Aqueous solutions containing a complexing agent in high concentration

Patent metadata

Field	Value
Publication number	US-9850453-B2
Application number	US-201414893859-A
Country	US
Kind code	B2
Filing date	May 13, 2014
Priority date	May 27, 2013
Publication date	Dec 26, 2017
Grant date	Dec 26, 2017

Abstract

Aqueous solution comprising (A) in the range of from 30 to 60% by weight of a complexing agent, selected from the alkali metal salts of methylglycine diacetic acid and the alkali metal salts of glutamic acid diacetic acid, (B) in the range of from 1 to 25% by weight of at least one salt of a sulfonic acid or of an organic acid, percentages referring to the total respective aqueous solution.

First claim

The invention claimed is:

1. An aqueous solution, comprising:
(A) from 30 to 60% by weight of a complexing agent, which is selected from the group consisting of an alkali metal salt of methylglycine diacetic acid and an alkali metal salt of glutamic acid diacetic acid, and
(B) from 1 to 25% by weight of at least one salt of a sulfonic acid or of an organic acid,
based on a total weight of the aqueous solution,
wherein the aqueous solution is free from surfactants,
wherein the aqueous solution has a total solids content from 31 to 65% by weight, and wherein a pH of the aqueous solution is from 9 to 14.

2. The aqueous solution according to claim 1 having the pH value of from 9 to 13.

3. The aqueous solution according to claim 1 , wherein (B) is at least one alkali metal salt of acetic acid, tartaric acid, lactic acid, maleic acid, fumaric acid, or of malic acid.

4. The aqueous solution according to claim 1 , wherein (B) is at least one alkali metal salt of methyl sulfonic acid.

5. The aqueous solution according to claim 1 , further comprising:
(C) a polyethylene glycol having an average molecular weight M n of from 400 to 10,000 g/mol.

6. A process for making the aqueous solution according to claim 1 , the process comprising combining the complexing agent (A) with the salt (B), thereby forming the aqueous solution.

7. A process for manufacturing a laundry care or dish wash formulation, the process comprising:
employing the aqueous solutions according to claim 1 in the process.

8. A process comprising transporting the aqueous solution according to claim 1 in a pipe or a container.

9. The aqueous solution according to claim 1 , wherein the alkali metal salt of methylglycine diacetic acid is a lithium salt, potassium salt, sodium salt, or a combination thereof.

10. The aqueous solution according to claim 1 , wherein the methylglycine diacetic acid is partially or fully neutralized with a respective alkali.

11. The aqueous solution according to claim 1 , wherein an average of from 2.7 to 3 COOH groups of the methylglycine diacetic acid is neutralized with an alkali metal.

12. The aqueous solution according to claim 1 , wherein the complexing agent (A) is a trisodium salt of the methylglycine diacetic acid.

13. The aqueous solution according to claim 1 , comprising from 35 to 50% by weight of the alkali metal salt of methylglycine diacetic acid as the complexing agent (A).

14. The aqueous solution according to claim 1 , comprising from 37 to 45% by weight of the alkali metal salt of methylglycine diacetic acid as the complexing agent (A).

15. The aqueous solution according to claim 1 , comprising from 45 to 58% by weight of the alkali metal salt of glutamic acid diacetic acid as the complexing agent (A).

16. The aqueous solution according to claim 1 , comprising from 46 to 53% by weight of the alkali metal salt of glutamic acid diacetic acid as the complexing agent (A).

17. The aqueous solution according to claim 5 , wherein the polyethylene glycol has an average molecular weight M n of from 600 to 6,000 g/mol.

18. The aqueous solution according to claim 5 , comprising from 1 to 20% by weight of the polyethylene glycol (C).

19. The aqueous solution according to claim 1 having a dynamic viscosity of from 80 to 500 mPa·s determined according to DIN 53018-1.2008-09 at 25° C.

20. The aqueous solution according to claim 1 having a Hazen color number of from 15 to 400 determined according to DIN EN 1557:1997-03 at 25° C.

Assignees

• Basf Se

Inventors

• Biel Markus Christian
• Greindl Thomas
• Hartmann Markus
• Staffel Wolfgang
• Reinoso Garcia Marta

Classifications

• C11D3/33 Primary

  Amino carboxylic acids · CPC title

• C11D3/3409

  Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates · CPC title

• C11D7/264

  Aldehydes; Ketones; Acetals or ketals · CPC title

• C11D3/2079

  Monocarboxylic acids-salts thereof · CPC title

• C11D7/3245

  Aminoacids · CPC title