Use of carbon dioxide soluble nonionic surfactants for enhanced crude oil recovery

Patent metadata

Field	Value
Publication number	US-9850421-B2
Application number	US-201214343905-A
Country	US
Kind code	B2
Filing date	Sep 20, 2012
Priority date	Sep 23, 2011
Publication date	Dec 26, 2017
Grant date	Dec 26, 2017

Abstract

The present disclosure includes a nonionic surfactant and a method of providing the nonionic surfactant, where the nonionic surfactant is soluble in carbon dioxide and is used as part of a dispersion for enhanced crude oil recovery. The nonionic surfactant can be part of an emulsion that includes carbon dioxide and a diluent.

First claim

We claim:

1. A dispersion for enhanced crude oil recovery, comprising:
carbon dioxide in a liquid or a super critical state;
a diluent selected from the group consisting of water, brine, connate water, surface water, distilled water, carbonated water, sea water and combinations thereof; and
a nonionic surfactant provided by a reaction product of an alkoxylation reaction of a primary aliphatic amine with propylene oxide followed by ethylene oxide, wherein the primary aliphatic amine is selected from a tertiary butylamine, a branched C8 tertiary alkyl primary amine, a mixture of branched C16 to C33 tertiary alkyl primary amine isomers and a mixture of branched C12 to C14 tertiary alkyl primary amine isomers, where the nonionic surfactant is formed with a molar ratio of propylene oxide to the branched alkyl monoamine in a range of 1.5:1.0 moles to 10:1.0 moles and a molar ratio of ethylene oxide to branched alkyl monoamine in a range of 3.0:1.0 moles to 40.0:1.0 moles.

2. The dispersion for enhanced crude oil recovery of claim 1 , where the branched alkyl monoamine is a branched C8 tertiary alkyl primary amine.

3. The dispersion for enhanced crude oil recovery of claim 1 , where the branched alkyl monoamine is a mixture of branched C12 to C14 tertiary alkyl primary amine isomers.

4. The dispersion for enhanced crude oil recovery of claim 1 , where the alkoxylation reaction has a molar ratio of propylene oxide to branched alkyl monoamine in a range of 1.5:1.0 moles to 10:1.0 moles.

5. The dispersion for enhanced crude oil recovery of claim 1 , where the the alkoxylation reaction has a molar ratio of ethylene oxide to branched alkyl monoamine in a range of 3.0:1.0 moles to 40.0:1.0 moles.

6. The dispersion for enhanced crude oil recovery of claim 5 , where the alkoxylation reaction uses a molar ratio of ethylene oxide to branched alkyl monoamine of 12.0:1.0 moles.

7. The dispersion for enhanced crude oil recovery of claim 5 , where the alkoxylation reaction uses a molar ratio of ethylene oxide to branched alkyl monoamine of 16.0:1.0 moles.

8. A method for recovering crude oil from a subterranean formation that is penetrated by at least one injection well and one production well, comprising:
forming a dispersion of carbon dioxide and a diluent in the subterranean formation with a nonionic surfactant, the nonionic surfactant provided by a reaction product of an alkoxylation reaction of primary aliphatic amine with propylene oxide followed by ethylene oxide, wherein the primary aliphatic amine is selected from a tertiary butylamine, a branched C8 tertiary alkyl primary amine, a mixture of branched C16 to C33 tertiary alkyl primary amine isomers and a mixture of branched C12 to C14 tertiary alkyl primary amine isomers, where the nonionic surfactant is formed with a molar ratio of propylene oxide to the branched alkyl monoamine in a range of 1.5:1.0 moles to 10:1.0 moles and a molar ratio of ethylene oxide to branched alkyl monoamine in a range of 3.0:1.0 moles to 40.0:1.0 moles, wherein the diluent is selected from the group consisting of water, brine, connate water, surface water, distilled water, carbonated water, sea water and combinations thereof; and
recovering crude oil from the subterranean formation from a production well.

9. The method of claim 8 , where forming the dispersion includes injecting the nonionic surfactant with water into the subterranean formation via the injection well.

10. The method of claim 9 , where injecting the nonionic surfactant with water into the subterranean formation includes injecting carbon dioxide into the subterranean formation after injecting the nonionic surfactant with water into the subterranean formation.

11. The method of claim 1 , wherein the molar ratio of propylene oxide to the branched alkyl monoamine is in a range of 3.0:1.0 moles to 10:1.0 moles.

12. The method of claim 1 , wherein the molar ratio of propylene oxide to the branched alkyl monoamine is in a range of 5.0:1.0 moles to 10:1.0 moles.

13. The method of claim 1 , wherein the molar ratio of propylene oxide to the branched alkyl monoamine is in a range of 3.0:1.0 moles to 5.0:1.0 moles.

14. The method of claim 1 , wherein the molar ratio of ethylene oxide to branched alkyl monoamine is in a range of 8.0:1.0 moles to 40.0:1.0 moles.

15. The method of claim 1 , wherein the molar ratio of ethylene oxide to branched alkyl monoamine is in a range of 8.0:1.0 moles to 22.0:1.0 moles.

16. The method of claim 1 , wherein the molar ratio of ethylene oxide to branched alkyl monoamine is in a range of 12.0:1.0 moles to 22.0:1.0 moles.

Assignees

• Dow Global Technologies Llc

Inventors

• Abbas Sayeed
• Sanders Aaron W
• Chakraborty Debashis

Classifications

• C09K8/584 Primary

  characterised by the use of specific surfactants · CPC title

• E21B43/164

  Injecting CO2 or carbonated water (in combination with organic material C09K8/594) · CPC title

• C08G65/2624

  containing aliphatic amine groups · CPC title

• C09K8/594 Primary

  Compositions used in combination with injected gas {, e.g. CO2 orcarbonated gas}(C09K8/592 takes precedence) · CPC title

• E21B43/16

  Enhanced recovery methods for obtaining hydrocarbons · CPC title