A method of producing a Ni superalloy component in which the superalloy has a γ phase matrix containing intermetallic γ′ precipitates, the method including:
providing a Ni superalloy casting of the component,
oxidising the component by heat treating the casting to produce a thermally grown oxide on a surface thereof,
then solutioning the component by heat treating the casting under vacuum and/or in an inert atmosphere at a temperature above the γ′ solvus to homogenise the γ phase, and
quenching and then ageing the solutioned component to grow intermetallic γ′ precipitates in the homogenised γ phase;
wherein the oxide thermally grown on the surface of the casting is sufficiently adherent and stable to substantially supress volatilisation of Ni from the surface of the casting during the solutioning heat treatment.

Assignees

• Rolls Royce Plc

Inventors

• D'Souza Neil John
• Goodwin Kevin
• Perry Martin Richard

Classifications

• C22C19/057

  with the maximum Cr content being less 10% · CPC title

• C22F1/10 Primary

  of nickel or cobalt or alloys based thereon · CPC title

• C22F1/02

  in inert or controlled atmosphere or vacuum (adjusting the composition of the atmosphere C21D1/76) · CPC title

• C22F1/002

  by rapid cooling or quenching; cooling agents used therefor · CPC title

• C23C8/10

  Oxidising · CPC title